The channel structure of trithallium pentaantimonate(V), Tl3Sb5O14
Single crystals of Tl3Sb5O14 were grown by solid-state reaction in a corundum crucible under air (1273 K, 12 h). The structure was determined by single-crystal X-ray diffraction. It is isotypic to the K3Sb5O14, Rb3Sb5O14 and Cs3Sb5O14 analogues with orthorhombic Pbam symmetry and cell parameters a =...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2022-04-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989022002869 |
| _version_ | 1811313143197990912 |
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| author | Paul Sicher Berthold Stöger |
| author_facet | Paul Sicher Berthold Stöger |
| author_sort | Paul Sicher |
| collection | DOAJ |
| description | Single crystals of Tl3Sb5O14 were grown by solid-state reaction in a corundum crucible under air (1273 K, 12 h). The structure was determined by single-crystal X-ray diffraction. It is isotypic to the K3Sb5O14, Rb3Sb5O14 and Cs3Sb5O14 analogues with orthorhombic Pbam symmetry and cell parameters a = 24.2899 (9) Å, b = 7.1931 (3) Å, c = 7.4182 (3) Å. The Sb atoms form irregular [SbO6] octahedra, which are linked via edges and corners into a triperiodic network. The Tl+ ions are located in distinct channels of the network extending along [010] and [001]. |
| first_indexed | 2024-04-13T10:48:44Z |
| format | Article |
| id | doaj.art-22e1d41f269c4a6b9a2cfef7561f080f |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-04-13T10:48:44Z |
| publishDate | 2022-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-22e1d41f269c4a6b9a2cfef7561f080f2022-12-22T02:49:43ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902022-04-0178441441710.1107/S2056989022002869pk2663The channel structure of trithallium pentaantimonate(V), Tl3Sb5O14Paul Sicher0Berthold Stöger1X-Ray Center, TU Wien, Getreidemarkt 9, 1060 Vienna, AustriaX-Ray Center, TU Wien, Getreidemarkt 9, 1060 Vienna, AustriaSingle crystals of Tl3Sb5O14 were grown by solid-state reaction in a corundum crucible under air (1273 K, 12 h). The structure was determined by single-crystal X-ray diffraction. It is isotypic to the K3Sb5O14, Rb3Sb5O14 and Cs3Sb5O14 analogues with orthorhombic Pbam symmetry and cell parameters a = 24.2899 (9) Å, b = 7.1931 (3) Å, c = 7.4182 (3) Å. The Sb atoms form irregular [SbO6] octahedra, which are linked via edges and corners into a triperiodic network. The Tl+ ions are located in distinct channels of the network extending along [010] and [001].http://scripts.iucr.org/cgi-bin/paper?S2056989022002869crystal structurechannel structureantimonate(v) |
| spellingShingle | Paul Sicher Berthold Stöger The channel structure of trithallium pentaantimonate(V), Tl3Sb5O14 Acta Crystallographica Section E: Crystallographic Communications crystal structure channel structure antimonate(v) |
| title | The channel structure of trithallium pentaantimonate(V), Tl3Sb5O14 |
| title_full | The channel structure of trithallium pentaantimonate(V), Tl3Sb5O14 |
| title_fullStr | The channel structure of trithallium pentaantimonate(V), Tl3Sb5O14 |
| title_full_unstemmed | The channel structure of trithallium pentaantimonate(V), Tl3Sb5O14 |
| title_short | The channel structure of trithallium pentaantimonate(V), Tl3Sb5O14 |
| title_sort | channel structure of trithallium pentaantimonate v tl3sb5o14 |
| topic | crystal structure channel structure antimonate(v) |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989022002869 |
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