Enantioselective Henry Reaction Catalyzed by Copper(II) Complex of Bis(<i>trans</i>-cyclohexane-1,2-diamine)-Based Ligand
Copper(II) complex of the ligand possessing two enantiomerically pure <i>trans</i>-cyclohexane-1,2-diamine units proved to be an efficient catalyst for the enantioselective Henry reaction of aromatic aldehydes with nitromethane. The effect of various reaction conditions on yield and enan...
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| Format: | Article |
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MDPI AG
2020-12-01
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| Series: | Catalysts |
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| Online Access: | https://www.mdpi.com/2073-4344/11/1/41 |
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| author | David Tetour Marika Novotná Jana Hodačová |
| author_facet | David Tetour Marika Novotná Jana Hodačová |
| author_sort | David Tetour |
| collection | DOAJ |
| description | Copper(II) complex of the ligand possessing two enantiomerically pure <i>trans</i>-cyclohexane-1,2-diamine units proved to be an efficient catalyst for the enantioselective Henry reaction of aromatic aldehydes with nitromethane. The effect of various reaction conditions on yield and enantioselectivity of the Henry reaction was studied. The results suggest that only one cyclohexane-1,2-diamine unit is involved in catalysis of the Henry reaction. |
| first_indexed | 2024-03-10T13:36:30Z |
| format | Article |
| id | doaj.art-22a0b56923d74bf19981373ef34a7d09 |
| institution | Directory Open Access Journal |
| issn | 2073-4344 |
| language | English |
| last_indexed | 2024-03-10T13:36:30Z |
| publishDate | 2020-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Catalysts |
| spelling | doaj.art-22a0b56923d74bf19981373ef34a7d092023-11-21T07:28:58ZengMDPI AGCatalysts2073-43442020-12-011114110.3390/catal11010041Enantioselective Henry Reaction Catalyzed by Copper(II) Complex of Bis(<i>trans</i>-cyclohexane-1,2-diamine)-Based LigandDavid Tetour0Marika Novotná1Jana Hodačová2Department of Organic Chemistry, Faculty of Chemical Technology, University of Chemistry and Technology, Technická 5, 166 28 Prague 6, Czech RepublicDepartment of Organic Chemistry, Faculty of Chemical Technology, University of Chemistry and Technology, Technická 5, 166 28 Prague 6, Czech RepublicDepartment of Organic Chemistry, Faculty of Chemical Technology, University of Chemistry and Technology, Technická 5, 166 28 Prague 6, Czech RepublicCopper(II) complex of the ligand possessing two enantiomerically pure <i>trans</i>-cyclohexane-1,2-diamine units proved to be an efficient catalyst for the enantioselective Henry reaction of aromatic aldehydes with nitromethane. The effect of various reaction conditions on yield and enantioselectivity of the Henry reaction was studied. The results suggest that only one cyclohexane-1,2-diamine unit is involved in catalysis of the Henry reaction.https://www.mdpi.com/2073-4344/11/1/41Henry reactionenantioselective catalysis<i>trans</i>-cyclohexane-1,2-diaminecopper(II) complexes |
| spellingShingle | David Tetour Marika Novotná Jana Hodačová Enantioselective Henry Reaction Catalyzed by Copper(II) Complex of Bis(<i>trans</i>-cyclohexane-1,2-diamine)-Based Ligand Catalysts Henry reaction enantioselective catalysis <i>trans</i>-cyclohexane-1,2-diamine copper(II) complexes |
| title | Enantioselective Henry Reaction Catalyzed by Copper(II) Complex of Bis(<i>trans</i>-cyclohexane-1,2-diamine)-Based Ligand |
| title_full | Enantioselective Henry Reaction Catalyzed by Copper(II) Complex of Bis(<i>trans</i>-cyclohexane-1,2-diamine)-Based Ligand |
| title_fullStr | Enantioselective Henry Reaction Catalyzed by Copper(II) Complex of Bis(<i>trans</i>-cyclohexane-1,2-diamine)-Based Ligand |
| title_full_unstemmed | Enantioselective Henry Reaction Catalyzed by Copper(II) Complex of Bis(<i>trans</i>-cyclohexane-1,2-diamine)-Based Ligand |
| title_short | Enantioselective Henry Reaction Catalyzed by Copper(II) Complex of Bis(<i>trans</i>-cyclohexane-1,2-diamine)-Based Ligand |
| title_sort | enantioselective henry reaction catalyzed by copper ii complex of bis i trans i cyclohexane 1 2 diamine based ligand |
| topic | Henry reaction enantioselective catalysis <i>trans</i>-cyclohexane-1,2-diamine copper(II) complexes |
| url | https://www.mdpi.com/2073-4344/11/1/41 |
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