Purified Glycerine from Biodiesel Production as Biomass or Waste-Based Green Raw Material for the Production of Biochemicals
Glycerine (glycerol) is a polyol consisting of three carbon atoms bonded to hydroxyl groups. It is a by-product of the transesterification of triglycerides, such as animal fats, vegetable oils, or used cooking oils during the biodiesel production process. Crude glycerine is subject to purification p...
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বিন্যাস: | প্রবন্ধ |
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MDPI AG
2023-06-01
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মালা: | Energies |
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অনলাইন ব্যবহার করুন: | https://www.mdpi.com/1996-1073/16/13/4889 |
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author | Grzegorz Borówka Grzegorz Semerjak Wojciech Krasodomski Jan Lubowicz |
author_facet | Grzegorz Borówka Grzegorz Semerjak Wojciech Krasodomski Jan Lubowicz |
author_sort | Grzegorz Borówka |
collection | DOAJ |
description | Glycerine (glycerol) is a polyol consisting of three carbon atoms bonded to hydroxyl groups. It is a by-product of the transesterification of triglycerides, such as animal fats, vegetable oils, or used cooking oils during the biodiesel production process. Crude glycerine is subject to purification processes resulting in distilled glycerine containing at least 99.5% glycerol. Currently, produced high-quality distilled glycerine is used in the food, pharmaceutical, and cosmetic industries. Recently, technologies for converting glycerol to other chemicals through catalytic processes have been intensively developed, e.g., production of bio-based 1,2-propanediol. In the near future, glycerol will certainly become a promising renewable raw material in many modern biorefineries for the synthesis of biofuels, chemicals, and bioenergy production. This paper presents the possibility of using ion exchange resins to remove impurities with trace amounts of sulphur and nitrogen compounds from crude and distilled glycerine, produced during the biodiesel production process from used cooking oils. It was determined that using ion exchange resins at the preliminary purification stage (before distillation) was ineffective. Using cationite resins to purify distilled glycerine produced from waste materials enables the removal of impurities in the form of sulphur and nitrogen compounds. |
first_indexed | 2024-03-11T01:42:44Z |
format | Article |
id | doaj.art-20c28b51983c4fb3a55172f16e2ddf0c |
institution | Directory Open Access Journal |
issn | 1996-1073 |
language | English |
last_indexed | 2024-03-11T01:42:44Z |
publishDate | 2023-06-01 |
publisher | MDPI AG |
record_format | Article |
series | Energies |
spelling | doaj.art-20c28b51983c4fb3a55172f16e2ddf0c2023-11-18T16:27:20ZengMDPI AGEnergies1996-10732023-06-011613488910.3390/en16134889Purified Glycerine from Biodiesel Production as Biomass or Waste-Based Green Raw Material for the Production of BiochemicalsGrzegorz Borówka0Grzegorz Semerjak1Wojciech Krasodomski2Jan Lubowicz3ORLEN Południe S.A., Fabryczna 22, 32-540 Trzebinia, PolandORLEN Południe S.A., Fabryczna 22, 32-540 Trzebinia, PolandOil and Gas Institute—National Research Institute, 25 A Lubicz Str., 31-503 Kraków, PolandOil and Gas Institute—National Research Institute, 25 A Lubicz Str., 31-503 Kraków, PolandGlycerine (glycerol) is a polyol consisting of three carbon atoms bonded to hydroxyl groups. It is a by-product of the transesterification of triglycerides, such as animal fats, vegetable oils, or used cooking oils during the biodiesel production process. Crude glycerine is subject to purification processes resulting in distilled glycerine containing at least 99.5% glycerol. Currently, produced high-quality distilled glycerine is used in the food, pharmaceutical, and cosmetic industries. Recently, technologies for converting glycerol to other chemicals through catalytic processes have been intensively developed, e.g., production of bio-based 1,2-propanediol. In the near future, glycerol will certainly become a promising renewable raw material in many modern biorefineries for the synthesis of biofuels, chemicals, and bioenergy production. This paper presents the possibility of using ion exchange resins to remove impurities with trace amounts of sulphur and nitrogen compounds from crude and distilled glycerine, produced during the biodiesel production process from used cooking oils. It was determined that using ion exchange resins at the preliminary purification stage (before distillation) was ineffective. Using cationite resins to purify distilled glycerine produced from waste materials enables the removal of impurities in the form of sulphur and nitrogen compounds.https://www.mdpi.com/1996-1073/16/13/4889glycerinebiodieselbiofuelsbio-based chemicalspurification of glycerineused cooking oils |
spellingShingle | Grzegorz Borówka Grzegorz Semerjak Wojciech Krasodomski Jan Lubowicz Purified Glycerine from Biodiesel Production as Biomass or Waste-Based Green Raw Material for the Production of Biochemicals Energies glycerine biodiesel biofuels bio-based chemicals purification of glycerine used cooking oils |
title | Purified Glycerine from Biodiesel Production as Biomass or Waste-Based Green Raw Material for the Production of Biochemicals |
title_full | Purified Glycerine from Biodiesel Production as Biomass or Waste-Based Green Raw Material for the Production of Biochemicals |
title_fullStr | Purified Glycerine from Biodiesel Production as Biomass or Waste-Based Green Raw Material for the Production of Biochemicals |
title_full_unstemmed | Purified Glycerine from Biodiesel Production as Biomass or Waste-Based Green Raw Material for the Production of Biochemicals |
title_short | Purified Glycerine from Biodiesel Production as Biomass or Waste-Based Green Raw Material for the Production of Biochemicals |
title_sort | purified glycerine from biodiesel production as biomass or waste based green raw material for the production of biochemicals |
topic | glycerine biodiesel biofuels bio-based chemicals purification of glycerine used cooking oils |
url | https://www.mdpi.com/1996-1073/16/13/4889 |
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