Heterometallic Complexes Containing the Ni<sup>II</sup>-Ln<sup>III</sup>-Ni<sup>II</sup> Moiety—Structures and Magnetic Properties
This review summarizes the structural characteristics and magnetic properties of trinuclear complexes containing the Ni<sup>II</sup>-Ln<sup>III</sup>-Ni<sup>II</sup> moiety and also oligonuclear complexes and coordination polymers containing the same trinuclear mo...
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| Format: | Article |
| Language: | English |
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MDPI AG
2020-12-01
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| Series: | Crystals |
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| Online Access: | https://www.mdpi.com/2073-4352/10/12/1117 |
| _version_ | 1797545360432824320 |
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| author | Catherine P. Raptopoulou |
| author_facet | Catherine P. Raptopoulou |
| author_sort | Catherine P. Raptopoulou |
| collection | DOAJ |
| description | This review summarizes the structural characteristics and magnetic properties of trinuclear complexes containing the Ni<sup>II</sup>-Ln<sup>III</sup>-Ni<sup>II</sup> moiety and also oligonuclear complexes and coordination polymers containing the same trinuclear moiety. The ligands used are mainly polydentate Schiff base ligands and reduced Schiff base ligands and, in some cases, oximato, β-diketonato, pyridyl ketone ligands and others. The compounds reported are restricted to those containing one, two and three oxygen atoms as bridges between the metal ions; examples of carboxylato and oximato bridging are also included due to structural similarity. The magnetic properties of the complexes range from ferro- to antiferromagnetic depending on the nature of the lanthanide ion. |
| first_indexed | 2024-03-10T14:14:20Z |
| format | Article |
| id | doaj.art-238d9771a94f453b90445a32ccb592f5 |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-03-10T14:14:20Z |
| publishDate | 2020-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-238d9771a94f453b90445a32ccb592f52023-11-20T23:53:31ZengMDPI AGCrystals2073-43522020-12-011012111710.3390/cryst10121117Heterometallic Complexes Containing the Ni<sup>II</sup>-Ln<sup>III</sup>-Ni<sup>II</sup> Moiety—Structures and Magnetic PropertiesCatherine P. Raptopoulou0Institute of Nanoscience and Nanotechnology, NCSR “Demokritos”, Aghia Paraskevi, 15310 Athens, GreeceThis review summarizes the structural characteristics and magnetic properties of trinuclear complexes containing the Ni<sup>II</sup>-Ln<sup>III</sup>-Ni<sup>II</sup> moiety and also oligonuclear complexes and coordination polymers containing the same trinuclear moiety. The ligands used are mainly polydentate Schiff base ligands and reduced Schiff base ligands and, in some cases, oximato, β-diketonato, pyridyl ketone ligands and others. The compounds reported are restricted to those containing one, two and three oxygen atoms as bridges between the metal ions; examples of carboxylato and oximato bridging are also included due to structural similarity. The magnetic properties of the complexes range from ferro- to antiferromagnetic depending on the nature of the lanthanide ion.https://www.mdpi.com/2073-4352/10/12/1117heterometallic complexestrinuclear moietynickel(II)lanthanide(III) ionscrystal structuresmagnetic properties |
| spellingShingle | Catherine P. Raptopoulou Heterometallic Complexes Containing the Ni<sup>II</sup>-Ln<sup>III</sup>-Ni<sup>II</sup> Moiety—Structures and Magnetic Properties Crystals heterometallic complexes trinuclear moiety nickel(II) lanthanide(III) ions crystal structures magnetic properties |
| title | Heterometallic Complexes Containing the Ni<sup>II</sup>-Ln<sup>III</sup>-Ni<sup>II</sup> Moiety—Structures and Magnetic Properties |
| title_full | Heterometallic Complexes Containing the Ni<sup>II</sup>-Ln<sup>III</sup>-Ni<sup>II</sup> Moiety—Structures and Magnetic Properties |
| title_fullStr | Heterometallic Complexes Containing the Ni<sup>II</sup>-Ln<sup>III</sup>-Ni<sup>II</sup> Moiety—Structures and Magnetic Properties |
| title_full_unstemmed | Heterometallic Complexes Containing the Ni<sup>II</sup>-Ln<sup>III</sup>-Ni<sup>II</sup> Moiety—Structures and Magnetic Properties |
| title_short | Heterometallic Complexes Containing the Ni<sup>II</sup>-Ln<sup>III</sup>-Ni<sup>II</sup> Moiety—Structures and Magnetic Properties |
| title_sort | heterometallic complexes containing the ni sup ii sup ln sup iii sup ni sup ii sup moiety structures and magnetic properties |
| topic | heterometallic complexes trinuclear moiety nickel(II) lanthanide(III) ions crystal structures magnetic properties |
| url | https://www.mdpi.com/2073-4352/10/12/1117 |
| work_keys_str_mv | AT catherinepraptopoulou heterometalliccomplexescontainingthenisupiisuplnsupiiisupnisupiisupmoietystructuresandmagneticproperties |