Bis(3-methylpyridinium) tetra(chlorido/bromido)cuprate(II)
The structure of the title salt, (C6H8N)2[CuCl3.4Br0.6], consists of two 3-methylpyridinium cations and a distorted tetrahedral [CuCl3.4Br0.6]2− dianion. Substitutional disorder with Br is exhibited for three of the Cl atoms of the anion, giving a mixed chloride/bromide cuprate(II) ani...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811019076 |
| _version_ | 1818320173529038848 |
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| author | Young-Inn Kim Hyun-Soo Lim Sung Kwon Kang |
| author_facet | Young-Inn Kim Hyun-Soo Lim Sung Kwon Kang |
| author_sort | Young-Inn Kim |
| collection | DOAJ |
| description | The structure of the title salt, (C6H8N)2[CuCl3.4Br0.6], consists of two 3-methylpyridinium cations and a distorted tetrahedral [CuCl3.4Br0.6]2− dianion. Substitutional disorder with Br is exhibited for three of the Cl atoms of the anion, giving a mixed chloride/bromide cuprate(II) anion. In the crystal, intermolecular N—H...Cl hydrogen bonds link two cations to one anion, forming a three-ion aggregate. These are connected into a supramolecular chain along the b axis via π–π interactions between the pyridinium rings [centroid–centroid distance = 3.743 (3) Å]. |
| first_indexed | 2024-12-13T10:20:48Z |
| format | Article |
| id | doaj.art-23314db8aae842b299c1cb718af86cea |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:20:48Z |
| publishDate | 2011-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-23314db8aae842b299c1cb718af86cea2022-12-21T23:51:11ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-06-01676m793m79410.1107/S1600536811019076Bis(3-methylpyridinium) tetra(chlorido/bromido)cuprate(II)Young-Inn KimHyun-Soo LimSung Kwon KangThe structure of the title salt, (C6H8N)2[CuCl3.4Br0.6], consists of two 3-methylpyridinium cations and a distorted tetrahedral [CuCl3.4Br0.6]2− dianion. Substitutional disorder with Br is exhibited for three of the Cl atoms of the anion, giving a mixed chloride/bromide cuprate(II) anion. In the crystal, intermolecular N—H...Cl hydrogen bonds link two cations to one anion, forming a three-ion aggregate. These are connected into a supramolecular chain along the b axis via π–π interactions between the pyridinium rings [centroid–centroid distance = 3.743 (3) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536811019076 |
| spellingShingle | Young-Inn Kim Hyun-Soo Lim Sung Kwon Kang Bis(3-methylpyridinium) tetra(chlorido/bromido)cuprate(II) Acta Crystallographica Section E |
| title | Bis(3-methylpyridinium) tetra(chlorido/bromido)cuprate(II) |
| title_full | Bis(3-methylpyridinium) tetra(chlorido/bromido)cuprate(II) |
| title_fullStr | Bis(3-methylpyridinium) tetra(chlorido/bromido)cuprate(II) |
| title_full_unstemmed | Bis(3-methylpyridinium) tetra(chlorido/bromido)cuprate(II) |
| title_short | Bis(3-methylpyridinium) tetra(chlorido/bromido)cuprate(II) |
| title_sort | bis 3 methylpyridinium tetra chlorido bromido cuprate ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811019076 |
| work_keys_str_mv | AT younginnkim bis3methylpyridiniumtetrachloridobromidocuprateii AT hyunsoolim bis3methylpyridiniumtetrachloridobromidocuprateii AT sungkwonkang bis3methylpyridiniumtetrachloridobromidocuprateii |