An integrated analytical study of crayons from the original art materials collection of the MUNCH museum in Oslo
Abstract Among the artists’ materials of the nineteenth century, pastel crayons merit scientific interest since their early commercial formulations are mostly unknown and, until now, have been considerably less studied with respect to other contemporary painting materials. In this framework, researc...
Main Authors: | , , , , , , , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Nature Portfolio
2021-03-01
|
Series: | Scientific Reports |
Online Access: | https://doi.org/10.1038/s41598-021-86031-6 |
_version_ | 1818855909214912512 |
---|---|
author | Jacopo La Nasa Brenda Doherty Francesca Rosi Chiara Braccini Frederique T. H. Broers Ilaria Degano Jordi Moles Matinero Costanza Miliani Francesca Modugno Francesca Sabatini Irina Crina Anca Sandu Laura Cartechini |
author_facet | Jacopo La Nasa Brenda Doherty Francesca Rosi Chiara Braccini Frederique T. H. Broers Ilaria Degano Jordi Moles Matinero Costanza Miliani Francesca Modugno Francesca Sabatini Irina Crina Anca Sandu Laura Cartechini |
author_sort | Jacopo La Nasa |
collection | DOAJ |
description | Abstract Among the artists’ materials of the nineteenth century, pastel crayons merit scientific interest since their early commercial formulations are mostly unknown and, until now, have been considerably less studied with respect to other contemporary painting materials. In this framework, research herein reports the results of a comprehensive multi-analytical study of 44 pastel crayons of two recognized brands (LeFranc and Dr. F. Schoenfeld) from the Munch museum collection of original materials belonging to Edvard Munch. The integrated use of complementary spectroscopic and hyphenated mass-spectrometry techniques allowed the compositional profiles of the crayons to be traced providing the identification of the inorganic and organic pigments, the fillers/extenders and the binders. All crayons resulted to be oil- based and the binder was identified to be a mixture of a drying oil (safflower or linseed oil), palm oil or Japan wax and beeswax. Among others, pigments such as ultramarine, chrome yellows, Prussian blue, manganese violet, viridian and madder lake have been identified. A significant alignment in formulations of the brands was observed with the only exception of the greens which showed distinctive pigment and filler compositions. The analytical information provided for these commercial artists’ materials will be of great interest for academia, museum and other institutions hosting art collections dating from the same period and it will be used by the Munch museum to draw proper conservation strategies of its own artwork collections. |
first_indexed | 2024-12-19T08:16:05Z |
format | Article |
id | doaj.art-2154751183ae4ee3bc8bda0b38689122 |
institution | Directory Open Access Journal |
issn | 2045-2322 |
language | English |
last_indexed | 2024-12-19T08:16:05Z |
publishDate | 2021-03-01 |
publisher | Nature Portfolio |
record_format | Article |
series | Scientific Reports |
spelling | doaj.art-2154751183ae4ee3bc8bda0b386891222022-12-21T20:29:30ZengNature PortfolioScientific Reports2045-23222021-03-0111111310.1038/s41598-021-86031-6An integrated analytical study of crayons from the original art materials collection of the MUNCH museum in OsloJacopo La Nasa0Brenda Doherty1Francesca Rosi2Chiara Braccini3Frederique T. H. Broers4Ilaria Degano5Jordi Moles Matinero6Costanza Miliani7Francesca Modugno8Francesca Sabatini9Irina Crina Anca Sandu10Laura Cartechini11Department of Chemistry and Industrial Chemistry, University of PisaIstituto CNR di Scienze e Tecnologie Chimiche “G.Natta” CNR-SCITECIstituto CNR di Scienze e Tecnologie Chimiche “G.Natta” CNR-SCITECDepartment of Chemistry and Industrial Chemistry, University of PisaIstituto CNR di Scienze e Tecnologie Chimiche “G.Natta” CNR-SCITECDepartment of Chemistry and Industrial Chemistry, University of PisaIstituto CNR di Scienze e Tecnologie Chimiche “G.Natta” CNR-SCITECIstituto CNR per le Scienze del Patrimonio Culturale (CNR-ISPC)Department of Chemistry and Industrial Chemistry, University of PisaDepartment of Chemistry and Industrial Chemistry, University of PisaDepartment of Collection Care and Management, MUNCHIstituto CNR di Scienze e Tecnologie Chimiche “G.Natta” CNR-SCITECAbstract Among the artists’ materials of the nineteenth century, pastel crayons merit scientific interest since their early commercial formulations are mostly unknown and, until now, have been considerably less studied with respect to other contemporary painting materials. In this framework, research herein reports the results of a comprehensive multi-analytical study of 44 pastel crayons of two recognized brands (LeFranc and Dr. F. Schoenfeld) from the Munch museum collection of original materials belonging to Edvard Munch. The integrated use of complementary spectroscopic and hyphenated mass-spectrometry techniques allowed the compositional profiles of the crayons to be traced providing the identification of the inorganic and organic pigments, the fillers/extenders and the binders. All crayons resulted to be oil- based and the binder was identified to be a mixture of a drying oil (safflower or linseed oil), palm oil or Japan wax and beeswax. Among others, pigments such as ultramarine, chrome yellows, Prussian blue, manganese violet, viridian and madder lake have been identified. A significant alignment in formulations of the brands was observed with the only exception of the greens which showed distinctive pigment and filler compositions. The analytical information provided for these commercial artists’ materials will be of great interest for academia, museum and other institutions hosting art collections dating from the same period and it will be used by the Munch museum to draw proper conservation strategies of its own artwork collections.https://doi.org/10.1038/s41598-021-86031-6 |
spellingShingle | Jacopo La Nasa Brenda Doherty Francesca Rosi Chiara Braccini Frederique T. H. Broers Ilaria Degano Jordi Moles Matinero Costanza Miliani Francesca Modugno Francesca Sabatini Irina Crina Anca Sandu Laura Cartechini An integrated analytical study of crayons from the original art materials collection of the MUNCH museum in Oslo Scientific Reports |
title | An integrated analytical study of crayons from the original art materials collection of the MUNCH museum in Oslo |
title_full | An integrated analytical study of crayons from the original art materials collection of the MUNCH museum in Oslo |
title_fullStr | An integrated analytical study of crayons from the original art materials collection of the MUNCH museum in Oslo |
title_full_unstemmed | An integrated analytical study of crayons from the original art materials collection of the MUNCH museum in Oslo |
title_short | An integrated analytical study of crayons from the original art materials collection of the MUNCH museum in Oslo |
title_sort | integrated analytical study of crayons from the original art materials collection of the munch museum in oslo |
url | https://doi.org/10.1038/s41598-021-86031-6 |
work_keys_str_mv | AT jacopolanasa anintegratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo AT brendadoherty anintegratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo AT francescarosi anintegratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo AT chiarabraccini anintegratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo AT frederiquethbroers anintegratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo AT ilariadegano anintegratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo AT jordimolesmatinero anintegratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo AT costanzamiliani anintegratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo AT francescamodugno anintegratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo AT francescasabatini anintegratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo AT irinacrinaancasandu anintegratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo AT lauracartechini anintegratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo AT jacopolanasa integratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo AT brendadoherty integratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo AT francescarosi integratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo AT chiarabraccini integratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo AT frederiquethbroers integratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo AT ilariadegano integratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo AT jordimolesmatinero integratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo AT costanzamiliani integratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo AT francescamodugno integratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo AT francescasabatini integratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo AT irinacrinaancasandu integratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo AT lauracartechini integratedanalyticalstudyofcrayonsfromtheoriginalartmaterialscollectionofthemunchmuseuminoslo |