Conversion of Hard to Soft Magnetic Ferrite Nanowires by Paramagnetic Shielding

In this study, we investigate the magnetization behavior of coaxial nanowires fabricated through the sol-gel electrospinning method. Our analysis uncovers a significant reduction in coercivity for CoFe<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="i...

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Main Authors: Xian-Lin Zeng, Indujan Sivanesarajah, Uwe Hartmann
Format: Article
Language:English
Published: MDPI AG 2023-10-01
Series:Solids
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Online Access:https://www.mdpi.com/2673-6497/4/4/19
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author Xian-Lin Zeng
Indujan Sivanesarajah
Uwe Hartmann
author_facet Xian-Lin Zeng
Indujan Sivanesarajah
Uwe Hartmann
author_sort Xian-Lin Zeng
collection DOAJ
description In this study, we investigate the magnetization behavior of coaxial nanowires fabricated through the sol-gel electrospinning method. Our analysis uncovers a significant reduction in coercivity for CoFe<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2</mn></msub></semantics></math></inline-formula>O<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>4</mn></msub></semantics></math></inline-formula> nanowires when BaTiO<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>3</mn></msub></semantics></math></inline-formula> is used as the shell material, effectively transforming them from hard to soft magnetic. This intriguing behavior is attributed to the magnetization reversal effect at the interface between ferromagnetic and paramagnetic regions, and it is also observed in NiFe<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2</mn></msub></semantics></math></inline-formula>O<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>4</mn></msub></semantics></math></inline-formula> and Fe<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2</mn></msub></semantics></math></inline-formula>O<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>3</mn></msub></semantics></math></inline-formula> nanowires. Surprisingly, introducing a GdBa<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2</mn></msub></semantics></math></inline-formula>Cu<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>3</mn></msub></semantics></math></inline-formula>O<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>7</mn></msub></semantics></math></inline-formula> shell induces a similar effect. Additionally, we employ magnetic impedance measurements on the coaxial nanowires, unveiling their potential for magnetic field sensing applications.
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spelling doaj.art-20d645223c6b4724976519d53d0bab9a2023-12-22T14:43:09ZengMDPI AGSolids2673-64972023-10-014430431510.3390/solids4040019Conversion of Hard to Soft Magnetic Ferrite Nanowires by Paramagnetic ShieldingXian-Lin Zeng0Indujan Sivanesarajah1Uwe Hartmann2Institute of Experimental Physics, Saarland University, D-66123 Saarbrücken, GermanyInstitute of Experimental Physics, Saarland University, D-66123 Saarbrücken, GermanyInstitute of Experimental Physics, Saarland University, D-66123 Saarbrücken, GermanyIn this study, we investigate the magnetization behavior of coaxial nanowires fabricated through the sol-gel electrospinning method. Our analysis uncovers a significant reduction in coercivity for CoFe<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2</mn></msub></semantics></math></inline-formula>O<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>4</mn></msub></semantics></math></inline-formula> nanowires when BaTiO<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>3</mn></msub></semantics></math></inline-formula> is used as the shell material, effectively transforming them from hard to soft magnetic. This intriguing behavior is attributed to the magnetization reversal effect at the interface between ferromagnetic and paramagnetic regions, and it is also observed in NiFe<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2</mn></msub></semantics></math></inline-formula>O<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>4</mn></msub></semantics></math></inline-formula> and Fe<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2</mn></msub></semantics></math></inline-formula>O<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>3</mn></msub></semantics></math></inline-formula> nanowires. Surprisingly, introducing a GdBa<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2</mn></msub></semantics></math></inline-formula>Cu<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>3</mn></msub></semantics></math></inline-formula>O<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>7</mn></msub></semantics></math></inline-formula> shell induces a similar effect. Additionally, we employ magnetic impedance measurements on the coaxial nanowires, unveiling their potential for magnetic field sensing applications.https://www.mdpi.com/2673-6497/4/4/19electrospinningcore-shell structurecoaxial nanowireferritemagnetic reversal
spellingShingle Xian-Lin Zeng
Indujan Sivanesarajah
Uwe Hartmann
Conversion of Hard to Soft Magnetic Ferrite Nanowires by Paramagnetic Shielding
Solids
electrospinning
core-shell structure
coaxial nanowire
ferrite
magnetic reversal
title Conversion of Hard to Soft Magnetic Ferrite Nanowires by Paramagnetic Shielding
title_full Conversion of Hard to Soft Magnetic Ferrite Nanowires by Paramagnetic Shielding
title_fullStr Conversion of Hard to Soft Magnetic Ferrite Nanowires by Paramagnetic Shielding
title_full_unstemmed Conversion of Hard to Soft Magnetic Ferrite Nanowires by Paramagnetic Shielding
title_short Conversion of Hard to Soft Magnetic Ferrite Nanowires by Paramagnetic Shielding
title_sort conversion of hard to soft magnetic ferrite nanowires by paramagnetic shielding
topic electrospinning
core-shell structure
coaxial nanowire
ferrite
magnetic reversal
url https://www.mdpi.com/2673-6497/4/4/19
work_keys_str_mv AT xianlinzeng conversionofhardtosoftmagneticferritenanowiresbyparamagneticshielding
AT indujansivanesarajah conversionofhardtosoftmagneticferritenanowiresbyparamagneticshielding
AT uwehartmann conversionofhardtosoftmagneticferritenanowiresbyparamagneticshielding