Design and Large Temperature Jump Testing of a Modular Finned-Tube Carbon–Ammonia Adsorption Generator for Gas-Fired Heat Pumps

Gas-fired heat pumps are a potential replacement for condensing boilers, utilizing fossil-fuel resources more efficiently and reducing the amount of biogas or hydrogen required in sustainable gas grids. However, their adoption has been limited due to their large size and high capital cost, resulting...

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Main Authors: Steven Metcalf, Ángeles Rivero-Pacho, Robert Critoph
Format: Article
Language:English
Published: MDPI AG 2021-06-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/14/11/3332
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author Steven Metcalf
Ángeles Rivero-Pacho
Robert Critoph
author_facet Steven Metcalf
Ángeles Rivero-Pacho
Robert Critoph
author_sort Steven Metcalf
collection DOAJ
description Gas-fired heat pumps are a potential replacement for condensing boilers, utilizing fossil-fuel resources more efficiently and reducing the amount of biogas or hydrogen required in sustainable gas grids. However, their adoption has been limited due to their large size and high capital cost, resulting in long payback times. For adsorption-based heat pumps, the major development challenge is to maximize the rate of heat transfer to the adsorbent, whilst minimizing the thermal mass. This work develops a modular finned-tube carbon–ammonia adsorption generator that incorporates the adsorbent in highly compacted 3-mm layers between aluminum fins. Manufacturing techniques that are amenable to low cost and high-volume production were developed. The module was tested using the large temperature jump (LTJ) method and achieved a time constant for adsorption and desorption of 50 s. The computational model predicted that if incorporated into two adsorption generators of 6 L volume each, they could be used to construct a gas-fired heat pump with a 10 kW heat output and a gas utilization efficiency (GUE, the ratio of useful heat output to higher calorific value of gas used) of 1.2.
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spelling doaj.art-22a0bb1e81e44b98ac5ed216f35eb1c42023-11-21T22:58:29ZengMDPI AGEnergies1996-10732021-06-011411333210.3390/en14113332Design and Large Temperature Jump Testing of a Modular Finned-Tube Carbon–Ammonia Adsorption Generator for Gas-Fired Heat PumpsSteven Metcalf0Ángeles Rivero-Pacho1Robert Critoph2School of Engineering, University of Warwick, Coventry CV4 7AL, UKSchool of Engineering, University of Warwick, Coventry CV4 7AL, UKSchool of Engineering, University of Warwick, Coventry CV4 7AL, UKGas-fired heat pumps are a potential replacement for condensing boilers, utilizing fossil-fuel resources more efficiently and reducing the amount of biogas or hydrogen required in sustainable gas grids. However, their adoption has been limited due to their large size and high capital cost, resulting in long payback times. For adsorption-based heat pumps, the major development challenge is to maximize the rate of heat transfer to the adsorbent, whilst minimizing the thermal mass. This work develops a modular finned-tube carbon–ammonia adsorption generator that incorporates the adsorbent in highly compacted 3-mm layers between aluminum fins. Manufacturing techniques that are amenable to low cost and high-volume production were developed. The module was tested using the large temperature jump (LTJ) method and achieved a time constant for adsorption and desorption of 50 s. The computational model predicted that if incorporated into two adsorption generators of 6 L volume each, they could be used to construct a gas-fired heat pump with a 10 kW heat output and a gas utilization efficiency (GUE, the ratio of useful heat output to higher calorific value of gas used) of 1.2.https://www.mdpi.com/1996-1073/14/11/3332adsorptionheat pumpactive carbonammonia
spellingShingle Steven Metcalf
Ángeles Rivero-Pacho
Robert Critoph
Design and Large Temperature Jump Testing of a Modular Finned-Tube Carbon–Ammonia Adsorption Generator for Gas-Fired Heat Pumps
Energies
adsorption
heat pump
active carbon
ammonia
title Design and Large Temperature Jump Testing of a Modular Finned-Tube Carbon–Ammonia Adsorption Generator for Gas-Fired Heat Pumps
title_full Design and Large Temperature Jump Testing of a Modular Finned-Tube Carbon–Ammonia Adsorption Generator for Gas-Fired Heat Pumps
title_fullStr Design and Large Temperature Jump Testing of a Modular Finned-Tube Carbon–Ammonia Adsorption Generator for Gas-Fired Heat Pumps
title_full_unstemmed Design and Large Temperature Jump Testing of a Modular Finned-Tube Carbon–Ammonia Adsorption Generator for Gas-Fired Heat Pumps
title_short Design and Large Temperature Jump Testing of a Modular Finned-Tube Carbon–Ammonia Adsorption Generator for Gas-Fired Heat Pumps
title_sort design and large temperature jump testing of a modular finned tube carbon ammonia adsorption generator for gas fired heat pumps
topic adsorption
heat pump
active carbon
ammonia
url https://www.mdpi.com/1996-1073/14/11/3332
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