Influence of Carbon Diffusion and the Presence of Oxygen on the Microstructure of Molybdenum Powders Densified by SPS
Due to molybdenum’s Body-Centered Cubic (BCC) crystalline structure, its ductile–brittle transition temperature is sensitive to shaping, purity and microstructure. Dense molybdenum parts are usually shaped by the powder metallurgy process. The aim of this work concerns the spark plasma sintering of...
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MDPI AG
2020-07-01
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| Series: | Metals |
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| Online Access: | https://www.mdpi.com/2075-4701/10/7/948 |
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| author | Mathias Moser Sylvain Lorand Florian Bussiere Frédéric Demoisson Hervé Couque Frédéric Bernard |
| author_facet | Mathias Moser Sylvain Lorand Florian Bussiere Frédéric Demoisson Hervé Couque Frédéric Bernard |
| author_sort | Mathias Moser |
| collection | DOAJ |
| description | Due to molybdenum’s Body-Centered Cubic (BCC) crystalline structure, its ductile–brittle transition temperature is sensitive to shaping, purity and microstructure. Dense molybdenum parts are usually shaped by the powder metallurgy process. The aim of this work concerns the spark plasma sintering of high-purity powders prepared by inductively coupled plasma. The influence of carbon diffusion and its interaction with oxygen on the density (i.e., the densification stage) and on the microstructure (i.e., the grain growth stage) during spark plasma sintering was investigated. The formation of carbide is usually expected for a sintering temperature above 1500 °C leading to grain growth (e.g., more than 10 times larger than the initial powder grain size after sintering at 1900 °C for 10 min). The brittleness was also affected by the segregation of molybdenum carbides at the grain boundaries (i.e., intergranular brittle fracture). Consequently, to reduce the sintering temperature to below 1500 °C, mechanically activated powders were used. From these milled powders, a dense molybdenum disc (60 mm in diameter and 10 mm in thickness) sintered at 1450 °C under a pressure of 70 MPa for 30 min was obtained. It is composed of a fine microstructure without carbide and oxide, its ductility is close to 13% with a maximum resistance of 550 MPa. |
| first_indexed | 2024-03-10T18:28:21Z |
| format | Article |
| id | doaj.art-22c224ed210043afbc0c9b6bdb5a99d4 |
| institution | Directory Open Access Journal |
| issn | 2075-4701 |
| language | English |
| last_indexed | 2024-03-10T18:28:21Z |
| publishDate | 2020-07-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Metals |
| spelling | doaj.art-22c224ed210043afbc0c9b6bdb5a99d42023-11-20T06:46:03ZengMDPI AGMetals2075-47012020-07-0110794810.3390/met10070948Influence of Carbon Diffusion and the Presence of Oxygen on the Microstructure of Molybdenum Powders Densified by SPSMathias Moser0Sylvain Lorand1Florian Bussiere2Frédéric Demoisson3Hervé Couque4Frédéric Bernard5Laboratoire Interdisciplinaire Carnot de Bourgogne, UMR6303 CNRS-Université de Bourgogne-Franche-Comté, BP 47870, 21078 Dijon, FranceLaboratoire Interdisciplinaire Carnot de Bourgogne, UMR6303 CNRS-Université de Bourgogne-Franche-Comté, BP 47870, 21078 Dijon, FranceLaboratoire Interdisciplinaire Carnot de Bourgogne, UMR6303 CNRS-Université de Bourgogne-Franche-Comté, BP 47870, 21078 Dijon, FranceLaboratoire Interdisciplinaire Carnot de Bourgogne, UMR6303 CNRS-Université de Bourgogne-Franche-Comté, BP 47870, 21078 Dijon, FranceNexter Munitions, 18 route de Guerry, 18000 Bourges, FranceLaboratoire Interdisciplinaire Carnot de Bourgogne, UMR6303 CNRS-Université de Bourgogne-Franche-Comté, BP 47870, 21078 Dijon, FranceDue to molybdenum’s Body-Centered Cubic (BCC) crystalline structure, its ductile–brittle transition temperature is sensitive to shaping, purity and microstructure. Dense molybdenum parts are usually shaped by the powder metallurgy process. The aim of this work concerns the spark plasma sintering of high-purity powders prepared by inductively coupled plasma. The influence of carbon diffusion and its interaction with oxygen on the density (i.e., the densification stage) and on the microstructure (i.e., the grain growth stage) during spark plasma sintering was investigated. The formation of carbide is usually expected for a sintering temperature above 1500 °C leading to grain growth (e.g., more than 10 times larger than the initial powder grain size after sintering at 1900 °C for 10 min). The brittleness was also affected by the segregation of molybdenum carbides at the grain boundaries (i.e., intergranular brittle fracture). Consequently, to reduce the sintering temperature to below 1500 °C, mechanically activated powders were used. From these milled powders, a dense molybdenum disc (60 mm in diameter and 10 mm in thickness) sintered at 1450 °C under a pressure of 70 MPa for 30 min was obtained. It is composed of a fine microstructure without carbide and oxide, its ductility is close to 13% with a maximum resistance of 550 MPa.https://www.mdpi.com/2075-4701/10/7/948molybdenumgrain growthcarbon diffusionball millingspark plasma sintering |
| spellingShingle | Mathias Moser Sylvain Lorand Florian Bussiere Frédéric Demoisson Hervé Couque Frédéric Bernard Influence of Carbon Diffusion and the Presence of Oxygen on the Microstructure of Molybdenum Powders Densified by SPS Metals molybdenum grain growth carbon diffusion ball milling spark plasma sintering |
| title | Influence of Carbon Diffusion and the Presence of Oxygen on the Microstructure of Molybdenum Powders Densified by SPS |
| title_full | Influence of Carbon Diffusion and the Presence of Oxygen on the Microstructure of Molybdenum Powders Densified by SPS |
| title_fullStr | Influence of Carbon Diffusion and the Presence of Oxygen on the Microstructure of Molybdenum Powders Densified by SPS |
| title_full_unstemmed | Influence of Carbon Diffusion and the Presence of Oxygen on the Microstructure of Molybdenum Powders Densified by SPS |
| title_short | Influence of Carbon Diffusion and the Presence of Oxygen on the Microstructure of Molybdenum Powders Densified by SPS |
| title_sort | influence of carbon diffusion and the presence of oxygen on the microstructure of molybdenum powders densified by sps |
| topic | molybdenum grain growth carbon diffusion ball milling spark plasma sintering |
| url | https://www.mdpi.com/2075-4701/10/7/948 |
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