Diethyl 2-amino-5-[(E)-(1-methyl-1H-pyrrol-2-yl)methylideneamino]thiophene-3,4-dicarboxylate
The structure of the title compound, C16H19N3O4S, shows the planes described by the thiophene and the pyrroles are twisted by 17.06 (4)°. Additionally, the structure shows the azomethine bond adopts the E configuration, while the pyrrole is disordered as a heterocycle flip...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810046775 |
| _version_ | 1818886970068172800 |
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| author | Stéphane Dufresne W. G. Skene |
| author_facet | Stéphane Dufresne W. G. Skene |
| author_sort | Stéphane Dufresne |
| collection | DOAJ |
| description | The structure of the title compound, C16H19N3O4S, shows the planes described by the thiophene and the pyrroles are twisted by 17.06 (4)°. Additionally, the structure shows the azomethine bond adopts the E configuration, while the pyrrole is disordered as a heterocycle flip [occupancy ratio 0.729 (5):0.271 (5)]. The three-dimensional network is well packed and involves N–H...O hydrogen bonding and π–π stacking [centroid–centroid distance = 4.294 (8) Å]. |
| first_indexed | 2024-12-19T16:29:47Z |
| format | Article |
| id | doaj.art-214e80324d844a47a14841a6553bbad8 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T16:29:47Z |
| publishDate | 2010-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-214e80324d844a47a14841a6553bbad82022-12-21T20:14:15ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612o3221o322110.1107/S1600536810046775Diethyl 2-amino-5-[(E)-(1-methyl-1H-pyrrol-2-yl)methylideneamino]thiophene-3,4-dicarboxylateStéphane DufresneW. G. SkeneThe structure of the title compound, C16H19N3O4S, shows the planes described by the thiophene and the pyrroles are twisted by 17.06 (4)°. Additionally, the structure shows the azomethine bond adopts the E configuration, while the pyrrole is disordered as a heterocycle flip [occupancy ratio 0.729 (5):0.271 (5)]. The three-dimensional network is well packed and involves N–H...O hydrogen bonding and π–π stacking [centroid–centroid distance = 4.294 (8) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536810046775 |
| spellingShingle | Stéphane Dufresne W. G. Skene Diethyl 2-amino-5-[(E)-(1-methyl-1H-pyrrol-2-yl)methylideneamino]thiophene-3,4-dicarboxylate Acta Crystallographica Section E |
| title | Diethyl 2-amino-5-[(E)-(1-methyl-1H-pyrrol-2-yl)methylideneamino]thiophene-3,4-dicarboxylate |
| title_full | Diethyl 2-amino-5-[(E)-(1-methyl-1H-pyrrol-2-yl)methylideneamino]thiophene-3,4-dicarboxylate |
| title_fullStr | Diethyl 2-amino-5-[(E)-(1-methyl-1H-pyrrol-2-yl)methylideneamino]thiophene-3,4-dicarboxylate |
| title_full_unstemmed | Diethyl 2-amino-5-[(E)-(1-methyl-1H-pyrrol-2-yl)methylideneamino]thiophene-3,4-dicarboxylate |
| title_short | Diethyl 2-amino-5-[(E)-(1-methyl-1H-pyrrol-2-yl)methylideneamino]thiophene-3,4-dicarboxylate |
| title_sort | diethyl 2 amino 5 e 1 methyl 1h pyrrol 2 yl methylideneamino thiophene 3 4 dicarboxylate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810046775 |
| work_keys_str_mv | AT stamp233phanedufresne diethyl2amino5e1methyl1hpyrrol2ylmethylideneaminothiophene34dicarboxylate AT wgskene diethyl2amino5e1methyl1hpyrrol2ylmethylideneaminothiophene34dicarboxylate |