Synthesis of Biscardanol as Key Intermediary in Preparation of Bistioxanthones

<p><em>The cashew nut shell liquid (CNSL) is an important source of phenolic compounds such as anacardic acids, cardols and cardanols. These compounds present many biological activities. The components of CNSL were isolated and purified by column chromatography. Cardanol was employed as...

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Main Authors: Glaucia Almeida Nunes, Dênis P. Lima, Ricardo V. Lima, Rosangela Silva Lopes
Format: Article
Language:English
Published: Universidade Federal de Mato Grosso do Sul 2012-06-01
Series:Orbital: The Electronic Journal of Chemistry
Subjects:
Online Access:http://orbital.ufms.br/index.php/Chemistry/article/view/349
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author Glaucia Almeida Nunes
Dênis P. Lima
Ricardo V. Lima
Rosangela Silva Lopes
author_facet Glaucia Almeida Nunes
Dênis P. Lima
Ricardo V. Lima
Rosangela Silva Lopes
author_sort Glaucia Almeida Nunes
collection DOAJ
description <p><em>The cashew nut shell liquid (CNSL) is an important source of phenolic compounds such as anacardic acids, cardols and cardanols. These compounds present many biological activities. The components of CNSL were isolated and purified by column chromatography. Cardanol was employed as starting material for a methathesis reaction making use of Grubbs 1<sup>st</sup> generation catalyst, under nitrogen atmosphere, in dichloromethane, heating at 50 <sup>o</sup>C and, magnetic stirring during 98 h. The product biscardanol is a key-intermediate for the synthesis of new bis thioxanthones.</em></p>
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spelling doaj.art-213ec567e7d442d0a7694cc4c53f744b2022-12-22T00:01:14ZengUniversidade Federal de Mato Grosso do SulOrbital: The Electronic Journal of Chemistry1984-64282012-06-0141232410.17807/orbital.v4i1.349119Synthesis of Biscardanol as Key Intermediary in Preparation of BistioxanthonesGlaucia Almeida Nunes0Dênis P. Lima1Ricardo V. Lima2Rosangela Silva Lopes3Centro de Ciências Exatas e Tecnologia, Universidade Federal de Mato Grosso do SulCentro de Ciências Exatas e Tecnologia, Universidade Federal de Mato Grosso do SulCentro de Ciências Exatas e Tecnologia, Universidade Federal de Mato Grosso do SulCentro de Ciências Exatas e Tecnologia, Universidade Federal de Mato Grosso do Sul<p><em>The cashew nut shell liquid (CNSL) is an important source of phenolic compounds such as anacardic acids, cardols and cardanols. These compounds present many biological activities. The components of CNSL were isolated and purified by column chromatography. Cardanol was employed as starting material for a methathesis reaction making use of Grubbs 1<sup>st</sup> generation catalyst, under nitrogen atmosphere, in dichloromethane, heating at 50 <sup>o</sup>C and, magnetic stirring during 98 h. The product biscardanol is a key-intermediate for the synthesis of new bis thioxanthones.</em></p>http://orbital.ufms.br/index.php/Chemistry/article/view/349cardanol1st generation grubbs catalystmetathesisbis thioxantones.
spellingShingle Glaucia Almeida Nunes
Dênis P. Lima
Ricardo V. Lima
Rosangela Silva Lopes
Synthesis of Biscardanol as Key Intermediary in Preparation of Bistioxanthones
Orbital: The Electronic Journal of Chemistry
cardanol
1st generation grubbs catalyst
metathesis
bis thioxantones.
title Synthesis of Biscardanol as Key Intermediary in Preparation of Bistioxanthones
title_full Synthesis of Biscardanol as Key Intermediary in Preparation of Bistioxanthones
title_fullStr Synthesis of Biscardanol as Key Intermediary in Preparation of Bistioxanthones
title_full_unstemmed Synthesis of Biscardanol as Key Intermediary in Preparation of Bistioxanthones
title_short Synthesis of Biscardanol as Key Intermediary in Preparation of Bistioxanthones
title_sort synthesis of biscardanol as key intermediary in preparation of bistioxanthones
topic cardanol
1st generation grubbs catalyst
metathesis
bis thioxantones.
url http://orbital.ufms.br/index.php/Chemistry/article/view/349
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AT rosangelasilvalopes synthesisofbiscardanolaskeyintermediaryinpreparationofbistioxanthones