Removal of Cochineal Dye Color through Atmospheric Pressure Plasma Discharge Jet

The extensive utilization of dyes across diverse industries has resulted in environmental pollution, leading to the degradation of water bodies. To prevent environmental contamination, the use of eco-friendly dyes and innovative processes for dye degradation is crucial. This study aimed to investiga...

Full description

Bibliographic Details
Main Authors: Arturo Quispe-Quispe, Luis F. Pérez-Falcón, Justiniano Quispe-Marcatoma, Carlos V. Landauro, Victor A. Peña Rodriguez
Format: Article
Language:English
Published: MDPI AG 2024-01-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/14/2/680
_version_ 1797340129240547328
author Arturo Quispe-Quispe
Luis F. Pérez-Falcón
Justiniano Quispe-Marcatoma
Carlos V. Landauro
Victor A. Peña Rodriguez
author_facet Arturo Quispe-Quispe
Luis F. Pérez-Falcón
Justiniano Quispe-Marcatoma
Carlos V. Landauro
Victor A. Peña Rodriguez
author_sort Arturo Quispe-Quispe
collection DOAJ
description The extensive utilization of dyes across diverse industries has resulted in environmental pollution, leading to the degradation of water bodies. To prevent environmental contamination, the use of eco-friendly dyes and innovative processes for dye degradation is crucial. This study aimed to investigate the color removal process of cochineal dye (Dactylopius coccus Costa) using the atmospheric pressure plasma jet (APPJ: Atmospheric Pressure Plasma Jet) technique. The dye extracted from the cochineal insect was treated with APPJ and the resulting color removal process was analyzed. Optical emission spectroscopy (OES) was used to investigate the plasma emission lines, and UV-Vis spectroscopy was used to monitor the color removal process. The results revealed that the decolorization of cochineal dye was a result of an oxidative degradation process caused by the interaction of the reactive species (NO<sub>3</sub><sup>−</sup> and NO<sub>2</sub><sup>−</sup>) generated by the APPJ plasma discharge with the dye molecules. This color removal process occurs in an acidic medium, leading to a pH change from 5.4 to 2.7. These pH changes can be attributed to fluctuations in the concentrations of reactive species such as nitrates and nitrites in the liquid phase. UV-Vis spectroscopy measurements showed that 90% of the cochineal color was removed within the first 10 min of treatment. This study enhances our understanding of natural color removal and provides insights into its mechanism, opening up possibilities for controlled modification and applications in various fields.
first_indexed 2024-03-08T09:58:30Z
format Article
id doaj.art-238d402ebc7c4fbb9135fc874ca2a433
institution Directory Open Access Journal
issn 2076-3417
language English
last_indexed 2024-03-08T09:58:30Z
publishDate 2024-01-01
publisher MDPI AG
record_format Article
series Applied Sciences
spelling doaj.art-238d402ebc7c4fbb9135fc874ca2a4332024-01-29T13:43:39ZengMDPI AGApplied Sciences2076-34172024-01-0114268010.3390/app14020680Removal of Cochineal Dye Color through Atmospheric Pressure Plasma Discharge JetArturo Quispe-Quispe0Luis F. Pérez-Falcón1Justiniano Quispe-Marcatoma2Carlos V. Landauro3Victor A. Peña Rodriguez4Facultad de Ingeniería, Universidad Nacional Micaela Bastidas de Apurímac, Av. Garcilaso de la Vega, Abancay 03300, PeruFacultad de Ingeniería, Universidad Nacional Micaela Bastidas de Apurímac, Av. Garcilaso de la Vega, Abancay 03300, PeruFacultad de Ciencias Físicas, Universidad Nacional Mayor de San Marcos, Lima 15081, PeruFacultad de Ciencias Físicas, Universidad Nacional Mayor de San Marcos, Lima 15081, PeruFacultad de Ciencias Físicas, Universidad Nacional Mayor de San Marcos, Lima 15081, PeruThe extensive utilization of dyes across diverse industries has resulted in environmental pollution, leading to the degradation of water bodies. To prevent environmental contamination, the use of eco-friendly dyes and innovative processes for dye degradation is crucial. This study aimed to investigate the color removal process of cochineal dye (Dactylopius coccus Costa) using the atmospheric pressure plasma jet (APPJ: Atmospheric Pressure Plasma Jet) technique. The dye extracted from the cochineal insect was treated with APPJ and the resulting color removal process was analyzed. Optical emission spectroscopy (OES) was used to investigate the plasma emission lines, and UV-Vis spectroscopy was used to monitor the color removal process. The results revealed that the decolorization of cochineal dye was a result of an oxidative degradation process caused by the interaction of the reactive species (NO<sub>3</sub><sup>−</sup> and NO<sub>2</sub><sup>−</sup>) generated by the APPJ plasma discharge with the dye molecules. This color removal process occurs in an acidic medium, leading to a pH change from 5.4 to 2.7. These pH changes can be attributed to fluctuations in the concentrations of reactive species such as nitrates and nitrites in the liquid phase. UV-Vis spectroscopy measurements showed that 90% of the cochineal color was removed within the first 10 min of treatment. This study enhances our understanding of natural color removal and provides insights into its mechanism, opening up possibilities for controlled modification and applications in various fields.https://www.mdpi.com/2076-3417/14/2/680oxidative degradationcochineal dyeAPPJ technique
spellingShingle Arturo Quispe-Quispe
Luis F. Pérez-Falcón
Justiniano Quispe-Marcatoma
Carlos V. Landauro
Victor A. Peña Rodriguez
Removal of Cochineal Dye Color through Atmospheric Pressure Plasma Discharge Jet
Applied Sciences
oxidative degradation
cochineal dye
APPJ technique
title Removal of Cochineal Dye Color through Atmospheric Pressure Plasma Discharge Jet
title_full Removal of Cochineal Dye Color through Atmospheric Pressure Plasma Discharge Jet
title_fullStr Removal of Cochineal Dye Color through Atmospheric Pressure Plasma Discharge Jet
title_full_unstemmed Removal of Cochineal Dye Color through Atmospheric Pressure Plasma Discharge Jet
title_short Removal of Cochineal Dye Color through Atmospheric Pressure Plasma Discharge Jet
title_sort removal of cochineal dye color through atmospheric pressure plasma discharge jet
topic oxidative degradation
cochineal dye
APPJ technique
url https://www.mdpi.com/2076-3417/14/2/680
work_keys_str_mv AT arturoquispequispe removalofcochinealdyecolorthroughatmosphericpressureplasmadischargejet
AT luisfperezfalcon removalofcochinealdyecolorthroughatmosphericpressureplasmadischargejet
AT justinianoquispemarcatoma removalofcochinealdyecolorthroughatmosphericpressureplasmadischargejet
AT carlosvlandauro removalofcochinealdyecolorthroughatmosphericpressureplasmadischargejet
AT victorapenarodriguez removalofcochinealdyecolorthroughatmosphericpressureplasmadischargejet