Solidification microstructure characteristics of Cu–Pb alloy by ECP treatment

The effects of high-density electric current pulse (ECP) treatment on the solidification of Cu–37.4 wt% Pb monotectic alloy melt were investigated. Compared to the method of molten glass purification combined with cyclic superheating, ECP treatment created finer microstructures of Cu–Pb alloys, with...

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Main Authors: Ma Teng, Sun Xiaosi, Ning Yanan, Hao Weixin
Format: Article
Language:English
Published: De Gruyter 2021-12-01
Series:High Temperature Materials and Processes
Subjects:
Online Access:https://doi.org/10.1515/htmp-2021-0039
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author Ma Teng
Sun Xiaosi
Ning Yanan
Hao Weixin
author_facet Ma Teng
Sun Xiaosi
Ning Yanan
Hao Weixin
author_sort Ma Teng
collection DOAJ
description The effects of high-density electric current pulse (ECP) treatment on the solidification of Cu–37.4 wt% Pb monotectic alloy melt were investigated. Compared to the method of molten glass purification combined with cyclic superheating, ECP treatment created finer microstructures of Cu–Pb alloys, with more homogeneous distribution of the Pb phase in the matrix. This phenomenon can be explained by the cluster theory for liquid metals and the non-equilibrium diffusion theory. First, ECP treatment could cause the fission of larger atomic clusters to increase the undercooling that enabled a large number of smaller clusters to grow and reach the critical nucleation radius. Second, ECP treatment could reduce the diffusion energy barrier to enhance the non-equilibrium diffusion of solute atoms and suppress the segregation of Pb.
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spelling doaj.art-219032a83b4446afb02f0440ac21e1932022-12-21T19:24:08ZengDe GruyterHigh Temperature Materials and Processes2191-03242021-12-0140138238810.1515/htmp-2021-0039Solidification microstructure characteristics of Cu–Pb alloy by ECP treatmentMa Teng0Sun Xiaosi1Ning Yanan2Hao Weixin3Department of Mathematics, Jinzhong University, Jinzhong 030619, Shanxi, ChinaDepartment of Metallurgy and Environmental Engineering, Shanxi Engineering Vocational College, Taiyuan 030002, Shanxi, ChinaSchool of Mathematical Sciences, Shanxi University, Taiyuan 030006, ChinaSchool of Materials Science and Engineering, Taiyuan University of Science and Technology, Taiyuan 030024, ChinaThe effects of high-density electric current pulse (ECP) treatment on the solidification of Cu–37.4 wt% Pb monotectic alloy melt were investigated. Compared to the method of molten glass purification combined with cyclic superheating, ECP treatment created finer microstructures of Cu–Pb alloys, with more homogeneous distribution of the Pb phase in the matrix. This phenomenon can be explained by the cluster theory for liquid metals and the non-equilibrium diffusion theory. First, ECP treatment could cause the fission of larger atomic clusters to increase the undercooling that enabled a large number of smaller clusters to grow and reach the critical nucleation radius. Second, ECP treatment could reduce the diffusion energy barrier to enhance the non-equilibrium diffusion of solute atoms and suppress the segregation of Pb.https://doi.org/10.1515/htmp-2021-0039electric current pulseundercoolinggrain refinementsolidification structurecu–37.4 wt% pb alloy
spellingShingle Ma Teng
Sun Xiaosi
Ning Yanan
Hao Weixin
Solidification microstructure characteristics of Cu–Pb alloy by ECP treatment
High Temperature Materials and Processes
electric current pulse
undercooling
grain refinement
solidification structure
cu–37.4 wt% pb alloy
title Solidification microstructure characteristics of Cu–Pb alloy by ECP treatment
title_full Solidification microstructure characteristics of Cu–Pb alloy by ECP treatment
title_fullStr Solidification microstructure characteristics of Cu–Pb alloy by ECP treatment
title_full_unstemmed Solidification microstructure characteristics of Cu–Pb alloy by ECP treatment
title_short Solidification microstructure characteristics of Cu–Pb alloy by ECP treatment
title_sort solidification microstructure characteristics of cu pb alloy by ecp treatment
topic electric current pulse
undercooling
grain refinement
solidification structure
cu–37.4 wt% pb alloy
url https://doi.org/10.1515/htmp-2021-0039
work_keys_str_mv AT mateng solidificationmicrostructurecharacteristicsofcupballoybyecptreatment
AT sunxiaosi solidificationmicrostructurecharacteristicsofcupballoybyecptreatment
AT ningyanan solidificationmicrostructurecharacteristicsofcupballoybyecptreatment
AT haoweixin solidificationmicrostructurecharacteristicsofcupballoybyecptreatment