A systematic variation in cationic distribution and its influence on the magnetization of mixed-metal (nickel and zinc) cobaltite spinels
Cobaltite oxide spinel (CoCo _2 O _4 ) is one promising material that has been extensively studied for decades due to its versatile applications. Revealing the correlation among chemical compositions, cationic distributions, and physical properties are crucial for exploring its novel application. He...
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| Format: | Article |
| Language: | English |
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IOP Publishing
2020-01-01
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| Series: | Materials Research Express |
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| Online Access: | https://doi.org/10.1088/2053-1591/abb4fc |
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| author | Wanchai Deeloed Worawat Wattanathana Pongsakorn Jantaratana Panida Prompinit Suttipong Wannapaiboon Suparat Singkammo Suchinda Sattayaporn Apirat Laobuthee Songwut Suramitr Yuranan Hanlumyuang |
| author_facet | Wanchai Deeloed Worawat Wattanathana Pongsakorn Jantaratana Panida Prompinit Suttipong Wannapaiboon Suparat Singkammo Suchinda Sattayaporn Apirat Laobuthee Songwut Suramitr Yuranan Hanlumyuang |
| author_sort | Wanchai Deeloed |
| collection | DOAJ |
| description | Cobaltite oxide spinel (CoCo _2 O _4 ) is one promising material that has been extensively studied for decades due to its versatile applications. Revealing the correlation among chemical compositions, cationic distributions, and physical properties are crucial for exploring its novel application. Here, a series of nickel/zinc co-substituted cobaltite spinels, Zn _1−X Ni _X Co _2 O _4 (ZNCO-X; where X = 0.00, 0.25, …, 1.00), was synthesized by calcining the hydrothermal-derived precursors and their magnetic properties have been investigated. Multiple x-ray based characterization techniques (XRD, XRF, XPS, and XAS) were applied to determine the crystalline structure and appropriated compositions of cation species (Zn ^2+ , Ni ^2+ , Ni ^3+ , Co ^2+ , and Co ^3+ ). In conjunction with Neel’s theory of antiferromagnetism, the theoretical magnetization of the spinel series was calculated based on the assumption that Zn ^2+ ion was located in tetrahedral (A site) while nickel cations (Ni ^2+ and Ni ^3+ ) occupying the octahedral (B site). The theoretical magnetization profile exhibited a good correlation. Superparamagnetic effect and cationic site exchange can be used to explain the discrepancies between the measured and calculated magnetizations. This work reported a systematic controlling of materials structure and cationic distribution, which are crucial for fine-tuning the magnetic property of the Zn _1−X Ni _X Co _2 O _4 cobaltite system. |
| first_indexed | 2024-03-12T15:33:09Z |
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| language | English |
| last_indexed | 2024-03-12T15:33:09Z |
| publishDate | 2020-01-01 |
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| series | Materials Research Express |
| spelling | doaj.art-20ca232d01974c7494478f59b7977bf72023-08-09T16:19:19ZengIOP PublishingMaterials Research Express2053-15912020-01-017909610410.1088/2053-1591/abb4fcA systematic variation in cationic distribution and its influence on the magnetization of mixed-metal (nickel and zinc) cobaltite spinelsWanchai Deeloed0https://orcid.org/0000-0002-6706-6421Worawat Wattanathana1https://orcid.org/0000-0002-3592-3708Pongsakorn Jantaratana2https://orcid.org/0000-0002-4050-3628Panida Prompinit3https://orcid.org/0000-0001-6532-0724Suttipong Wannapaiboon4https://orcid.org/0000-0002-6765-9809Suparat Singkammo5Suchinda Sattayaporn6https://orcid.org/0000-0002-7618-8340Apirat Laobuthee7https://orcid.org/0000-0001-9744-9864Songwut Suramitr8https://orcid.org/0000-0002-6941-8814Yuranan Hanlumyuang9https://orcid.org/0000-0003-0252-1435Department of Chemistry, Faculty of Science, Kasetsart University , Bangkok 10900, Thailand; Center for Advanced Studies in Nanotechnology for Chemical, Food and Agricultural Industries, KU Institute for Advanced Studies, Kasetsart University, Bangkok 10900, ThailandDepartment of Materials Engineering, Faculty of Engineering, Kasetsart