Phase Transition Field Effect Transistor Observed in an <i>α</i>-(BEDT-TTF)<sub>2</sub>I<sub>3</sub> Single Crystal

The metal–insulator transition induced by the gate electric field in the charge order phase of the <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mi>α</mi></semantics></math></inline-formu...

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Bibliographic Details
Main Authors: Ryosuke Ando, Ryo Watanuki, Kazuhiro Kudo, Hyuma Masu, Masatoshi Sakai
Format: Article
Language:English
Published: MDPI AG 2023-08-01
Series:Solids
Subjects:
Online Access:https://www.mdpi.com/2673-6497/4/3/13
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Summary:The metal–insulator transition induced by the gate electric field in the charge order phase of the <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mi>α</mi></semantics></math></inline-formula>-(BEDT-TTF)<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2</mn></msub></semantics></math></inline-formula>I<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>3</mn></msub></semantics></math></inline-formula> single-crystal field-effect transistor (FET) structure was clearly observed near the phase transition temperature. An abrupt increase in the electrical conductance induced by the applied gate electric field was evident, which corresponds to the partial dissolution of the charge order phase triggered by the gate electric field. The estimated nominal dissolved charge order region (i.e., the gate-induced metallic region) was overestimated in 130–150 K, suggesting additional effects such as Joule heating. On the other hand, in the lower temperature region below 120 K, the corresponding dissolved charge order was several monolayers of BEDT-TTF, suggesting that it is possible to dissolve the charge order phase within the bistable temperature region.
ISSN:2673-6497