Cristalização e taxa crítica de resfriamento para vitrificação do poli(sebacato de decametileno)
We synthesized Poly(decamethylene sebacate) - P10MS - and studied its overall crystallization rates in a range of temperatures using Differential Scanning Calorimetry in isothermal conditions, which enabled us to identify the crystallization mechanism by means of the Johnson-Mehl-Avrami-Kolmogorov e...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Sociedade Brasileira de Química
2003-01-01
|
| Series: | Química Nova |
| Subjects: | |
| Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422003000200011 |
| _version_ | 1819134472636858368 |
|---|---|
| author | Guimarães Luciana Maria Zanotto Edgar Dutra |
| author_facet | Guimarães Luciana Maria Zanotto Edgar Dutra |
| author_sort | Guimarães Luciana Maria |
| collection | DOAJ |
| description | We synthesized Poly(decamethylene sebacate) - P10MS - and studied its overall crystallization rates in a range of temperatures using Differential Scanning Calorimetry in isothermal conditions, which enabled us to identify the crystallization mechanism by means of the Johnson-Mehl-Avrami-Kolmogorov equation. The critical cooling rate (Rc) to vitrify the P10MS was determined using a non-isothermal method proposed by Barandiarán & Colmenero (BC). The value of Rc is around 50-250 K/s, which confirms the experimentally observed difficulty to vitrify this polymer. |
| first_indexed | 2024-12-22T10:03:44Z |
| format | Article |
| id | doaj.art-214492193ec946a789628234dbf0d3f7 |
| institution | Directory Open Access Journal |
| issn | 0100-4042 1678-7064 |
| language | English |
| last_indexed | 2024-12-22T10:03:44Z |
| publishDate | 2003-01-01 |
| publisher | Sociedade Brasileira de Química |
| record_format | Article |
| series | Química Nova |
| spelling | doaj.art-214492193ec946a789628234dbf0d3f72022-12-21T18:30:01ZengSociedade Brasileira de QuímicaQuímica Nova0100-40421678-70642003-01-01262202207Cristalização e taxa crítica de resfriamento para vitrificação do poli(sebacato de decametileno)Guimarães Luciana MariaZanotto Edgar DutraWe synthesized Poly(decamethylene sebacate) - P10MS - and studied its overall crystallization rates in a range of temperatures using Differential Scanning Calorimetry in isothermal conditions, which enabled us to identify the crystallization mechanism by means of the Johnson-Mehl-Avrami-Kolmogorov equation. The critical cooling rate (Rc) to vitrify the P10MS was determined using a non-isothermal method proposed by Barandiarán & Colmenero (BC). The value of Rc is around 50-250 K/s, which confirms the experimentally observed difficulty to vitrify this polymer.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422003000200011crystallizationcritical cooling ratepoly(decamethylene sebacate) |
| spellingShingle | Guimarães Luciana Maria Zanotto Edgar Dutra Cristalização e taxa crítica de resfriamento para vitrificação do poli(sebacato de decametileno) Química Nova crystallization critical cooling rate poly(decamethylene sebacate) |
| title | Cristalização e taxa crítica de resfriamento para vitrificação do poli(sebacato de decametileno) |
| title_full | Cristalização e taxa crítica de resfriamento para vitrificação do poli(sebacato de decametileno) |
| title_fullStr | Cristalização e taxa crítica de resfriamento para vitrificação do poli(sebacato de decametileno) |
| title_full_unstemmed | Cristalização e taxa crítica de resfriamento para vitrificação do poli(sebacato de decametileno) |
| title_short | Cristalização e taxa crítica de resfriamento para vitrificação do poli(sebacato de decametileno) |
| title_sort | cristalizacao e taxa critica de resfriamento para vitrificacao do poli sebacato de decametileno |
| topic | crystallization critical cooling rate poly(decamethylene sebacate) |
| url | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422003000200011 |
| work_keys_str_mv | AT guimaraeslucianamaria cristalizacaoetaxacriticaderesfriamentoparavitrificacaodopolisebacatodedecametileno AT zanottoedgardutra cristalizacaoetaxacriticaderesfriamentoparavitrificacaodopolisebacatodedecametileno |