Direct evidence for metallic mercury causing photo-induced darkening of red cinnabar tempera paints

Photo-induced darkening of red cinnabar (α-HgS) often dramatically changes the appearance of artworks, but the reduction mechanism of Hg2+ remains unclear. Here, the authors propose an alternative pathway for the blackening reaction of cinnabar, considering its semiconductor properties and pigment-b...

Full description

Bibliographic Details
Main Authors: Kerstin Elert, Manuel Pérez Mendoza, Carolina Cardell
Format: Article
Language:English
Published: Nature Portfolio 2021-12-01
Series:Communications Chemistry
Online Access:https://doi.org/10.1038/s42004-021-00610-2
_version_ 1818701476159029248
author Kerstin Elert
Manuel Pérez Mendoza
Carolina Cardell
author_facet Kerstin Elert
Manuel Pérez Mendoza
Carolina Cardell
author_sort Kerstin Elert
collection DOAJ
description Photo-induced darkening of red cinnabar (α-HgS) often dramatically changes the appearance of artworks, but the reduction mechanism of Hg2+ remains unclear. Here, the authors propose an alternative pathway for the blackening reaction of cinnabar, considering its semiconductor properties and pigment-binder interactions
first_indexed 2024-12-17T15:21:27Z
format Article
id doaj.art-218ca057b86a48dca3c3e8ce8b063f15
institution Directory Open Access Journal
issn 2399-3669
language English
last_indexed 2024-12-17T15:21:27Z
publishDate 2021-12-01
publisher Nature Portfolio
record_format Article
series Communications Chemistry
spelling doaj.art-218ca057b86a48dca3c3e8ce8b063f152022-12-21T21:43:24ZengNature PortfolioCommunications Chemistry2399-36692021-12-014111010.1038/s42004-021-00610-2Direct evidence for metallic mercury causing photo-induced darkening of red cinnabar tempera paintsKerstin Elert0Manuel Pérez Mendoza1Carolina Cardell2Department of Mineralogy and Petrology, University of GranadaDepartment of Inorganic Chemistry, University of GranadaDepartment of Mineralogy and Petrology, University of GranadaPhoto-induced darkening of red cinnabar (α-HgS) often dramatically changes the appearance of artworks, but the reduction mechanism of Hg2+ remains unclear. Here, the authors propose an alternative pathway for the blackening reaction of cinnabar, considering its semiconductor properties and pigment-binder interactionshttps://doi.org/10.1038/s42004-021-00610-2
spellingShingle Kerstin Elert
Manuel Pérez Mendoza
Carolina Cardell
Direct evidence for metallic mercury causing photo-induced darkening of red cinnabar tempera paints
Communications Chemistry
title Direct evidence for metallic mercury causing photo-induced darkening of red cinnabar tempera paints
title_full Direct evidence for metallic mercury causing photo-induced darkening of red cinnabar tempera paints
title_fullStr Direct evidence for metallic mercury causing photo-induced darkening of red cinnabar tempera paints
title_full_unstemmed Direct evidence for metallic mercury causing photo-induced darkening of red cinnabar tempera paints
title_short Direct evidence for metallic mercury causing photo-induced darkening of red cinnabar tempera paints
title_sort direct evidence for metallic mercury causing photo induced darkening of red cinnabar tempera paints
url https://doi.org/10.1038/s42004-021-00610-2
work_keys_str_mv AT kerstinelert directevidenceformetallicmercurycausingphotoinduceddarkeningofredcinnabartemperapaints
AT manuelperezmendoza directevidenceformetallicmercurycausingphotoinduceddarkeningofredcinnabartemperapaints
AT carolinacardell directevidenceformetallicmercurycausingphotoinduceddarkeningofredcinnabartemperapaints