Salinity Gradient Power Driven Water Electrolysis for Hydrogen Production

The present work demonstrates an innovative system combining Reverse Electrodialysis (RED) and Alkaline Polymer Electrolyte Water Electrolysis (APEWE) for sustainable hydrogen production. The Salinity Gradient Power (SGP)-RED unit was tested with a thermally regenerative solution of NH4HCO3 in the c...

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Main Authors: R.A. Tufa, D. Chanda, L. Tundis, J. Hnat, K. Bouzek, J. Veerman, E. Fontananova, G. Di Profio, E. Curcio
Format: Article
Language:English
Published: AIDIC Servizi S.r.l. 2017-09-01
Series:Chemical Engineering Transactions
Online Access:https://www.cetjournal.it/index.php/cet/article/view/423
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author R.A. Tufa
D. Chanda
L. Tundis
J. Hnat
K. Bouzek
J. Veerman
E. Fontananova
G. Di Profio
E. Curcio
author_facet R.A. Tufa
D. Chanda
L. Tundis
J. Hnat
K. Bouzek
J. Veerman
E. Fontananova
G. Di Profio
E. Curcio
author_sort R.A. Tufa
collection DOAJ
description The present work demonstrates an innovative system combining Reverse Electrodialysis (RED) and Alkaline Polymer Electrolyte Water Electrolysis (APEWE) for sustainable hydrogen production. The Salinity Gradient Power (SGP)-RED unit was tested with a thermally regenerative solution of NH4HCO3 in the concentration range of 0.15-1.5 M, whereas the water electrolysis unit equipped with quaternary ammonium functionalized anion selective membrane, Ni anode modified with Platinum Group Metal (PGM)-free electrocatalyst, Ni cathode modified with an electrochemically Reduced Graphene Oxide (RGO) was investigated at a varying temperature (50 - 80 °C). The integrated RED-APEWE system reached a maximum hydrogen production rate of 3.0x10-3 mol H2/h per cm2 of electrode surface area. Owing to the use of the thermally regenerative NH4HCO3 solution, this work presents a profound basis to design a system allowing the conversion of low-grade waste heat into electricity in a closed loop with simultaneous production of hydrogen using salinity gradient energy.
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spelling doaj.art-227ddd3ba4ba4bd594335ea3dd992dfc2022-12-22T04:07:36ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162017-09-016010.3303/CET1760048Salinity Gradient Power Driven Water Electrolysis for Hydrogen ProductionR.A. TufaD. ChandaL. TundisJ. HnatK. BouzekJ. VeermanE. FontananovaG. Di ProfioE. CurcioThe present work demonstrates an innovative system combining Reverse Electrodialysis (RED) and Alkaline Polymer Electrolyte Water Electrolysis (APEWE) for sustainable hydrogen production. The Salinity Gradient Power (SGP)-RED unit was tested with a thermally regenerative solution of NH4HCO3 in the concentration range of 0.15-1.5 M, whereas the water electrolysis unit equipped with quaternary ammonium functionalized anion selective membrane, Ni anode modified with Platinum Group Metal (PGM)-free electrocatalyst, Ni cathode modified with an electrochemically Reduced Graphene Oxide (RGO) was investigated at a varying temperature (50 - 80 °C). The integrated RED-APEWE system reached a maximum hydrogen production rate of 3.0x10-3 mol H2/h per cm2 of electrode surface area. Owing to the use of the thermally regenerative NH4HCO3 solution, this work presents a profound basis to design a system allowing the conversion of low-grade waste heat into electricity in a closed loop with simultaneous production of hydrogen using salinity gradient energy.https://www.cetjournal.it/index.php/cet/article/view/423
spellingShingle R.A. Tufa
D. Chanda
L. Tundis
J. Hnat
K. Bouzek
J. Veerman
E. Fontananova
G. Di Profio
E. Curcio
Salinity Gradient Power Driven Water Electrolysis for Hydrogen Production
Chemical Engineering Transactions
title Salinity Gradient Power Driven Water Electrolysis for Hydrogen Production
title_full Salinity Gradient Power Driven Water Electrolysis for Hydrogen Production
title_fullStr Salinity Gradient Power Driven Water Electrolysis for Hydrogen Production
title_full_unstemmed Salinity Gradient Power Driven Water Electrolysis for Hydrogen Production
title_short Salinity Gradient Power Driven Water Electrolysis for Hydrogen Production
title_sort salinity gradient power driven water electrolysis for hydrogen production
url https://www.cetjournal.it/index.php/cet/article/view/423
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AT ltundis salinitygradientpowerdrivenwaterelectrolysisforhydrogenproduction
AT jhnat salinitygradientpowerdrivenwaterelectrolysisforhydrogenproduction
AT kbouzek salinitygradientpowerdrivenwaterelectrolysisforhydrogenproduction
AT jveerman salinitygradientpowerdrivenwaterelectrolysisforhydrogenproduction
AT efontananova salinitygradientpowerdrivenwaterelectrolysisforhydrogenproduction
AT gdiprofio salinitygradientpowerdrivenwaterelectrolysisforhydrogenproduction
AT ecurcio salinitygradientpowerdrivenwaterelectrolysisforhydrogenproduction