3-Aminocarbonylpyridinium difluoroacetate at 123 K
In the crystal of the title compound, C6H7N2O+·C2HF2O2−, the cation adopts a catemeric N—H...O hydrogen-bonded chain motif involving the carboxamide group, with two further N—H...O hydrogen bonds connecting the cations to adjacent difluoroacetat...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809043414 |
| _version_ | 1818948289928626176 |
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| author | Julie Bardin Alastair J. Florence Jean-Baptiste Arlin Alan R. Kennedy Li Ven Wong |
| author_facet | Julie Bardin Alastair J. Florence Jean-Baptiste Arlin Alan R. Kennedy Li Ven Wong |
| author_sort | Julie Bardin |
| collection | DOAJ |
| description | In the crystal of the title compound, C6H7N2O+·C2HF2O2−, the cation adopts a catemeric N—H...O hydrogen-bonded chain motif involving the carboxamide group, with two further N—H...O hydrogen bonds connecting the cations to adjacent difluoroacetate anions via the carboxamide and pyridinium N atoms. The carboxamide group of the nicotinamidium ion is twisted by 32.3 (6)° from the pyridine ring plane. A number of C—H...O and C—H...F interactions consolidate the packing. |
| first_indexed | 2024-12-20T08:44:26Z |
| format | Article |
| id | doaj.art-20ada4a7ff874caa99b3ce47f15979d0 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T08:44:26Z |
| publishDate | 2009-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-20ada4a7ff874caa99b3ce47f15979d02022-12-21T19:46:18ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511o2896o289710.1107/S16005368090434143-Aminocarbonylpyridinium difluoroacetate at 123 KJulie BardinAlastair J. FlorenceJean-Baptiste ArlinAlan R. KennedyLi Ven WongIn the crystal of the title compound, C6H7N2O+·C2HF2O2−, the cation adopts a catemeric N—H...O hydrogen-bonded chain motif involving the carboxamide group, with two further N—H...O hydrogen bonds connecting the cations to adjacent difluoroacetate anions via the carboxamide and pyridinium N atoms. The carboxamide group of the nicotinamidium ion is twisted by 32.3 (6)° from the pyridine ring plane. A number of C—H...O and C—H...F interactions consolidate the packing.http://scripts.iucr.org/cgi-bin/paper?S1600536809043414 |
| spellingShingle | Julie Bardin Alastair J. Florence Jean-Baptiste Arlin Alan R. Kennedy Li Ven Wong 3-Aminocarbonylpyridinium difluoroacetate at 123 K Acta Crystallographica Section E |
| title | 3-Aminocarbonylpyridinium difluoroacetate at 123 K |
| title_full | 3-Aminocarbonylpyridinium difluoroacetate at 123 K |
| title_fullStr | 3-Aminocarbonylpyridinium difluoroacetate at 123 K |
| title_full_unstemmed | 3-Aminocarbonylpyridinium difluoroacetate at 123 K |
| title_short | 3-Aminocarbonylpyridinium difluoroacetate at 123 K |
| title_sort | 3 aminocarbonylpyridinium difluoroacetate at 123 amp 8197 k |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809043414 |
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