Effect of Sugars on Gelation Kinetics of Gelatin Gels

We investigate the rheological behavior of aqueous solutions containing animal gelatin, sugars and polyols. The aim is to study how the gelation kinetics, transition temperatures and gel strengths of an aqueous gelatin solution can be affected by the progressive addition of co-solutes. Aqueous solut...

Full description

Bibliographic Details
Main Authors: Pietro Renato Avallone, Martina Romano, Andrea Sarrica, Marco Delmonte, Rossana Pasquino, Nino Grizzuti
Format: Article
Language:English
Published: MDPI AG 2022-05-01
Series:Fluids
Subjects:
Online Access:https://www.mdpi.com/2311-5521/7/5/163
_version_ 1797499886295318528
author Pietro Renato Avallone
Martina Romano
Andrea Sarrica
Marco Delmonte
Rossana Pasquino
Nino Grizzuti
author_facet Pietro Renato Avallone
Martina Romano
Andrea Sarrica
Marco Delmonte
Rossana Pasquino
Nino Grizzuti
author_sort Pietro Renato Avallone
collection DOAJ
description We investigate the rheological behavior of aqueous solutions containing animal gelatin, sugars and polyols. The aim is to study how the gelation kinetics, transition temperatures and gel strengths of an aqueous gelatin solution can be affected by the progressive addition of co-solutes. Aqueous solutions with a fixed mass percentage of gelatin of <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><mn>6.8</mn></mrow></semantics></math></inline-formula> wt% were prepared at various concentrations of sugars and polyols. Through Dynamic Temperature Ramp tests, performed at various ramp rates, and Dynamic Time Sweep and Dynamic Frequency Sweep tests, carried out at different temperatures, it was possible both to evaluate the transition temperatures and to monitor the gelation kinetics of the samples. It was found that the contribution of co-solutes positively affects both the gelation process and the thermal stability of the aqueous gelatin solution by reducing the gelation time and improving the mechanical properties of the gel in terms of network elasticity.
first_indexed 2024-03-10T03:54:52Z
format Article
id doaj.art-21364f1ffd684cf9831dcbde88cbc121
institution Directory Open Access Journal
issn 2311-5521
language English
last_indexed 2024-03-10T03:54:52Z
publishDate 2022-05-01
publisher MDPI AG
record_format Article
series Fluids
spelling doaj.art-21364f1ffd684cf9831dcbde88cbc1212023-11-23T10:57:56ZengMDPI AGFluids2311-55212022-05-017516310.3390/fluids7050163Effect of Sugars on Gelation Kinetics of Gelatin GelsPietro Renato Avallone0Martina Romano1Andrea Sarrica2Marco Delmonte3Rossana Pasquino4Nino Grizzuti5Department of Chemical, Materials, and Industrial Production Engineering, Federico II University, P.le Tecchio 80, 80125 Naples, ItalyPerfetti Van Melle, Lainate, 20045 Milan, ItalyPerfetti Van Melle, Lainate, 20045 Milan, ItalyPerfetti Van Melle, Lainate, 20045 Milan, ItalyDepartment of Chemical, Materials, and Industrial Production Engineering, Federico II University, P.le Tecchio 80, 80125 Naples, ItalyDepartment of Chemical, Materials, and Industrial Production Engineering, Federico II University, P.le Tecchio 80, 80125 Naples, ItalyWe investigate the rheological behavior of aqueous solutions containing animal gelatin, sugars and polyols. The aim is to study how the gelation kinetics, transition temperatures and gel strengths of an aqueous gelatin solution can be affected by the progressive addition of co-solutes. Aqueous solutions with a fixed mass percentage of gelatin of <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><mn>6.8</mn></mrow></semantics></math></inline-formula> wt% were prepared at various concentrations of sugars and polyols. Through Dynamic Temperature Ramp tests, performed at various ramp rates, and Dynamic Time Sweep and Dynamic Frequency Sweep tests, carried out at different temperatures, it was possible both to evaluate the transition temperatures and to monitor the gelation kinetics of the samples. It was found that the contribution of co-solutes positively affects both the gelation process and the thermal stability of the aqueous gelatin solution by reducing the gelation time and improving the mechanical properties of the gel in terms of network elasticity.https://www.mdpi.com/2311-5521/7/5/163gelatinsugarsviscoelasticitysol-gel transitiongel time
spellingShingle Pietro Renato Avallone
Martina Romano
Andrea Sarrica
Marco Delmonte
Rossana Pasquino
Nino Grizzuti
Effect of Sugars on Gelation Kinetics of Gelatin Gels
Fluids
gelatin
sugars
viscoelasticity
sol-gel transition
gel time
title Effect of Sugars on Gelation Kinetics of Gelatin Gels
title_full Effect of Sugars on Gelation Kinetics of Gelatin Gels
title_fullStr Effect of Sugars on Gelation Kinetics of Gelatin Gels
title_full_unstemmed Effect of Sugars on Gelation Kinetics of Gelatin Gels
title_short Effect of Sugars on Gelation Kinetics of Gelatin Gels
title_sort effect of sugars on gelation kinetics of gelatin gels
topic gelatin
sugars
viscoelasticity
sol-gel transition
gel time
url https://www.mdpi.com/2311-5521/7/5/163
work_keys_str_mv AT pietrorenatoavallone effectofsugarsongelationkineticsofgelatingels
AT martinaromano effectofsugarsongelationkineticsofgelatingels
AT andreasarrica effectofsugarsongelationkineticsofgelatingels
AT marcodelmonte effectofsugarsongelationkineticsofgelatingels
AT rossanapasquino effectofsugarsongelationkineticsofgelatingels
AT ninogrizzuti effectofsugarsongelationkineticsofgelatingels