High Humidity Response of Sol–Gel-Synthesized BiFeO<sub>3</sub> Ferroelectric Film

In this work, a BiFeO<sub>3</sub> film is prepared via a facile sol–gel method, and the effects of the relative humidity (RH) on the BiFeO<sub>3</sub> film in terms of capacitance, impedance and current–voltage (<i>I</i>–<i>V</i>) are explored. The cap...

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Main Authors: Yaming Zhang, Bingbing Li, Yanmin Jia
Format: Article
Language:English
Published: MDPI AG 2022-04-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/15/8/2932
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author Yaming Zhang
Bingbing Li
Yanmin Jia
author_facet Yaming Zhang
Bingbing Li
Yanmin Jia
author_sort Yaming Zhang
collection DOAJ
description In this work, a BiFeO<sub>3</sub> film is prepared via a facile sol–gel method, and the effects of the relative humidity (RH) on the BiFeO<sub>3</sub> film in terms of capacitance, impedance and current–voltage (<i>I</i>–<i>V</i>) are explored. The capacitance of the BiFeO<sub>3</sub> film increased from 25 to 1410 pF with the increase of RH from 30% to 90%. In particular, the impedance varied by more than two orders of magnitude as RH varied between 30% and 90% at 10 Hz, indicating a good hysteresis and response time. The mechanism underlying humidity sensitivity was analyzed by complex impedance spectroscopy. The adsorption of water molecules played key roles at low and high humidity, extending the potential application of ferroelectric BiFeO<sub>3</sub> films in humidity-sensitive devices.
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spelling doaj.art-21346cd17b504bf5a288a0f94be53be12023-12-03T13:39:44ZengMDPI AGMaterials1996-19442022-04-01158293210.3390/ma15082932High Humidity Response of Sol–Gel-Synthesized BiFeO<sub>3</sub> Ferroelectric FilmYaming Zhang0Bingbing Li1Yanmin Jia2School of Science, Xi’an University of Posts and Telecommunications, Xi’an 710048, ChinaSchool of Communication and Information Engineering, Xi’an University of Posts and Telecommunications, Xi’an 710048, ChinaSchool of Science, Xi’an University of Posts and Telecommunications, Xi’an 710048, ChinaIn this work, a BiFeO<sub>3</sub> film is prepared via a facile sol–gel method, and the effects of the relative humidity (RH) on the BiFeO<sub>3</sub> film in terms of capacitance, impedance and current–voltage (<i>I</i>–<i>V</i>) are explored. The capacitance of the BiFeO<sub>3</sub> film increased from 25 to 1410 pF with the increase of RH from 30% to 90%. In particular, the impedance varied by more than two orders of magnitude as RH varied between 30% and 90% at 10 Hz, indicating a good hysteresis and response time. The mechanism underlying humidity sensitivity was analyzed by complex impedance spectroscopy. The adsorption of water molecules played key roles at low and high humidity, extending the potential application of ferroelectric BiFeO<sub>3</sub> films in humidity-sensitive devices.https://www.mdpi.com/1996-1944/15/8/2932ferroelectricsBiFeO<sub>3</sub>humidity responsesol–gel preparation
spellingShingle Yaming Zhang
Bingbing Li
Yanmin Jia
High Humidity Response of Sol–Gel-Synthesized BiFeO<sub>3</sub> Ferroelectric Film
Materials
ferroelectrics
BiFeO<sub>3</sub>
humidity response
sol–gel preparation
title High Humidity Response of Sol–Gel-Synthesized BiFeO<sub>3</sub> Ferroelectric Film
title_full High Humidity Response of Sol–Gel-Synthesized BiFeO<sub>3</sub> Ferroelectric Film
title_fullStr High Humidity Response of Sol–Gel-Synthesized BiFeO<sub>3</sub> Ferroelectric Film
title_full_unstemmed High Humidity Response of Sol–Gel-Synthesized BiFeO<sub>3</sub> Ferroelectric Film
title_short High Humidity Response of Sol–Gel-Synthesized BiFeO<sub>3</sub> Ferroelectric Film
title_sort high humidity response of sol gel synthesized bifeo sub 3 sub ferroelectric film
topic ferroelectrics
BiFeO<sub>3</sub>
humidity response
sol–gel preparation
url https://www.mdpi.com/1996-1944/15/8/2932
work_keys_str_mv AT yamingzhang highhumidityresponseofsolgelsynthesizedbifeosub3subferroelectricfilm
AT bingbingli highhumidityresponseofsolgelsynthesizedbifeosub3subferroelectricfilm
AT yanminjia highhumidityresponseofsolgelsynthesizedbifeosub3subferroelectricfilm