Metal-Containing Zinc Phosphate EDI Zeolites Synthesized by Sol–gel Assisted Hydrothermal Method
Three different metal-containing zinc phosphate, [C<sub>3</sub>H<sub>12</sub>N<sub>2</sub>][Zn<sub>0.5</sub>Fe<sub>1.5</sub>(PO<sub>4</sub>)<sub>2</sub>] (1), [C<sub>3</sub>H<sub>12</sub>N<...
| Main Authors: | , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2020-04-01
|
| Series: | Minerals |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2075-163X/10/5/391 |
| _version_ | 1797569397630435328 |
|---|---|
| author | Xuelei Wang Zhaojun Dong Qiufeng Wang Chao Meng Weibin Zhuang Jiyuan Liu Ying Song Yuxin Jin Shaobin Yang |
| author_facet | Xuelei Wang Zhaojun Dong Qiufeng Wang Chao Meng Weibin Zhuang Jiyuan Liu Ying Song Yuxin Jin Shaobin Yang |
| author_sort | Xuelei Wang |
| collection | DOAJ |
| description | Three different metal-containing zinc phosphate, [C<sub>3</sub>H<sub>12</sub>N<sub>2</sub>][Zn<sub>0.5</sub>Fe<sub>1.5</sub>(PO<sub>4</sub>)<sub>2</sub>] (1), [C<sub>3</sub>H<sub>12</sub>N<sub>2</sub>][Zn<sub>0.67</sub>Co<sub>1.33</sub>(PO<sub>4</sub>)<sub>2</sub>] (2) and [C<sub>3</sub>H<sub>12</sub>N<sub>2</sub>][Zn<sub>0.67</sub>Ni<sub>1.33</sub>(PO<sub>4</sub>)<sub>2</sub>] (3) with EDI topology were prepared by sol–gel assisted hydrothermal method. The advantages of this method are lower synthesis temperature and uniform mixing. The crystalline metal-containing zinc phosphate zeolites exhibit a variety of SEM morphologies because of the entanglement of three different metal ions. The zinc ions in the zinc phosphate EDI molecular sieve were partially substituted by Fe, Co and Ni ions. The ICP analysis shows that the metal ratios of Zn/M are 1/3, 1/2 and 1/2. Variable temperature susceptibility was measured on powder samples in the range 2–300 K. All three M-EDI molecular sieves exhibit antiferromagnetic properties. In addition, they were analyzed by XRD, CHN, IR and TG. |
| first_indexed | 2024-03-10T20:11:09Z |
| format | Article |
| id | doaj.art-21e85e37f67f4754b9dd277b1d6f3f6d |
| institution | Directory Open Access Journal |
| issn | 2075-163X |
| language | English |
| last_indexed | 2024-03-10T20:11:09Z |
| publishDate | 2020-04-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Minerals |
| spelling | doaj.art-21e85e37f67f4754b9dd277b1d6f3f6d2023-11-19T22:55:23ZengMDPI AGMinerals2075-163X2020-04-0110539110.3390/min10050391Metal-Containing Zinc Phosphate EDI Zeolites Synthesized by Sol–gel Assisted Hydrothermal MethodXuelei Wang0Zhaojun Dong1Qiufeng Wang2Chao Meng3Weibin Zhuang4Jiyuan Liu5Ying Song6Yuxin Jin7Shaobin Yang8College of Materials Science and Engineering, Liaoning Technical University, Fuxin 123000, ChinaCollege of New Energy and Environment, Jilin University, Changchun 130012, ChinaSchool of Geomatics, Liaoning Technical University, Fuxin 123000 ChinaCollege of Materials Science and Engineering, Liaoning Technical University, Fuxin 123000, ChinaCollege of Materials Science and Engineering, Liaoning Technical University, Fuxin 123000, ChinaCollege of Materials Science and Engineering, Liaoning Technical University, Fuxin 123000, ChinaCollege of Materials Science and Engineering, Liaoning Technical University, Fuxin 123000, ChinaCollege of Materials Science and Engineering, Liaoning Technical University, Fuxin 123000, ChinaCollege of Materials Science