Effect of Silane Functionalization on Properties of Poly(Lactic Acid)/Palygorskite Nanocomposites
Poly(lactic acid) (PLA)/palygorskite (Paly) nanocomposites were prepared using the melt compounding technique. Paly modified by 3-aminopropyltriethoxysilane (APTES) and vinyltrimethoxysilane (VTMS) was used as nanofiller for PLA with concentrations in the 1–7 wt% range. It has been found that the fu...
Main Authors: | , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2021-01-01
|
Series: | Inorganics |
Subjects: | |
Online Access: | https://www.mdpi.com/2304-6740/9/1/3 |
_version_ | 1797542584832229376 |
---|---|
author | Anton Kasprzhitskii Georgy Lazorenko Alexander Kruglikov Irina Kuchkina Vadim Gorodov |
author_facet | Anton Kasprzhitskii Georgy Lazorenko Alexander Kruglikov Irina Kuchkina Vadim Gorodov |
author_sort | Anton Kasprzhitskii |
collection | DOAJ |
description | Poly(lactic acid) (PLA)/palygorskite (Paly) nanocomposites were prepared using the melt compounding technique. Paly modified by 3-aminopropyltriethoxysilane (APTES) and vinyltrimethoxysilane (VTMS) was used as nanofiller for PLA with concentrations in the 1–7 wt% range. It has been found that the functionalization allows a covalent bond between the hydroxyl groups of the Paly and the PLA matrix, evidenced by the improvement in mechanical properties. Paly modification with VTMS has better properties compared with Pale modification with APTES. This indicates a better adhesion between the Paly-VTMS and PLA matrix, and a good dispersion of the nanofiller in the polymer matrix. |
first_indexed | 2024-03-10T13:32:38Z |
format | Article |
id | doaj.art-23ba559d7538489ebfdac89ffa72942b |
institution | Directory Open Access Journal |
issn | 2304-6740 |
language | English |
last_indexed | 2024-03-10T13:32:38Z |
publishDate | 2021-01-01 |
publisher | MDPI AG |
record_format | Article |
series | Inorganics |
spelling | doaj.art-23ba559d7538489ebfdac89ffa72942b2023-11-21T07:45:07ZengMDPI AGInorganics2304-67402021-01-0191310.3390/inorganics9010003Effect of Silane Functionalization on Properties of Poly(Lactic Acid)/Palygorskite NanocompositesAnton Kasprzhitskii0Georgy Lazorenko1Alexander Kruglikov2Irina Kuchkina3Vadim Gorodov4Department of Physics, Rostov State Transport University, Narodnogo Opolcheniya Sq., 344038 Rostov-on-Don, RussiaDepartment of Physics, Rostov State Transport University, Narodnogo Opolcheniya Sq., 344038 Rostov-on-Don, RussiaDepartment of Physics, Rostov State Transport University, Narodnogo Opolcheniya Sq., 344038 Rostov-on-Don, RussiaEnikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, 70 Profsoyuznaya Street, 117393 Moscow, RussiaNesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova Street, 119991 Moscow, RussiaPoly(lactic acid) (PLA)/palygorskite (Paly) nanocomposites were prepared using the melt compounding technique. Paly modified by 3-aminopropyltriethoxysilane (APTES) and vinyltrimethoxysilane (VTMS) was used as nanofiller for PLA with concentrations in the 1–7 wt% range. It has been found that the functionalization allows a covalent bond between the hydroxyl groups of the Paly and the PLA matrix, evidenced by the improvement in mechanical properties. Paly modification with VTMS has better properties compared with Pale modification with APTES. This indicates a better adhesion between the Paly-VTMS and PLA matrix, and a good dispersion of the nanofiller in the polymer matrix.https://www.mdpi.com/2304-6740/9/1/3palygorskitecoupling agentpoly(lactic acid)3-aminopropyltriethoxysilanevinyltrimethoxysilane |
spellingShingle | Anton Kasprzhitskii Georgy Lazorenko Alexander Kruglikov Irina Kuchkina Vadim Gorodov Effect of Silane Functionalization on Properties of Poly(Lactic Acid)/Palygorskite Nanocomposites Inorganics palygorskite coupling agent poly(lactic acid) 3-aminopropyltriethoxysilane vinyltrimethoxysilane |
title | Effect of Silane Functionalization on Properties of Poly(Lactic Acid)/Palygorskite Nanocomposites |
title_full | Effect of Silane Functionalization on Properties of Poly(Lactic Acid)/Palygorskite Nanocomposites |
title_fullStr | Effect of Silane Functionalization on Properties of Poly(Lactic Acid)/Palygorskite Nanocomposites |
title_full_unstemmed | Effect of Silane Functionalization on Properties of Poly(Lactic Acid)/Palygorskite Nanocomposites |
title_short | Effect of Silane Functionalization on Properties of Poly(Lactic Acid)/Palygorskite Nanocomposites |
title_sort | effect of silane functionalization on properties of poly lactic acid palygorskite nanocomposites |
topic | palygorskite coupling agent poly(lactic acid) 3-aminopropyltriethoxysilane vinyltrimethoxysilane |
url | https://www.mdpi.com/2304-6740/9/1/3 |
work_keys_str_mv | AT antonkasprzhitskii effectofsilanefunctionalizationonpropertiesofpolylacticacidpalygorskitenanocomposites AT georgylazorenko effectofsilanefunctionalizationonpropertiesofpolylacticacidpalygorskitenanocomposites AT alexanderkruglikov effectofsilanefunctionalizationonpropertiesofpolylacticacidpalygorskitenanocomposites AT irinakuchkina effectofsilanefunctionalizationonpropertiesofpolylacticacidpalygorskitenanocomposites AT vadimgorodov effectofsilanefunctionalizationonpropertiesofpolylacticacidpalygorskitenanocomposites |