The effect of water-to-binder ratio (W/B) on pore structure of one-part alkali activated mortar

One-part alkali-activated materials (AAMs) are alternative cementitious materials to respond to the shortcoming of conventional two-part systems. Combining aluminosilicate precursor by-products with ordinary Portland cement (OPC) helps develop a robust performance. It can potentially be used as a pa...

Full description

Bibliographic Details
Main Authors: Eddy Yusslee, S. Beskhyroun
Format: Article
Language:English
Published: Elsevier 2023-01-01
Series:Heliyon
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2405844023001901
_version_ 1811173327829467136
author Eddy Yusslee
S. Beskhyroun
author_facet Eddy Yusslee
S. Beskhyroun
author_sort Eddy Yusslee
collection DOAJ
description One-part alkali-activated materials (AAMs) are alternative cementitious materials to respond to the shortcoming of conventional two-part systems. Combining aluminosilicate precursor by-products with ordinary Portland cement (OPC) helps develop a robust performance. It can potentially be used as a patching product for concrete repair materials.Mix design for the one-part AAMs in this report is formulated to ensure its application is according to the structural concrete repair materials Class R4, EN1504-3 specification. In addition, the lower alkalinity alkali activator employed is helpful for economic reasons and less harmful to handle. Furthermore, the addition of powdered admixture enhances the performance of hardened products for retarding effect, provides additional calcium for geopolymer reactions, and offers stable mechanical strength. Finally, an adequate water-to-binder (W/B) ratio has completed the mix design proportion and effectively activated the chemical reaction of the dry mixed ingredients in the geopolymerization process for binding purposes.In this study, the water-to-binder ratio was set in the range of 0.30, 0.35 and 0.40 for all mortar samples at constant mix design formulation and activated by low alkalinity of solid potassium carbonate (K2CO3). At 0.30 W/B ratio, the setting time is delayed to 120 min but shorter than other W/B ratios. Mechanical strength of the mortar increased over time up to 63 N/mm2 at 56 days of curing age, recorded low porosity level of 16%, minimal pore structure area of 17.374 m2/g and documented above 2.0 MPa of pull-off bonding strength that encounters restrained drying shrinkage and expansion impact at 56 days of age under different curing conditions.
first_indexed 2024-04-10T17:45:05Z
format Article
id doaj.art-2104b46b1229402dad214edbf0657467
institution Directory Open Access Journal
issn 2405-8440
language English
last_indexed 2024-04-10T17:45:05Z
publishDate 2023-01-01
publisher Elsevier
record_format Article
series Heliyon
spelling doaj.art-2104b46b1229402dad214edbf06574672023-02-03T05:00:01ZengElsevierHeliyon2405-84402023-01-0191e12983The effect of water-to-binder ratio (W/B) on pore structure of one-part alkali activated mortarEddy Yusslee0S. Beskhyroun1Corresponding author.; Auckland University of Technology (AUT), Auckland, 1010, New ZealandAuckland University of Technology (AUT), Auckland, 1010, New ZealandOne-part alkali-activated materials (AAMs) are alternative cementitious materials to respond to the shortcoming of conventional two-part systems. Combining aluminosilicate precursor by-products with ordinary Portland cement (OPC) helps develop a robust performance. It can potentially be used as a patching product for concrete repair materials.Mix design for the one-part AAMs in this report is formulated to ensure its application is according to the structural concrete repair materials Class R4, EN1504-3 specification. In addition, the lower alkalinity alkali activator employed is helpful for economic reasons and less harmful to handle. Furthermore, the addition of powdered admixture enhances the performance of hardened products for retarding effect, provides additional calcium for geopolymer reactions, and offers stable mechanical strength. Finally, an adequate water-to-binder (W/B) ratio has completed the mix design proportion and effectively activated the chemical reaction of the dry mixed ingredients in the geopolymerization process for binding purposes.In this study, the water-to-binder ratio was set in the range of 0.30, 0.35 and 0.40 for all mortar samples at constant mix design formulation and activated by low alkalinity of solid potassium carbonate (K2CO3). At 0.30 W/B ratio, the setting time is delayed to 120 min but shorter than other W/B ratios. Mechanical strength of the mortar increased over time up to 63 N/mm2 at 56 days of curing age, recorded low porosity level of 16%, minimal pore structure area of 17.374 m2/g and documented above 2.0 MPa of pull-off bonding strength that encounters restrained drying shrinkage and expansion impact at 56 days of age under different curing conditions.http://www.sciencedirect.com/science/article/pii/S2405844023001901MicrostructureScanning electron microscope (SEM)Dispersive X-Ray analysis (XRD)Calcium oxide (CaO)Superplasticizer (SP)
spellingShingle Eddy Yusslee
S. Beskhyroun
The effect of water-to-binder ratio (W/B) on pore structure of one-part alkali activated mortar
Heliyon
Microstructure
Scanning electron microscope (SEM)
Dispersive X-Ray analysis (XRD)
Calcium oxide (CaO)
Superplasticizer (SP)
title The effect of water-to-binder ratio (W/B) on pore structure of one-part alkali activated mortar
title_full The effect of water-to-binder ratio (W/B) on pore structure of one-part alkali activated mortar
title_fullStr The effect of water-to-binder ratio (W/B) on pore structure of one-part alkali activated mortar
title_full_unstemmed The effect of water-to-binder ratio (W/B) on pore structure of one-part alkali activated mortar
title_short The effect of water-to-binder ratio (W/B) on pore structure of one-part alkali activated mortar
title_sort effect of water to binder ratio w b on pore structure of one part alkali activated mortar
topic Microstructure
Scanning electron microscope (SEM)
Dispersive X-Ray analysis (XRD)
Calcium oxide (CaO)
Superplasticizer (SP)
url http://www.sciencedirect.com/science/article/pii/S2405844023001901
work_keys_str_mv AT eddyyusslee theeffectofwatertobinderratiowbonporestructureofonepartalkaliactivatedmortar
AT sbeskhyroun theeffectofwatertobinderratiowbonporestructureofonepartalkaliactivatedmortar
AT eddyyusslee effectofwatertobinderratiowbonporestructureofonepartalkaliactivatedmortar
AT sbeskhyroun effectofwatertobinderratiowbonporestructureofonepartalkaliactivatedmortar