and Engineering, Liaoning Technical University, Fuxin 123000, ChinaThree different metal-containing zinc phosphate, [C<sub>3</sub>H<sub>12</sub>N<sub>2</sub>][Zn<sub>0.5</sub>Fe<sub>1.5</sub>(PO<sub>4</sub>)<sub>2</sub>] (1), [C<sub>3</sub>H<sub>12</sub>N<sub>2</sub>][Zn<sub>0.67</sub>Co<sub>1.33</sub>(PO<sub>4</sub>)<sub>2</sub>] (2) and [C<sub>3</sub>H<sub>12</sub>N<sub>2</sub>][Zn<sub>0.67</sub>Ni<sub>1.33</sub>(PO<sub>4</sub>)<sub>2</sub>] (3) with EDI topology were prepared by sol–gel assisted hydrothermal method. The advantages of this method are lower synthesis temperature and uniform mixing. The crystalline metal-containing zinc phosphate zeolites exhibit a variety of SEM morphologies because of the entanglement of three different metal ions. The zinc ions in the zinc phosphate EDI molecular sieve were partially substituted by Fe, Co and Ni ions. The ICP analysis shows that the metal ratios of Zn/M are 1/3, 1/2 and 1/2. Variable temperature susceptibility was measured on powder samples in the range 2–300 K. All three M-EDI molecular sieves exhibit antiferromagnetic properties. In addition, they were analyzed by XRD, CHN, IR and TG.https://www.mdpi.com/2075-163X/10/5/391EDI zeolitezinc phosphatesol–gelhydrothermalmetal-containingmagnetic property |
| spellingShingle | Xuelei Wang Zhaojun Dong Qiufeng Wang Chao Meng Weibin Zhuang Jiyuan Liu Ying Song Yuxin Jin Shaobin Yang Metal-Containing Zinc Phosphate EDI Zeolites Synthesized by Sol–gel Assisted Hydrothermal Method Minerals EDI zeolite zinc phosphate sol–gel hydrothermal metal-containing magnetic property |
| title | Metal-Containing Zinc Phosphate EDI Zeolites Synthesized by Sol–gel Assisted Hydrothermal Method |
| title_full | Metal-Containing Zinc Phosphate EDI Zeolites Synthesized by Sol–gel Assisted Hydrothermal Method |
| title_fullStr | Metal-Containing Zinc Phosphate EDI Zeolites Synthesized by Sol–gel Assisted Hydrothermal Method |
| title_full_unstemmed | Metal-Containing Zinc Phosphate EDI Zeolites Synthesized by Sol–gel Assisted Hydrothermal Method |
| title_short | Metal-Containing Zinc Phosphate EDI Zeolites Synthesized by Sol–gel Assisted Hydrothermal Method |
| title_sort | metal containing zinc phosphate edi zeolites synthesized by sol gel assisted hydrothermal method |
| topic | EDI zeolite zinc phosphate sol–gel hydrothermal metal-containing magnetic property |
| url | https://www.mdpi.com/2075-163X/10/5/391 |
| work_keys_str_mv | AT xueleiwang metalcontainingzincphosphateedizeolitessynthesizedbysolgelassistedhydrothermalmethod AT zhaojundong metalcontainingzincphosphateedizeolitessynthesizedbysolgelassistedhydrothermalmethod AT qiufengwang metalcontainingzincphosphateedizeolitessynthesizedbysolgelassistedhydrothermalmethod AT chaomeng metalcontainingzincphosphateedizeolitessynthesizedbysolgelassistedhydrothermalmethod AT weibinzhuang metalcontainingzincphosphateedizeolitessynthesizedbysolgelassistedhydrothermalmethod AT jiyuanliu metalcontainingzincphosphateedizeolitessynthesizedbysolgelassistedhydrothermalmethod AT yingsong metalcontainingzincphosphateedizeolitessynthesizedbysolgelassistedhydrothermalmethod AT yuxinjin metalcontainingzincphosphateedizeolitessynthesizedbysolgelassistedhydrothermalmethod AT shaobinyang metalcontainingzincphosphateedizeolitessynthesizedbysolgelassistedhydrothermalmethod |