On the adsorbed mass of polymers on surfaces
It is shown that for ideal polymers interacting with a surface via the pseudopotential of a delta function, the number of contacts between the monomer units and the surface as a function of concentration cb is a dependence of the form cb/(1-cb). The architecture of the polymer, the degre...
| Main Author: | |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Serbian Chemical Society
2001-01-01
|
| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2001/0352-51390106403S.pdf |
| _version_ | 1818865792017498112 |
|---|---|
| author | Stratouras Georgios K. |
| author_facet | Stratouras Georgios K. |
| author_sort | Stratouras Georgios K. |
| collection | DOAJ |
| description | It is shown that for ideal polymers interacting with a surface via the
pseudopotential of a delta function, the number of contacts between the
monomer units and the surface as a function of concentration cb is a
dependence of the form cb/(1-cb). The architecture of the polymer, the
degree of polymerization, the interaction energy between a monomer unit and
the surface, the area of the surface and the monomer length are embodied in
the parameters and. The above dependence of the adsorbed mass of a
polymer on the concentration is confirmed by the experimental results of
Takahashi and his collaborators. For linear polystyrene of molecular weight
134 105,interacting with a chrome plate, the parameters and are,
respectively, about equal to (89938/273)-6 m and (-19300/273)m3 kg-1. |
| first_indexed | 2024-12-19T10:53:10Z |
| format | Article |
| id | doaj.art-238c960455c440e7ae050bbd17ab7432 |
| institution | Directory Open Access Journal |
| issn | 0352-5139 1820-7421 |
| language | English |
| last_indexed | 2024-12-19T10:53:10Z |
| publishDate | 2001-01-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-238c960455c440e7ae050bbd17ab74322022-12-21T20:24:54ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212001-01-0166640340910.2298/JSC0106403S0352-51390106403SOn the adsorbed mass of polymers on surfacesStratouras Georgios K.0Akropolis, Nicosia, CyprusIt is shown that for ideal polymers interacting with a surface via the pseudopotential of a delta function, the number of contacts between the monomer units and the surface as a function of concentration cb is a dependence of the form cb/(1-cb). The architecture of the polymer, the degree of polymerization, the interaction energy between a monomer unit and the surface, the area of the surface and the monomer length are embodied in the parameters and. The above dependence of the adsorbed mass of a polymer on the concentration is confirmed by the experimental results of Takahashi and his collaborators. For linear polystyrene of molecular weight 134 105,interacting with a chrome plate, the parameters and are, respectively, about equal to (89938/273)-6 m and (-19300/273)m3 kg-1.http://www.doiserbia.nb.rs/img/doi/0352-5139/2001/0352-51390106403S.pdfadsorbed masspolymerlinearcyclica-b diblock copolymer |
| spellingShingle | Stratouras Georgios K. On the adsorbed mass of polymers on surfaces Journal of the Serbian Chemical Society adsorbed mass polymer linear cyclic a-b diblock copolymer |
| title | On the adsorbed mass of polymers on surfaces |
| title_full | On the adsorbed mass of polymers on surfaces |
| title_fullStr | On the adsorbed mass of polymers on surfaces |
| title_full_unstemmed | On the adsorbed mass of polymers on surfaces |
| title_short | On the adsorbed mass of polymers on surfaces |
| title_sort | on the adsorbed mass of polymers on surfaces |
| topic | adsorbed mass polymer linear cyclic a-b diblock copolymer |
| url | http://www.doiserbia.nb.rs/img/doi/0352-5139/2001/0352-51390106403S.pdf |
| work_keys_str_mv | AT stratourasgeorgiosk ontheadsorbedmassofpolymersonsurfaces |