Review on recent trends and prospects in π‐conjugated luminescent aggregates for biomedical applications
Abstract Metal‐free organic molecules with structurally diverse aggregation‐induced emission (AIE) behavior and new functional photophysical properties reveal unique structure–property relationships, especially bright luminescence, and have attracted extensive attention in the past few decades. Desp...
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| Format: | Article |
| Language: | English |
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Wiley
2022-10-01
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| Series: | Aggregate |
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| Online Access: | https://doi.org/10.1002/agt2.172 |
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| author | Debasish Barman Kavita Narang Retwik Parui Nehal Zehra Mst Nasima Khatun Laxmi Raman Adil Parameswar Krishnan Iyer |
| author_facet | Debasish Barman Kavita Narang Retwik Parui Nehal Zehra Mst Nasima Khatun Laxmi Raman Adil Parameswar Krishnan Iyer |
| author_sort | Debasish Barman |
| collection | DOAJ |
| description | Abstract Metal‐free organic molecules with structurally diverse aggregation‐induced emission (AIE) behavior and new functional photophysical properties reveal unique structure–property relationships, especially bright luminescence, and have attracted extensive attention in the past few decades. Despite tremendous progress on fluorescent molecules development, the extended π‐conjugated organic AIE probes with their nanorange self‐assembly, coassembly, unique morphology, high biocompatibility, and light‐harvesting capabilities enable them as potential candidates in numerous translational application perspectives. In particular, a few important classes of AIE light up small molecules, supramolecules, oligomers, polymers, including nanoparticles and photosensitizer molecules, with their emerging properties of thermally activated delayed fluorescence, room temperature phosphorescence, including emission switching stimuli‐responsive behavior and multifunctional properties, have been boosted by the rare features of aggregation at their condensed or solid states. This review highlights salient features of AIE‐based emitters, encompassing molecular design strategies, stimulating photophysical properties, mechanistic aspects, and their efficacy in various electronic and biomedical applications, broadly covering properties of small molecules to oligomers, macromolecules to polymers. |
| first_indexed | 2024-04-11T19:44:35Z |
| format | Article |
| id | doaj.art-22a3e36db0414a54a1f351fb3f0fb38c |
| institution | Directory Open Access Journal |
| issn | 2692-4560 |
| language | English |
| last_indexed | 2024-04-11T19:44:35Z |
| publishDate | 2022-10-01 |
| publisher | Wiley |
| record_format | Article |
| series | Aggregate |
| spelling | doaj.art-22a3e36db0414a54a1f351fb3f0fb38c2022-12-22T04:06:31ZengWileyAggregate2692-45602022-10-0135n/an/a10.1002/agt2.172Review on recent trends and prospects in π‐conjugated luminescent aggregates for biomedical applicationsDebasish Barman0Kavita Narang1Retwik Parui2Nehal Zehra3Mst Nasima Khatun4Laxmi Raman Adil5Parameswar Krishnan Iyer6Department of Chemistry School of Health Science and Technology Centre for Nanotechnology, Indian Institute of Technology Guwahati Guwahati IndiaDepartment of Chemistry School of Health Science and Technology Centre for Nanotechnology, Indian Institute of Technology Guwahati Guwahati IndiaDepartment of Chemistry School of Health Science and Technology Centre for Nanotechnology, Indian Institute of Technology Guwahati Guwahati IndiaDepartment of Chemistry School of Health Science and Technology Centre for Nanotechnology, Indian Institute of Technology Guwahati Guwahati IndiaDepartment of Chemistry School of Health Science and Technology Centre for Nanotechnology, Indian Institute of Technology Guwahati Guwahati IndiaDepartment of Chemistry School of Health Science and Technology Centre for Nanotechnology, Indian Institute of Technology Guwahati Guwahati IndiaDepartment of Chemistry School of Health Science and Technology Centre for Nanotechnology, Indian Institute of Technology Guwahati Guwahati IndiaAbstract Metal‐free organic molecules with structurally diverse aggregation‐induced emission (AIE) behavior and new functional photophysical properties reveal unique structure–property relationships, especially bright luminescence, and have attracted extensive attention in the past few decades. Despite tremendous progress on fluorescent molecules development, the extended π‐conjugated organic AIE probes with their nanorange self‐assembly, coassembly, unique morphology, high biocompatibility, and light‐harvesting capabilities enable them as potential candidates in numerous translational application perspectives. In particular, a few important classes of AIE light up small molecules, supramolecules, oligomers, polymers, including nanoparticles and photosensitizer molecules, with their emerging properties of thermally activated delayed fluorescence, room temperature phosphorescence, including emission switching stimuli‐responsive behavior and multifunctional properties, have been boosted by the rare features of aggregation at their condensed or solid states. This review highlights salient features of AIE‐based emitters, encompassing molecular design strategies, stimulating photophysical properties, mechanistic aspects, and their efficacy in various electronic and biomedical applications, broadly covering properties of small molecules to oligomers, macromolecules to polymers.https://doi.org/10.1002/agt2.172aggregation‐induced emissionmacromoleculesphotosensitizerspolymersroom temperature phosphorescencesmall molecules |
| spellingShingle | Debasish Barman Kavita Narang Retwik Parui Nehal Zehra Mst Nasima Khatun Laxmi Raman Adil Parameswar Krishnan Iyer Review on recent trends and prospects in π‐conjugated luminescent aggregates for biomedical applications Aggregate aggregation‐induced emission macromolecules photosensitizers polymers room temperature phosphorescence small molecules |
| title | Review on recent trends and prospects in π‐conjugated luminescent aggregates for biomedical applications |
| title_full | Review on recent trends and prospects in π‐conjugated luminescent aggregates for biomedical applications |
| title_fullStr | Review on recent trends and prospects in π‐conjugated luminescent aggregates for biomedical applications |
| title_full_unstemmed | Review on recent trends and prospects in π‐conjugated luminescent aggregates for biomedical applications |
| title_short | Review on recent trends and prospects in π‐conjugated luminescent aggregates for biomedical applications |
| title_sort | review on recent trends and prospects in π conjugated luminescent aggregates for biomedical applications |
| topic | aggregation‐induced emission macromolecules photosensitizers polymers room temperature phosphorescence small molecules |
| url | https://doi.org/10.1002/agt2.172 |
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