University, Bangkok 10900, ThailandDepartment of Physics, Faculty of Science, Kasetsart University , Bangkok 10900, ThailandHybrid Nanostructure and Nanocomposites Laboratory, National Nanotechnology Center (NANOTEC), National Science and Technology Development Agency (NSTDA), Pathum Thani 12120, ThailandSynchrotron Light Research Institute, 111 University Avenue , Suranaree, Muang, Nakhon Ratchasima 30000, ThailandSynchrotron Light Research Institute, 111 University Avenue , Suranaree, Muang, Nakhon Ratchasima 30000, ThailandSynchrotron Light Research Institute, 111 University Avenue , Suranaree, Muang, Nakhon Ratchasima 30000, ThailandDepartment of Materials Engineering, Faculty of Engineering, Kasetsart University, Bangkok 10900, ThailandDepartment of Chemistry, Faculty of Science, Kasetsart University , Bangkok 10900, Thailand; Center for Advanced Studies in Nanotechnology for Chemical, Food and Agricultural Industries, KU Institute for Advanced Studies, Kasetsart University, Bangkok 10900, ThailandDepartment of Materials Engineering, Faculty of Engineering, Kasetsart University, Bangkok 10900, ThailandCobaltite oxide spinel (CoCo _2 O _4 ) is one promising material that has been extensively studied for decades due to its versatile applications. Revealing the correlation among chemical compositions, cationic distributions, and physical properties are crucial for exploring its novel application. Here, a series of nickel/zinc co-substituted cobaltite spinels, Zn _1−X Ni _X Co _2 O _4 (ZNCO-X; where X = 0.00, 0.25, …, 1.00), was synthesized by calcining the hydrothermal-derived precursors and their magnetic properties have been investigated. Multiple x-ray based characterization techniques (XRD, XRF, XPS, and XAS) were applied to determine the crystalline structure and appropriated compositions of cation species (Zn ^2+ , Ni ^2+ , Ni ^3+ , Co ^2+ , and Co ^3+ ). In conjunction with Neel’s theory of antiferromagnetism, the theoretical magnetization of the spinel series was calculated based on the assumption that Zn ^2+ ion was located in tetrahedral (A site) while nickel cations (Ni ^2+ and Ni ^3+ ) occupying the octahedral (B site). The theoretical magnetization profile exhibited a good correlation. Superparamagnetic effect and cationic site exchange can be used to explain the discrepancies between the measured and calculated magnetizations. This work reported a systematic controlling of materials structure and cationic distribution, which are crucial for fine-tuning the magnetic property of the Zn _1−X Ni _X Co _2 O _4 cobaltite system.https://doi.org/10.1088/2053-1591/abb4fccobaltite spinelx-ray techniquescationic distributionmagnetization |
| spellingShingle | Wanchai Deeloed Worawat Wattanathana Pongsakorn Jantaratana Panida Prompinit Suttipong Wannapaiboon Suparat Singkammo Suchinda Sattayaporn Apirat Laobuthee Songwut Suramitr Yuranan Hanlumyuang A systematic variation in cationic distribution and its influence on the magnetization of mixed-metal (nickel and zinc) cobaltite spinels Materials Research Express cobaltite spinel x-ray techniques cationic distribution magnetization |
| title | A systematic variation in cationic distribution and its influence on the magnetization of mixed-metal (nickel and zinc) cobaltite spinels |
| title_full | A systematic variation in cationic distribution and its influence on the magnetization of mixed-metal (nickel and zinc) cobaltite spinels |
| title_fullStr | A systematic variation in cationic distribution and its influence on the magnetization of mixed-metal (nickel and zinc) cobaltite spinels |
| title_full_unstemmed | A systematic variation in cationic distribution and its influence on the magnetization of mixed-metal (nickel and zinc) cobaltite spinels |
| title_short | A systematic variation in cationic distribution and its influence on the magnetization of mixed-metal (nickel and zinc) cobaltite spinels |
| title_sort | systematic variation in cationic distribution and its influence on the magnetization of mixed metal nickel and zinc cobaltite spinels |
| topic | cobaltite spinel x-ray techniques cationic distribution magnetization |
| url | https://doi.org/10.1088/2053-1591/abb4fc |
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