Effective hydrodeoxygenation bio-oil via natural zeolite supported transition metal oxide catalyst
Bio-oil from biomass pyrolysis is promising to be used as a sustainable biofuel and high-value-added chemical. However, the presence of high acid, water, and oxygenate causes corrosive properties, low higher heating value (HHV), and instability of the bio-oil component. Therefore, refining the bio-o...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2023-06-01
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| Series: | Arabian Journal of Chemistry |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S1878535223001697 |
| _version_ | 1797846337476100096 |
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| author | Junifa Layla Sihombing Herlinawati Herlinawati Ahmad Nasir Pulungan Lisnawaty Simatupang Rahayu Rahayu Ary Anggara Wibowo |
| author_facet | Junifa Layla Sihombing Herlinawati Herlinawati Ahmad Nasir Pulungan Lisnawaty Simatupang Rahayu Rahayu Ary Anggara Wibowo |
| author_sort | Junifa Layla Sihombing |
| collection | DOAJ |
| description | Bio-oil from biomass pyrolysis is promising to be used as a sustainable biofuel and high-value-added chemical. However, the presence of high acid, water, and oxygenate causes corrosive properties, low higher heating value (HHV), and instability of the bio-oil component. Therefore, refining the bio-oil is essential to improve its quality. In this study, we introduced natural zeolite (HZ) impregnated with transition metal oxide (TMO) to refine the bio-oil using the hydrodeoxygenation method (HDO) at various catalyst ratios and temperatures. We find that ZnO/HZ 5% wt. shows the best catalytic performance, with the conversion of organic phase reaching ∼ 50%. The refined bio-oil from Fe2O3, ZnO, and CuO has high-quality physicochemical properties with carbon, oxygen, water level, and HHV values are 37–52%, 40–53%, 8–27%, and 17–21 MJ/kg, respectively. This result represents a high catalytic performance for the hydrodeoxygenation process of bio-oil using natural zeolite-based transition metal oxide for better and low-cost biofuel production. |
| first_indexed | 2024-04-09T17:54:21Z |
| format | Article |
| id | doaj.art-22a83249a0304a68a8368baa2efa8e04 |
| institution | Directory Open Access Journal |
| issn | 1878-5352 |
| language | English |
| last_indexed | 2024-04-09T17:54:21Z |
| publishDate | 2023-06-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Arabian Journal of Chemistry |
| spelling | doaj.art-22a83249a0304a68a8368baa2efa8e042023-04-15T05:51:58ZengElsevierArabian Journal of Chemistry1878-53522023-06-01166104707Effective hydrodeoxygenation bio-oil via natural zeolite supported transition metal oxide catalystJunifa Layla Sihombing0Herlinawati Herlinawati1Ahmad Nasir Pulungan2Lisnawaty Simatupang3Rahayu Rahayu4Ary Anggara Wibowo5Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, Jl. Willem Iskandar Pasar V Medan Estate, Medan 20221, Indonesia; Corresponding author.Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, Jl. Willem Iskandar Pasar V Medan Estate, Medan 20221, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, Jl. Willem Iskandar Pasar V Medan Estate, Medan 20221, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, Jl. Willem Iskandar Pasar V Medan Estate, Medan 20221, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, Jl. Willem Iskandar Pasar V Medan Estate, Medan 20221, IndonesiaSchool of Engineering, College of Engineering and Computer Science, The Australian National University, North Road, 2601, Australian Capital Territory, AustraliaBio-oil from biomass pyrolysis is promising to be used as a sustainable biofuel and high-value-added chemical. However, the presence of high acid, water, and oxygenate causes corrosive properties, low higher heating value (HHV), and instability of the bio-oil component. Therefore, refining the bio-oil is essential to improve its quality. In this study, we introduced natural zeolite (HZ) impregnated with transition metal oxide (TMO) to refine the bio-oil using the hydrodeoxygenation method (HDO) at various catalyst ratios and temperatures. We find that ZnO/HZ 5% wt. shows the best catalytic performance, with the conversion of organic phase reaching ∼ 50%. The refined bio-oil from Fe2O3, ZnO, and CuO has high-quality physicochemical properties with carbon, oxygen, water level, and HHV values are 37–52%, 40–53%, 8–27%, and 17–21 MJ/kg, respectively. This result represents a high catalytic performance for the hydrodeoxygenation process of bio-oil using natural zeolite-based transition metal oxide for better and low-cost biofuel production.http://www.sciencedirect.com/science/article/pii/S1878535223001697HydrodeoxygenationUpgraded bio-oilMetal oxide catalystZeolite support |
| spellingShingle | Junifa Layla Sihombing Herlinawati Herlinawati Ahmad Nasir Pulungan Lisnawaty Simatupang Rahayu Rahayu Ary Anggara Wibowo Effective hydrodeoxygenation bio-oil via natural zeolite supported transition metal oxide catalyst Arabian Journal of Chemistry Hydrodeoxygenation Upgraded bio-oil Metal oxide catalyst Zeolite support |
| title | Effective hydrodeoxygenation bio-oil via natural zeolite supported transition metal oxide catalyst |
| title_full | Effective hydrodeoxygenation bio-oil via natural zeolite supported transition metal oxide catalyst |
| title_fullStr | Effective hydrodeoxygenation bio-oil via natural zeolite supported transition metal oxide catalyst |
| title_full_unstemmed | Effective hydrodeoxygenation bio-oil via natural zeolite supported transition metal oxide catalyst |
| title_short | Effective hydrodeoxygenation bio-oil via natural zeolite supported transition metal oxide catalyst |
| title_sort | effective hydrodeoxygenation bio oil via natural zeolite supported transition metal oxide catalyst |
| topic | Hydrodeoxygenation Upgraded bio-oil Metal oxide catalyst Zeolite support |
| url | http://www.sciencedirect.com/science/article/pii/S1878535223001697 |
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