KINETIC APPROACH OF SODIUM LEACHING IN SOME CALCAREOUS SOILS AT NORTHERN IRAQ

<strong>Four undisturbed soil samples were collected differ in their textures representing Rashidiya, Mustah and Talseen 1&2 locations </strong>in Nineveh province / northern of Iraq<strong>, classified within great soil group Calciorthids. Samples were put in soil columns and...

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Main Authors: H. Ahmed, M. A. J. Al-Obaidi, M. T. S. Khalil
Format: Article
Language:Arabic
Published: College of Agriculture 2018-06-01
Series:Mesopotamia Journal of Agriculture
Subjects:
Online Access:https://magrj.mosuljournals.com/article_161447_3b894641ad7cacaa3742fb8d9acf6b5d.pdf
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author H. Ahmed
M. A. J. Al-Obaidi
M. T. S. Khalil
author_facet H. Ahmed
M. A. J. Al-Obaidi
M. T. S. Khalil
author_sort H. Ahmed
collection DOAJ
description <strong>Four undisturbed soil samples were collected differ in their textures representing Rashidiya, Mustah and Talseen 1&2 locations </strong>in Nineveh province / northern of Iraq<strong>, classified within great soil group Calciorthids. Samples were put in soil columns and leached by using distilled water (rain water), Tigris water, chlorine and sulfuric water to describe sodium leaching from calcareous soils via kinetic approaches. Results indicated that quantity of leached sodium up to 30<sup>th</sup> pore volumes of waters was ranged from 19.93 mmol<sub>c</sub>. liter<sup>-1</sup> for sandy loam soil by using distilled water to 455.63 mmol<sub>c</sub> liter<sup>-1</sup> for silty clay soil by using sulfuric water which reflect the role of water ionic strength in sodium leaching from soils. Leaching curves also referred that sodium was desorbed and leached via two stages. First rapid stage up to the 10<sup>th</sup> pore volumes indicating for of sodium salts solubility role, while second stage continued up to 30<sup>th</sup> pore volumes indicating for the role of ionic exchange. Mathematical description appeared a high harmony for 1<sup>st</sup> order equation in sodium leaching description and determination coefficient values R<sup>2</sup> were ranged from (0.87 - 0.99), leaching rates were from (22</strong>× 10<sup>-3</sup>). Hr<sup>-1</sup> for silty clay soil by using distilled water <strong>to (40 </strong>×<strong> 10<sup>-3</sup>). Hr<sup>-1</sup> for sandy loam soil by using sulfuric water referring that sodium desorption and leaching to soil liquid phase was simple and spontaneous and leaching free energy ∆G values were ranged from -2.26 to -1.19 kjole. mole<sup>-1</sup>.</strong>
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spelling doaj.art-22193d39fea24cb5a8b0d21ebcb929d42022-12-21T20:07:51ZaraCollege of AgricultureMesopotamia Journal of Agriculture1815-316X2224-97962018-06-014629210110.33899/magrj.2018.161447161447KINETIC APPROACH OF SODIUM LEACHING IN SOME CALCAREOUS SOILS AT NORTHERN IRAQH. Ahmed0M. A. J. Al-Obaidi1M. T. S. Khalil2College of Agriculture and Forestry, Mosul University. IraqCollege of Agriculture and Forestry, Mosul University. IraqCollege of Agriculture and Forestry, Mosul University. Iraq<strong>Four undisturbed soil samples were collected differ in their textures representing Rashidiya, Mustah and Talseen 1&2 locations </strong>in Nineveh province / northern of Iraq<strong>, classified within great soil group Calciorthids. Samples were put in soil columns and leached by using distilled water (rain water), Tigris water, chlorine and sulfuric water to describe sodium leaching from calcareous soils via kinetic approaches. Results indicated that quantity of leached sodium up to 30<sup>th</sup> pore volumes of waters was ranged from 19.93 mmol<sub>c</sub>. liter<sup>-1</sup> for sandy loam soil by using distilled water to 455.63 mmol<sub>c</sub> liter<sup>-1</sup> for silty clay soil by using sulfuric water which reflect the role of water ionic strength in sodium leaching from soils. Leaching curves also referred that sodium was desorbed and leached via two stages. First rapid stage up to the 10<sup>th</sup> pore volumes indicating for of sodium salts solubility role, while second stage continued up to 30<sup>th</sup> pore volumes indicating for the role of ionic exchange. Mathematical description appeared a high harmony for 1<sup>st</sup> order equation in sodium leaching description and determination coefficient values R<sup>2</sup> were ranged from (0.87 - 0.99), leaching rates were from (22</strong>× 10<sup>-3</sup>). Hr<sup>-1</sup> for silty clay soil by using distilled water <strong>to (40 </strong>×<strong> 10<sup>-3</sup>). Hr<sup>-1</sup> for sandy loam soil by using sulfuric water referring that sodium desorption and leaching to soil liquid phase was simple and spontaneous and leaching free energy ∆G values were ranged from -2.26 to -1.19 kjole. mole<sup>-1</sup>.</strong>https://magrj.mosuljournals.com/article_161447_3b894641ad7cacaa3742fb8d9acf6b5d.pdf: soil columnskinetic equationspore volumesfree energy
spellingShingle H. Ahmed
M. A. J. Al-Obaidi
M. T. S. Khalil
KINETIC APPROACH OF SODIUM LEACHING IN SOME CALCAREOUS SOILS AT NORTHERN IRAQ
Mesopotamia Journal of Agriculture
: soil columns
kinetic equations
pore volumes
free energy
title KINETIC APPROACH OF SODIUM LEACHING IN SOME CALCAREOUS SOILS AT NORTHERN IRAQ
title_full KINETIC APPROACH OF SODIUM LEACHING IN SOME CALCAREOUS SOILS AT NORTHERN IRAQ
title_fullStr KINETIC APPROACH OF SODIUM LEACHING IN SOME CALCAREOUS SOILS AT NORTHERN IRAQ
title_full_unstemmed KINETIC APPROACH OF SODIUM LEACHING IN SOME CALCAREOUS SOILS AT NORTHERN IRAQ
title_short KINETIC APPROACH OF SODIUM LEACHING IN SOME CALCAREOUS SOILS AT NORTHERN IRAQ
title_sort kinetic approach of sodium leaching in some calcareous soils at northern iraq
topic : soil columns
kinetic equations
pore volumes
free energy
url https://magrj.mosuljournals.com/article_161447_3b894641ad7cacaa3742fb8d9acf6b5d.pdf
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