[Bis(diphenylphosphanyl)dimethylsilane-κ2P,P′]tetracarbonylchromium(0)

The title compound, [Cr(C26H26P2Si)(CO)4], was obtained by the reaction of Ph2PSiMe2PPh2 with Cr(CO)6 in refluxing toluene by ligand exchange. The CrC4P2 coordination geometry at the Cr atom is distorted octahedral, with a P—Cr—P bite angle of 80.27 (1)&...

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Bibliographic Details
Main Authors: Normen Peulecke, Stephan Peitz, Bernd H. Müller, Anke Spannenberg, Uwe Rosenthal
Format: Article
Language:English
Published: International Union of Crystallography 2010-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810043679