Ionic liquid/Mn complex immobilized on phenylene based periodic mesoporous organosilica: An efficient and reusable nanocatalyst for green oxidation of alcohols
A novel bifunctional periodic mesoporous organosilica with ionic liquid and phenylene framework supported manganese (BPMO-Ph-IL/Mn) was synthesized, characterized and its catalytic application was investigated. The BPMO-Ph-IL/Mn nanocatalyst was prepared through grafting of ionic liquid on a phenyle...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2021-09-01
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| Series: | Applied Surface Science Advances |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2666523921000453 |
| Summary: | A novel bifunctional periodic mesoporous organosilica with ionic liquid and phenylene framework supported manganese (BPMO-Ph-IL/Mn) was synthesized, characterized and its catalytic application was investigated. The BPMO-Ph-IL/Mn nanocatalyst was prepared through grafting of ionic liquid on a phenylene based PMO followed by treatment with manganese nitrate. The designed BPMO-Ph-IL/Mn catalyst was characterized using FT-IR, PXRD, TEM, EDX and N2 adsorption–desorption analyses. This was used as an efficient catalyst for selective oxidation of different alcohols. The BPMO-Ph-IL/Mn catalyst was recovered and reused for at least five times without a significant decrease in its efficiency. |
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| ISSN: | 2666-5239 |