Influence of Particle Size on Toughening Mechanisms of Layered Silicates in CFRP

Carbon-fiber-reinforced epoxies are frequently used for lightweight applications that require high mechanical properties. Still, there is potential regarding the improvement of the interlaminar-fracture toughness. As matrix toughening with nanoparticles is one possibility, in this study two differen...

Full description

Bibliographic Details
Main Authors: Julia Hutschreuther, Raphael Kunz, Josef Breu, Volker Altstädt
Format: Article
Language:English
Published: MDPI AG 2020-05-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/13/10/2396
_version_ 1797567208049606656
author Julia Hutschreuther
Raphael Kunz
Josef Breu
Volker Altstädt
author_facet Julia Hutschreuther
Raphael Kunz
Josef Breu
Volker Altstädt
author_sort Julia Hutschreuther
collection DOAJ
description Carbon-fiber-reinforced epoxies are frequently used for lightweight applications that require high mechanical properties. Still, there is potential regarding the improvement of the interlaminar-fracture toughness. As matrix toughening with nanoparticles is one possibility, in this study two different layered silicates are used to reinforce carbon fiber composites. The first type is a synthetical K-Hectorite (K-Hect) with outstanding lateral extension (6 µm) that has shown high toughening ability in resins in previous work. The other is a commercial montmorillonite (MMT) with a smaller size (400 nm). The aim of this study is to show the influence of the particles on mode I and mode II fracture toughness, especially the influence of particle size. Therefore, double-cantilever-beam tests and end-notched-flexure tests were carried out. Additionally, the fracture mechanisms were investigated via scanning electron microscopy (SEM). It is concluded, that the larger Hectorite particles are beneficial for mode I fracture behavior because of enhanced toughening mechanisms. One the other hand, the mode II energy dissipation rate is increased by the smaller montmorillonite particles due to sufficient interaction with the formation of hackling structures.
first_indexed 2024-03-10T19:39:24Z
format Article
id doaj.art-2253e8fe34774ae28a8d9eca8c36d6e8
institution Directory Open Access Journal
issn 1996-1944
language English
last_indexed 2024-03-10T19:39:24Z
publishDate 2020-05-01
publisher MDPI AG
record_format Article
series Materials
spelling doaj.art-2253e8fe34774ae28a8d9eca8c36d6e82023-11-20T01:24:21ZengMDPI AGMaterials1996-19442020-05-011310239610.3390/ma13102396Influence of Particle Size on Toughening Mechanisms of Layered Silicates in CFRPJulia Hutschreuther0Raphael Kunz1Josef Breu2Volker Altstädt3Bavarian Polymer Institute and Department of Polymer Engineering, University of Bayreuth, Universitätsstraße 30, 95447 Bayreuth, GermanyBavarian Polymer Institute and Department of Inorganic Chemistry I, University of Bayreuth, Universitätsstraße 30, 95447 Bayreuth, GermanyBavarian Polymer Institute and Department of Inorganic Chemistry I, University of Bayreuth, Universitätsstraße 30, 95447 Bayreuth, GermanyBavarian Polymer Institute and Department of Polymer Engineering, University of Bayreuth, Universitätsstraße 30, 95447 Bayreuth, GermanyCarbon-fiber-reinforced epoxies are frequently used for lightweight applications that require high mechanical properties. Still, there is potential regarding the improvement of the interlaminar-fracture toughness. As matrix toughening with nanoparticles is one possibility, in this study two different layered silicates are used to reinforce carbon fiber composites. The first type is a synthetical K-Hectorite (K-Hect) with outstanding lateral extension (6 µm) that has shown high toughening ability in resins in previous work. The other is a commercial montmorillonite (MMT) with a smaller size (400 nm). The aim of this study is to show the influence of the particles on mode I and mode II fracture toughness, especially the influence of particle size. Therefore, double-cantilever-beam tests and end-notched-flexure tests were carried out. Additionally, the fracture mechanisms were investigated via scanning electron microscopy (SEM). It is concluded, that the larger Hectorite particles are beneficial for mode I fracture behavior because of enhanced toughening mechanisms. One the other hand, the mode II energy dissipation rate is increased by the smaller montmorillonite particles due to sufficient interaction with the formation of hackling structures.https://www.mdpi.com/1996-1944/13/10/2396interlaminar-fracture toughnesslayered silicatecarbon-fiber-reinforced compositeprepreg
spellingShingle Julia Hutschreuther
Raphael Kunz
Josef Breu
Volker Altstädt
Influence of Particle Size on Toughening Mechanisms of Layered Silicates in CFRP
Materials
interlaminar-fracture toughness
layered silicate
carbon-fiber-reinforced composite
prepreg
title Influence of Particle Size on Toughening Mechanisms of Layered Silicates in CFRP
title_full Influence of Particle Size on Toughening Mechanisms of Layered Silicates in CFRP
title_fullStr Influence of Particle Size on Toughening Mechanisms of Layered Silicates in CFRP
title_full_unstemmed Influence of Particle Size on Toughening Mechanisms of Layered Silicates in CFRP
title_short Influence of Particle Size on Toughening Mechanisms of Layered Silicates in CFRP
title_sort influence of particle size on toughening mechanisms of layered silicates in cfrp
topic interlaminar-fracture toughness
layered silicate
carbon-fiber-reinforced composite
prepreg
url https://www.mdpi.com/1996-1944/13/10/2396
work_keys_str_mv AT juliahutschreuther influenceofparticlesizeontougheningmechanismsoflayeredsilicatesincfrp
AT raphaelkunz influenceofparticlesizeontougheningmechanismsoflayeredsilicatesincfrp
AT josefbreu influenceofparticlesizeontougheningmechanismsoflayeredsilicatesincfrp
AT volkeraltstadt influenceofparticlesizeontougheningmechanismsoflayeredsilicatesincfrp