Atmospheric Plasma Deposition of SiO2 Films for Adhesion Promoting Layers on Titanium

This paper evaluates the deposition of silica layers at atmospheric pressure as a pretreatment for the structural bonding of titanium (Ti6Al4V, Ti15V3Cr3Sn3Al) in comparison to an anodizing process (NaTESi process). The SiO2 film was deposited using the LARGE plasma source, a linearly extended DC ar...

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Bibliographic Details
Main Authors: Liliana Kotte, Jana Haag, Tobias Mertens, Stefan Kaskel
Format: Article
Language:English
Published: MDPI AG 2014-12-01
Series:Metals
Subjects:
Online Access:http://www.mdpi.com/2075-4701/4/4/639
Description
Summary:This paper evaluates the deposition of silica layers at atmospheric pressure as a pretreatment for the structural bonding of titanium (Ti6Al4V, Ti15V3Cr3Sn3Al) in comparison to an anodizing process (NaTESi process). The SiO2 film was deposited using the LARGE plasma source, a linearly extended DC arc plasma source and applying hexamethyldisiloxane (HMDSO) as a precursor. The morphology of the surface was analyzed by means of SEM, while the characterization of the chemical composition of deposited plasma layers was done by XPS and FTIR. The long-term durability of bonded samples was evaluated by means of a wedge test in hot/wet condition. The almost stoichiometric SiO2 film features a good long-term stability and a high bonding strength compared to the films produced with the wet-chemical NaTESi process.
ISSN:2075-4701