The Influence of Microstructured Charcoal Additive on ANFO’s Properties

The verification of the blasting parameters of Ammonium Nitrate Fuel Oil (ANFO) with the addition of microstructured charcoal (MC) produced by destructive wood distillation was performed. Additional investigation of specific surface and pore distribution by the nitrogen adsorption of the two granula...

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Main Authors: Andrzej Biessikirski, Suzana Gotovac Atlagić, Mateusz Pytlik, Łukasz Kuterasiński, Michał Dworzak, Michał Twardosz, Dagmara Nowak-Senderowska, Bogna Daria Napruszewska
Format: Article
Language:English
Published: MDPI AG 2021-07-01
Series:Energies
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Online Access:https://www.mdpi.com/1996-1073/14/14/4354
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author Andrzej Biessikirski
Suzana Gotovac Atlagić
Mateusz Pytlik
Łukasz Kuterasiński
Michał Dworzak
Michał Twardosz
Dagmara Nowak-Senderowska
Bogna Daria Napruszewska
author_facet Andrzej Biessikirski
Suzana Gotovac Atlagić
Mateusz Pytlik
Łukasz Kuterasiński
Michał Dworzak
Michał Twardosz
Dagmara Nowak-Senderowska
Bogna Daria Napruszewska
author_sort Andrzej Biessikirski
collection DOAJ
description The verification of the blasting parameters of Ammonium Nitrate Fuel Oil (ANFO) with the addition of microstructured charcoal (MC) produced by destructive wood distillation was performed. Additional investigation of specific surface and pore distribution by the nitrogen adsorption of the two granulations of MC was also carried out. High-resolution scanning electron microscopy was used for morphology evaluation and revealed smoothening of the initially developed external surface of carbon with intensive milling. In addition, the analysis of the thermal properties of the studied samples (TG/DSC) indicated that the size of the microstructured charcoal additives influenced the decomposition temperature of the prepared materials. The explosives containing microstructured charcoal grains of −90 μm underwent decomposition at lower temperatures in comparison with those containing higher sizes of microstructure charcoal grains (−1.18 mm), for which the decomposition temperature reached 292 °C. The obtained results of blasting parameters compared to the results derived from thermodynamic simulation showed the non-ideal character of the explosives (much lower values of blasting parameters than in established thermodynamic models). It was indicated that higher velocities of detonations (VOD) were obtained for non-ideal explosives where finer MC grains were added. Blasting tests confirmed that the studied type of MC can be applied as an additive to the ANFO.
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spelling doaj.art-22b4e847b64d464f944fbfe02d75fb622023-11-22T03:44:07ZengMDPI AGEnergies1996-10732021-07-011414435410.3390/en14144354The Influence of Microstructured Charcoal Additive on ANFO’s PropertiesAndrzej Biessikirski0Suzana Gotovac Atlagić1Mateusz Pytlik2Łukasz Kuterasiński3Michał Dworzak4Michał Twardosz5Dagmara Nowak-Senderowska6Bogna Daria Napruszewska7Faculty of Civil Engineering and Resource Management, AGH University of Science and Technology, Al. Mickiewicza 30, 30-059 Kraków, PolandFaculty of Natural Sciences and Mathematics, University of Banja Luka, Mladena Stojanovića 2, 78000 Banja Luka, Bosnia and HerzegovinaConformity Assessment Body, Central Mining Institute, Plac Gwarków 1, 40-166 Katowice, PolandJerzy Haber Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, ul. Niezapominajek 8, 30-239 Kraków, PolandFaculty of Civil Engineering and Resource Management, AGH University of Science and Technology, Al. Mickiewicza 30, 30-059 Kraków, PolandFaculty of Civil Engineering and Resource Management, AGH University of Science and Technology, Al. Mickiewicza 30, 30-059 Kraków, PolandFaculty of Civil Engineering and Resource Management, AGH University of Science and Technology, Al. Mickiewicza 30, 30-059 Kraków, PolandJerzy Haber Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, ul. Niezapominajek 8, 30-239 Kraków, PolandThe verification of the blasting parameters of Ammonium Nitrate Fuel Oil (ANFO) with the addition of microstructured charcoal (MC) produced by destructive wood distillation was performed. Additional investigation of specific surface and pore distribution by the nitrogen adsorption of the two granulations of MC was also carried out. High-resolution scanning electron microscopy was used for morphology evaluation and revealed smoothening of the initially developed external surface of carbon with intensive milling. In addition, the analysis of the thermal properties of the studied samples (TG/DSC) indicated that the size of the microstructured charcoal additives influenced the decomposition temperature of the prepared materials. The explosives containing microstructured charcoal grains of −90 μm underwent decomposition at lower temperatures in comparison with those containing higher sizes of microstructure charcoal grains (−1.18 mm), for which the decomposition temperature reached 292 °C. The obtained results of blasting parameters compared to the results derived from thermodynamic simulation showed the non-ideal character of the explosives (much lower values of blasting parameters than in established thermodynamic models). It was indicated that higher velocities of detonations (VOD) were obtained for non-ideal explosives where finer MC grains were added. Blasting tests confirmed that the studied type of MC can be applied as an additive to the ANFO.https://www.mdpi.com/1996-1073/14/14/4354ANFOmicrostructure charcoalexplosivesblasting properties
spellingShingle Andrzej Biessikirski
Suzana Gotovac Atlagić
Mateusz Pytlik
Łukasz Kuterasiński
Michał Dworzak
Michał Twardosz
Dagmara Nowak-Senderowska
Bogna Daria Napruszewska
The Influence of Microstructured Charcoal Additive on ANFO’s Properties
Energies
ANFO
microstructure charcoal
explosives
blasting properties
title The Influence of Microstructured Charcoal Additive on ANFO’s Properties
title_full The Influence of Microstructured Charcoal Additive on ANFO’s Properties
title_fullStr The Influence of Microstructured Charcoal Additive on ANFO’s Properties
title_full_unstemmed The Influence of Microstructured Charcoal Additive on ANFO’s Properties
title_short The Influence of Microstructured Charcoal Additive on ANFO’s Properties
title_sort influence of microstructured charcoal additive on anfo s properties
topic ANFO
microstructure charcoal
explosives
blasting properties
url https://www.mdpi.com/1996-1073/14/14/4354
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