Crystal structure of (E)-3-{[2-(2,4-dichlorobenzylidene)hydrazin-1-yl]carbonyl}pyridinium chloride trihydrate

In the title hydrated salt, C13H10Cl2N3O+·Cl−·3H2O, the organic cation exhibits a dihedral angle of 8.26 (14)° between the mean planes of the pyridinium and benzene rings, and dihedral angles of 8.70 (15) and 15.93 (5)° between the mean planes of the hydrazide group and the benzene and pyridinium ri...

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Main Authors: J. Josephine Novina, G. Vasuki, M. Suresh, M. Syed Ali Padusha
Format: Article
Language:English
Published: International Union of Crystallography 2015-02-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015000286
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author J. Josephine Novina
G. Vasuki
M. Suresh
M. Syed Ali Padusha
author_facet J. Josephine Novina
G. Vasuki
M. Suresh
M. Syed Ali Padusha
author_sort J. Josephine Novina
collection DOAJ
description In the title hydrated salt, C13H10Cl2N3O+·Cl−·3H2O, the organic cation exhibits a dihedral angle of 8.26 (14)° between the mean planes of the pyridinium and benzene rings, and dihedral angles of 8.70 (15) and 15.93 (5)° between the mean planes of the hydrazide group and the benzene and pyridinium rings, respectively. In the crystal, N—H...O, N—H...Cl, C—H...O, C—H...Cl, O—H...O, O—H...N and O—H...Cl hydrogen bonds link the complex cations, chloride anions and solvent water molecules into a three-dimensional network.
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spelling doaj.art-21d0d8f2cf2744fdb1c2229c061634192022-12-22T04:06:24ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-02-01712o105o10610.1107/S2056989015000286bq2398Crystal structure of (E)-3-{[2-(2,4-dichlorobenzylidene)hydrazin-1-yl]carbonyl}pyridinium chloride trihydrateJ. Josephine Novina0G. Vasuki1M. Suresh2M. Syed Ali Padusha3Department of Physics, Idhaya College for Women, Kumbakonam 1, IndiaDepartment of Physics, Kunthavai Naachiar Govt. Arts College (W) (Autonomous), Thanjavur 7, IndiaPG & Research Department of Chemistry, Jamal Mohamed College, Tiruchirappalli 20, IndiaPG & Research Department of Chemistry, Jamal Mohamed College, Tiruchirappalli 20, IndiaIn the title hydrated salt, C13H10Cl2N3O+·Cl−·3H2O, the organic cation exhibits a dihedral angle of 8.26 (14)° between the mean planes of the pyridinium and benzene rings, and dihedral angles of 8.70 (15) and 15.93 (5)° between the mean planes of the hydrazide group and the benzene and pyridinium rings, respectively. In the crystal, N—H...O, N—H...Cl, C—H...O, C—H...Cl, O—H...O, O—H...N and O—H...Cl hydrogen bonds link the complex cations, chloride anions and solvent water molecules into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S2056989015000286crystals structurepyridiniumhydrazide grouphydrogen bonds
spellingShingle J. Josephine Novina
G. Vasuki
M. Suresh
M. Syed Ali Padusha
Crystal structure of (E)-3-{[2-(2,4-dichlorobenzylidene)hydrazin-1-yl]carbonyl}pyridinium chloride trihydrate
Acta Crystallographica Section E: Crystallographic Communications
crystals structure
pyridinium
hydrazide group
hydrogen bonds
title Crystal structure of (E)-3-{[2-(2,4-dichlorobenzylidene)hydrazin-1-yl]carbonyl}pyridinium chloride trihydrate
title_full Crystal structure of (E)-3-{[2-(2,4-dichlorobenzylidene)hydrazin-1-yl]carbonyl}pyridinium chloride trihydrate
title_fullStr Crystal structure of (E)-3-{[2-(2,4-dichlorobenzylidene)hydrazin-1-yl]carbonyl}pyridinium chloride trihydrate
title_full_unstemmed Crystal structure of (E)-3-{[2-(2,4-dichlorobenzylidene)hydrazin-1-yl]carbonyl}pyridinium chloride trihydrate
title_short Crystal structure of (E)-3-{[2-(2,4-dichlorobenzylidene)hydrazin-1-yl]carbonyl}pyridinium chloride trihydrate
title_sort crystal structure of e 3 2 2 4 dichlorobenzylidene hydrazin 1 yl carbonyl pyridinium chloride trihydrate
topic crystals structure
pyridinium
hydrazide group
hydrogen bonds
url http://scripts.iucr.org/cgi-bin/paper?S2056989015000286
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AT msuresh crystalstructureofe3224dichlorobenzylidenehydrazin1ylcarbonylpyridiniumchloridetrihydrate
AT msyedalipadusha crystalstructureofe3224dichlorobenzylidenehydrazin1ylcarbonylpyridiniumchloridetrihydrate