Water as dispersion medium to fabricate homogeneous nano-hectorite solid-state electrolyte for suppressing lithium dendrite
The rational design of green chemical, low-cost, and highly efficient solid-state electrolytes for Li-metal anode is a promising but still challenging strategy for preventing Li dendrite growth and developing safe and ultralong cycle life Li-metal batteries. Herein, a homogeneous composite solid pol...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2024-03-01
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| Series: | Journal of Materiomics |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2352847823001429 |
| _version_ | 1797292872733556736 |
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| author | Xin Pei Wenfei Wei Gang He |
| author_facet | Xin Pei Wenfei Wei Gang He |
| author_sort | Xin Pei |
| collection | DOAJ |
| description | The rational design of green chemical, low-cost, and highly efficient solid-state electrolytes for Li-metal anode is a promising but still challenging strategy for preventing Li dendrite growth and developing safe and ultralong cycle life Li-metal batteries. Herein, a homogeneous composite solid polymer electrolyte (CSPE) is fabricated with water as the ideal dispersion medium, hectorite (Ht) as nanofiller, and poly (ethylene oxide) (PEO) as the matrix, to guide uniform Li plating/stripping. Benefiting from the merit of Ht can form uniformly dispersed nanosheets in water, the obtained CSPE inheres to a low melting point, robust mechanical property, and high Li+ transference number. Moreover, the fabricated Li symmetric battery using PEO-Ht-LiClO4 CSPE keeps cycling steadily for 4 000 h. The well demonstrated water-based CSPE paves the way for developing low-cost, environmentally friendly, and safe solid-state electrolytes for Li-metal batteries. |
| first_indexed | 2024-03-07T20:04:46Z |
| format | Article |
| id | doaj.art-21cb9c07e3a54739a15213b840a7ea19 |
| institution | Directory Open Access Journal |
| issn | 2352-8478 |
| language | English |
| last_indexed | 2024-03-07T20:04:46Z |
| publishDate | 2024-03-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Journal of Materiomics |
| spelling | doaj.art-21cb9c07e3a54739a15213b840a7ea192024-02-28T05:13:38ZengElsevierJournal of Materiomics2352-84782024-03-01102463470Water as dispersion medium to fabricate homogeneous nano-hectorite solid-state electrolyte for suppressing lithium dendriteXin Pei0Wenfei Wei1Gang He2Xinjiang Institute of Technology, Xinjiang, 843100, China; Engineering Research Center of Nano-Geomaterials of Ministry of Education, Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan, 430074, ChinaKey Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining, Qinghai, 810008, China; Corresponding author.Xinjiang Institute of Technology, Xinjiang, 843100, China; Engineering Research Center of Nano-Geomaterials of Ministry of Education, Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan, 430074, China; Corresponding author. Xinjiang Institute of Technology, Xinjiang 843100, China.The rational design of green chemical, low-cost, and highly efficient solid-state electrolytes for Li-metal anode is a promising but still challenging strategy for preventing Li dendrite growth and developing safe and ultralong cycle life Li-metal batteries. Herein, a homogeneous composite solid polymer electrolyte (CSPE) is fabricated with water as the ideal dispersion medium, hectorite (Ht) as nanofiller, and poly (ethylene oxide) (PEO) as the matrix, to guide uniform Li plating/stripping. Benefiting from the merit of Ht can form uniformly dispersed nanosheets in water, the obtained CSPE inheres to a low melting point, robust mechanical property, and high Li+ transference number. Moreover, the fabricated Li symmetric battery using PEO-Ht-LiClO4 CSPE keeps cycling steadily for 4 000 h. The well demonstrated water-based CSPE paves the way for developing low-cost, environmentally friendly, and safe solid-state electrolytes for Li-metal batteries.http://www.sciencedirect.com/science/article/pii/S2352847823001429WaterSolid-state electrolytesHomogeneousHectoriteLi-metal battery |
| spellingShingle | Xin Pei Wenfei Wei Gang He Water as dispersion medium to fabricate homogeneous nano-hectorite solid-state electrolyte for suppressing lithium dendrite Journal of Materiomics Water Solid-state electrolytes Homogeneous Hectorite Li-metal battery |
| title | Water as dispersion medium to fabricate homogeneous nano-hectorite solid-state electrolyte for suppressing lithium dendrite |
| title_full | Water as dispersion medium to fabricate homogeneous nano-hectorite solid-state electrolyte for suppressing lithium dendrite |
| title_fullStr | Water as dispersion medium to fabricate homogeneous nano-hectorite solid-state electrolyte for suppressing lithium dendrite |
| title_full_unstemmed | Water as dispersion medium to fabricate homogeneous nano-hectorite solid-state electrolyte for suppressing lithium dendrite |
| title_short | Water as dispersion medium to fabricate homogeneous nano-hectorite solid-state electrolyte for suppressing lithium dendrite |
| title_sort | water as dispersion medium to fabricate homogeneous nano hectorite solid state electrolyte for suppressing lithium dendrite |
| topic | Water Solid-state electrolytes Homogeneous Hectorite Li-metal battery |
| url | http://www.sciencedirect.com/science/article/pii/S2352847823001429 |
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