Thermoelectric properties of In-rich InGaN and InN/InGaN superlattices

The thermoelectric properties of n-type InGaN alloys with high In-content and InN/InGaN thin film superlattices (SL) grown by molecular beam epitaxy are investigated. Room-temperature measurements of the thermoelectric properties reveal that an increasing Ga-content in ternary InGaN alloys (0 < x...

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Hlavní autoři: James (Zi-Jian) Ju, Bo Sun, Georg Haunschild, Bernhard Loitsch, Benedikt Stoib, Martin S. Brandt, Martin Stutzmann, Yee Kan Koh, Gregor Koblmüller
Médium: Článek
Jazyk:English
Vydáno: AIP Publishing LLC 2016-04-01
Edice:AIP Advances
On-line přístup:http://dx.doi.org/10.1063/1.4948446
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author James (Zi-Jian) Ju
Bo Sun
Georg Haunschild
Bernhard Loitsch
Benedikt Stoib
Martin S. Brandt
Martin Stutzmann
Yee Kan Koh
Gregor Koblmüller
author_facet James (Zi-Jian) Ju
Bo Sun
Georg Haunschild
Bernhard Loitsch
Benedikt Stoib
Martin S. Brandt
Martin Stutzmann
Yee Kan Koh
Gregor Koblmüller
author_sort James (Zi-Jian) Ju
collection DOAJ
description The thermoelectric properties of n-type InGaN alloys with high In-content and InN/InGaN thin film superlattices (SL) grown by molecular beam epitaxy are investigated. Room-temperature measurements of the thermoelectric properties reveal that an increasing Ga-content in ternary InGaN alloys (0 < x(Ga) < 0.2) yields a more than 10-fold reduction in thermal conductivity (κ) without deteriorating electrical conductivity (σ), while the Seebeck coefficient (S) increases slightly due to a widening band gap compared to binary InN. Employing InN/InGaN SLs (x(Ga) = 0.1) with different periods, we demonstrate that confinement effects strongly enhance electron mobility with values as high as ∼820 cm2/V s at an electron density ne of ∼5×1019 cm−3, leading to an exceptionally high σ of ∼5400 (Ωcm)−1. Simultaneously, in very short-period SL structures S becomes decoupled from ne, κ is further reduced below the alloy limit (κ < 9 W/m-K), and the power factor increases to 2.5×10−4 W/m-K2 by more than a factor of 5 as compared to In-rich InGaN alloys. These findings demonstrate that quantum confinement in group-III nitride-based superlattices facilitates improvements of thermoelectric properties over bulk-like ternary nitride alloys.
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spelling doaj.art-226b6f07901b4e678bcbf1916e7ad2dc2022-12-22T03:49:57ZengAIP Publishing LLCAIP Advances2158-32262016-04-0164045216045216-910.1063/1.4948446066604ADVThermoelectric properties of In-rich InGaN and InN/InGaN superlatticesJames (Zi-Jian) Ju0Bo Sun1Georg Haunschild2Bernhard Loitsch3Benedikt Stoib4Martin S. Brandt5Martin Stutzmann6Yee Kan Koh7Gregor Koblmüller8Walter Schottky Institut, Physik Department, TU München, 85748 Garching, GermanyDepartment of Mechanical Engineering, National University of Singapore, 117576, SingaporeWalter Schottky Institut, Physik Department, TU München, 85748 Garching, GermanyWalter Schottky Institut, Physik Department, TU München, 85748 Garching, GermanyWalter Schottky Institut, Physik Department, TU München, 85748 Garching, GermanyWalter Schottky Institut, Physik Department, TU München, 85748 Garching, GermanyWalter Schottky Institut, Physik Department, TU München, 85748 Garching, GermanyDepartment of Mechanical Engineering, National University of Singapore, 117576, SingaporeWalter Schottky Institut, Physik Department, TU München, 85748 Garching, GermanyThe thermoelectric properties of n-type InGaN alloys with high In-content and InN/InGaN thin film superlattices (SL) grown by molecular beam epitaxy are investigated. Room-temperature measurements of the thermoelectric properties reveal that an increasing Ga-content in ternary InGaN alloys (0 < x(Ga) < 0.2) yields a more than 10-fold reduction in thermal conductivity (κ) without deteriorating electrical conductivity (σ), while the Seebeck coefficient (S) increases slightly due to a widening band gap compared to binary InN. Employing InN/InGaN SLs (x(Ga) = 0.1) with different periods, we demonstrate that confinement effects strongly enhance electron mobility with values as high as ∼820 cm2/V s at an electron density ne of ∼5×1019 cm−3, leading to an exceptionally high σ of ∼5400 (Ωcm)−1. Simultaneously, in very short-period SL structures S becomes decoupled from ne, κ is further reduced below the alloy limit (κ < 9 W/m-K), and the power factor increases to 2.5×10−4 W/m-K2 by more than a factor of 5 as compared to In-rich InGaN alloys. These findings demonstrate that quantum confinement in group-III nitride-based superlattices facilitates improvements of thermoelectric properties over bulk-like ternary nitride alloys.http://dx.doi.org/10.1063/1.4948446
spellingShingle James (Zi-Jian) Ju
Bo Sun
Georg Haunschild
Bernhard Loitsch
Benedikt Stoib
Martin S. Brandt
Martin Stutzmann
Yee Kan Koh
Gregor Koblmüller
Thermoelectric properties of In-rich InGaN and InN/InGaN superlattices
AIP Advances
title Thermoelectric properties of In-rich InGaN and InN/InGaN superlattices
title_full Thermoelectric properties of In-rich InGaN and InN/InGaN superlattices
title_fullStr Thermoelectric properties of In-rich InGaN and InN/InGaN superlattices
title_full_unstemmed Thermoelectric properties of In-rich InGaN and InN/InGaN superlattices
title_short Thermoelectric properties of In-rich InGaN and InN/InGaN superlattices
title_sort thermoelectric properties of in rich ingan and inn ingan superlattices
url http://dx.doi.org/10.1063/1.4948446
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