Iron-catalyzed carboazidation of alkenes and alkynes
Carboazidation of alkenes and alkynes holds the promise to construct valuable, functionalized molecules. Here, the authors report a general and efficient iron-catalyzed carboazidation of both alkenes and alkynes enabled by t-butyl perbenzoate.
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2019-01-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-018-07985-2 |
| _version_ | 1818977702510592000 |
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| author | Haigen Xiong Nagarajan Ramkumar Mong-Feng Chiou Wujun Jian Yajun Li Ji-Hu Su Xinhao Zhang Hongli Bao |
| author_facet | Haigen Xiong Nagarajan Ramkumar Mong-Feng Chiou Wujun Jian Yajun Li Ji-Hu Su Xinhao Zhang Hongli Bao |
| author_sort | Haigen Xiong |
| collection | DOAJ |
| description | Carboazidation of alkenes and alkynes holds the promise to construct valuable, functionalized molecules. Here, the authors report a general and efficient iron-catalyzed carboazidation of both alkenes and alkynes enabled by t-butyl perbenzoate. |
| first_indexed | 2024-12-20T16:31:56Z |
| format | Article |
| id | doaj.art-20dbac7da9644b238e707ce2e645841b |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-20T16:31:56Z |
| publishDate | 2019-01-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-20dbac7da9644b238e707ce2e645841b2022-12-21T19:33:14ZengNature PortfolioNature Communications2041-17232019-01-011011710.1038/s41467-018-07985-2Iron-catalyzed carboazidation of alkenes and alkynesHaigen Xiong0Nagarajan Ramkumar1Mong-Feng Chiou2Wujun Jian3Yajun Li4Ji-Hu Su5Xinhao Zhang6Hongli Bao7Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, State Key Laboratory of Structural Chemistry, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesKey Laboratory of Coal to Ethylene Glycol and Its Related Technology, State Key Laboratory of Structural Chemistry, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesKey Laboratory of Coal to Ethylene Glycol and Its Related Technology, State Key Laboratory of Structural Chemistry, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesKey Laboratory of Coal to Ethylene Glycol and Its Related Technology, State Key Laboratory of Structural Chemistry, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesKey Laboratory of Coal to Ethylene Glycol and Its Related Technology, State Key Laboratory of Structural Chemistry, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesHefei National Laboratory for Physical Sciences at the Microscale and Department of Modern Physics, CAS Key Laboratory of Microscale Magnetic Resonance, University of Science and Technology of ChinaLab of Computational Chemistry and Drug Design, Key Laboratory of Chemical Genomics, Peking University Shenzhen Graduate SchoolKey Laboratory of Coal to Ethylene Glycol and Its Related Technology, State Key Laboratory of Structural Chemistry, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesCarboazidation of alkenes and alkynes holds the promise to construct valuable, functionalized molecules. Here, the authors report a general and efficient iron-catalyzed carboazidation of both alkenes and alkynes enabled by t-butyl perbenzoate.https://doi.org/10.1038/s41467-018-07985-2 |
| spellingShingle | Haigen Xiong Nagarajan Ramkumar Mong-Feng Chiou Wujun Jian Yajun Li Ji-Hu Su Xinhao Zhang Hongli Bao Iron-catalyzed carboazidation of alkenes and alkynes Nature Communications |
| title | Iron-catalyzed carboazidation of alkenes and alkynes |
| title_full | Iron-catalyzed carboazidation of alkenes and alkynes |
| title_fullStr | Iron-catalyzed carboazidation of alkenes and alkynes |
| title_full_unstemmed | Iron-catalyzed carboazidation of alkenes and alkynes |
| title_short | Iron-catalyzed carboazidation of alkenes and alkynes |
| title_sort | iron catalyzed carboazidation of alkenes and alkynes |
| url | https://doi.org/10.1038/s41467-018-07985-2 |
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