Ionic liquid/Mn complex immobilized on phenylene based periodic mesoporous organosilica: An efficient and reusable nanocatalyst for green oxidation of alcohols
A novel bifunctional periodic mesoporous organosilica with ionic liquid and phenylene framework supported manganese (BPMO-Ph-IL/Mn) was synthesized, characterized and its catalytic application was investigated. The BPMO-Ph-IL/Mn nanocatalyst was prepared through grafting of ionic liquid on a phenyle...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Elsevier
2021-09-01
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| Series: | Applied Surface Science Advances |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2666523921000453 |
| _version_ | 1818647304242987008 |
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| author | Hakimeh Ardeshirfard Dawood Elhamifar |
| author_facet | Hakimeh Ardeshirfard Dawood Elhamifar |
| author_sort | Hakimeh Ardeshirfard |
| collection | DOAJ |
| description | A novel bifunctional periodic mesoporous organosilica with ionic liquid and phenylene framework supported manganese (BPMO-Ph-IL/Mn) was synthesized, characterized and its catalytic application was investigated. The BPMO-Ph-IL/Mn nanocatalyst was prepared through grafting of ionic liquid on a phenylene based PMO followed by treatment with manganese nitrate. The designed BPMO-Ph-IL/Mn catalyst was characterized using FT-IR, PXRD, TEM, EDX and N2 adsorption–desorption analyses. This was used as an efficient catalyst for selective oxidation of different alcohols. The BPMO-Ph-IL/Mn catalyst was recovered and reused for at least five times without a significant decrease in its efficiency. |
| first_indexed | 2024-12-17T01:00:24Z |
| format | Article |
| id | doaj.art-227e6fa4c8ae457abb565435646c1c4b |
| institution | Directory Open Access Journal |
| issn | 2666-5239 |
| language | English |
| last_indexed | 2024-12-17T01:00:24Z |
| publishDate | 2021-09-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Applied Surface Science Advances |
| spelling | doaj.art-227e6fa4c8ae457abb565435646c1c4b2022-12-21T22:09:28ZengElsevierApplied Surface Science Advances2666-52392021-09-015100099Ionic liquid/Mn complex immobilized on phenylene based periodic mesoporous organosilica: An efficient and reusable nanocatalyst for green oxidation of alcoholsHakimeh Ardeshirfard0Dawood Elhamifar1Department of Chemistry, Yasouj University, Yasouj, IranCorresponding author.; Department of Chemistry, Yasouj University, Yasouj, IranA novel bifunctional periodic mesoporous organosilica with ionic liquid and phenylene framework supported manganese (BPMO-Ph-IL/Mn) was synthesized, characterized and its catalytic application was investigated. The BPMO-Ph-IL/Mn nanocatalyst was prepared through grafting of ionic liquid on a phenylene based PMO followed by treatment with manganese nitrate. The designed BPMO-Ph-IL/Mn catalyst was characterized using FT-IR, PXRD, TEM, EDX and N2 adsorption–desorption analyses. This was used as an efficient catalyst for selective oxidation of different alcohols. The BPMO-Ph-IL/Mn catalyst was recovered and reused for at least five times without a significant decrease in its efficiency.http://www.sciencedirect.com/science/article/pii/S2666523921000453Periodic mesoporous organosilicaIonic liquidManganeseGreen conditionsOxidation of alcohols |
| spellingShingle | Hakimeh Ardeshirfard Dawood Elhamifar Ionic liquid/Mn complex immobilized on phenylene based periodic mesoporous organosilica: An efficient and reusable nanocatalyst for green oxidation of alcohols Applied Surface Science Advances Periodic mesoporous organosilica Ionic liquid Manganese Green conditions Oxidation of alcohols |
| title | Ionic liquid/Mn complex immobilized on phenylene based periodic mesoporous organosilica: An efficient and reusable nanocatalyst for green oxidation of alcohols |
| title_full | Ionic liquid/Mn complex immobilized on phenylene based periodic mesoporous organosilica: An efficient and reusable nanocatalyst for green oxidation of alcohols |
| title_fullStr | Ionic liquid/Mn complex immobilized on phenylene based periodic mesoporous organosilica: An efficient and reusable nanocatalyst for green oxidation of alcohols |
| title_full_unstemmed | Ionic liquid/Mn complex immobilized on phenylene based periodic mesoporous organosilica: An efficient and reusable nanocatalyst for green oxidation of alcohols |
| title_short | Ionic liquid/Mn complex immobilized on phenylene based periodic mesoporous organosilica: An efficient and reusable nanocatalyst for green oxidation of alcohols |
| title_sort | ionic liquid mn complex immobilized on phenylene based periodic mesoporous organosilica an efficient and reusable nanocatalyst for green oxidation of alcohols |
| topic | Periodic mesoporous organosilica Ionic liquid Manganese Green conditions Oxidation of alcohols |
| url | http://www.sciencedirect.com/science/article/pii/S2666523921000453 |
| work_keys_str_mv | AT hakimehardeshirfard ionicliquidmncompleximmobilizedonphenylenebasedperiodicmesoporousorganosilicaanefficientandreusablenanocatalystforgreenoxidationofalcohols AT dawoodelhamifar ionicliquidmncompleximmobilizedonphenylenebasedperiodicmesoporousorganosilicaanefficientandreusablenanocatalystforgreenoxidationofalcohols |