Low Detection Limit and High Sensitivity 2-Butanone Gas Sensor Based on ZnO Nanosheets Decorated by Co Nanoparticles Derived from ZIF-67

2-butanone has been certified to cause potential harm to the human body, environment, etc. Therefore, achieving a method for the high sensitivity and low limit detection of 2-butanone is of great significance. To achieve this goal, this article uses ZIF-67 prepared by a precipitation method as a cob...

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Bibliographic Details
Main Authors: Hua Zhang, Wenjie Zhao, Fanli Meng
Format: Article
Language:English
Published: MDPI AG 2023-08-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/13/17/2398
Description
Summary:2-butanone has been certified to cause potential harm to the human body, environment, etc. Therefore, achieving a method for the high sensitivity and low limit detection of 2-butanone is of great significance. To achieve this goal, this article uses ZIF-67 prepared by a precipitation method as a cobalt source, and then prepares cobalt-modified zinc oxide nanosheets through a hydrothermal method. The microstructure of the materials was observed by SEM, EDS, TEM, HRTEM, XPS and XRD. The test data display that the sensor ZC2 can produce a high response (2540) to 100 ppm 2-butanone at 270 °C, which is 21 times higher than that of pure ZnO materials. Its detection limit is also optimized to 24 ppb. The sensor (ZC2) also excels in these properties: selectivity, repeatability and stability over 30 days. Further analysis indicates that the synergistic and catalytic effects of p-n heterojunction are the key sources for optimizing the performance of sensors for detecting 2-butanone.
ISSN:2079-4991