Surface Functionalization of Cotton Fabrics by Photo-Grafting for pH Sensing Applications

This paper investigates the photo-grafting of a halochromic molecule on cotton fabric surfaces. Nitrazine yellow (NY) dye was modified with a methacrylate moiety (GMA) obtaining a photo-reactive dye (GMA-NY), which was covalently grafted onto the cellulosic substrate by means of UV irradiation. The...

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Main Authors: Parnian Kianfar, Molla Tadesse Abate, Valentina Trovato, Giuseppe Rosace, Ada Ferri, Roberta Bongiovanni, Alessandra Vitale
Format: Article
Language:English
Published: Frontiers Media S.A. 2020-02-01
Series:Frontiers in Materials
Subjects:
Online Access:https://www.frontiersin.org/article/10.3389/fmats.2020.00039/full
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author Parnian Kianfar
Molla Tadesse Abate
Valentina Trovato
Giuseppe Rosace
Ada Ferri
Roberta Bongiovanni
Alessandra Vitale
author_facet Parnian Kianfar
Molla Tadesse Abate
Valentina Trovato
Giuseppe Rosace
Ada Ferri
Roberta Bongiovanni
Alessandra Vitale
author_sort Parnian Kianfar
collection DOAJ
description This paper investigates the photo-grafting of a halochromic molecule on cotton fabric surfaces. Nitrazine yellow (NY) dye was modified with a methacrylate moiety (GMA) obtaining a photo-reactive dye (GMA-NY), which was covalently grafted onto the cellulosic substrate by means of UV irradiation. The photo-grafting reaction was studied by FT-IR spectroscopy, while the pH response of the functionalized fabric was evaluated at different pH conditions (i.e., acidic and alkaline conditions) both in wet and vapor environments by spectrophotometric analyses. The results showed that the photo-grafting of the modified dye onto the fabric was successful: treated cotton clearly changed color when subjected to different pH. It was thus demonstrated that the GMA-NY dye, photo-grafted on cotton, can successfully impart pH sensing properties to the fabric, which can therefore find numerous applications in the area of smart textiles.
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spelling doaj.art-23cc072a27444af78270e80be34716082022-12-22T00:06:32ZengFrontiers Media S.A.Frontiers in Materials2296-80162020-02-01710.3389/fmats.2020.00039489091Surface Functionalization of Cotton Fabrics by Photo-Grafting for pH Sensing ApplicationsParnian Kianfar0Molla Tadesse Abate1Valentina Trovato2Giuseppe Rosace3Ada Ferri4Roberta Bongiovanni5Alessandra Vitale6Department of Applied Science and Technology, Politecnico di Torino, Turin, ItalyDepartment of Applied Science and Technology, Politecnico di Torino, Turin, ItalyDepartment of Engineering and Applied Sciences, University of Bergamo, Bergamo, ItalyDepartment of Engineering and Applied Sciences, University of Bergamo, Bergamo, ItalyDepartment of Applied Science and Technology, Politecnico di Torino, Turin, ItalyDepartment of Applied Science and Technology, Politecnico di Torino, Turin, ItalyDepartment of Applied Science and Technology, Politecnico di Torino, Turin, ItalyThis paper investigates the photo-grafting of a halochromic molecule on cotton fabric surfaces. Nitrazine yellow (NY) dye was modified with a methacrylate moiety (GMA) obtaining a photo-reactive dye (GMA-NY), which was covalently grafted onto the cellulosic substrate by means of UV irradiation. The photo-grafting reaction was studied by FT-IR spectroscopy, while the pH response of the functionalized fabric was evaluated at different pH conditions (i.e., acidic and alkaline conditions) both in wet and vapor environments by spectrophotometric analyses. The results showed that the photo-grafting of the modified dye onto the fabric was successful: treated cotton clearly changed color when subjected to different pH. It was thus demonstrated that the GMA-NY dye, photo-grafted on cotton, can successfully impart pH sensing properties to the fabric, which can therefore find numerous applications in the area of smart textiles.https://www.frontiersin.org/article/10.3389/fmats.2020.00039/fullphoto-graftingpH sensingcotton functionalizationhalochromic dyesmart textileswearable sensors
spellingShingle Parnian Kianfar
Molla Tadesse Abate
Valentina Trovato
Giuseppe Rosace
Ada Ferri
Roberta Bongiovanni
Alessandra Vitale
Surface Functionalization of Cotton Fabrics by Photo-Grafting for pH Sensing Applications
Frontiers in Materials
photo-grafting
pH sensing
cotton functionalization
halochromic dye
smart textiles
wearable sensors
title Surface Functionalization of Cotton Fabrics by Photo-Grafting for pH Sensing Applications
title_full Surface Functionalization of Cotton Fabrics by Photo-Grafting for pH Sensing Applications
title_fullStr Surface Functionalization of Cotton Fabrics by Photo-Grafting for pH Sensing Applications
title_full_unstemmed Surface Functionalization of Cotton Fabrics by Photo-Grafting for pH Sensing Applications
title_short Surface Functionalization of Cotton Fabrics by Photo-Grafting for pH Sensing Applications
title_sort surface functionalization of cotton fabrics by photo grafting for ph sensing applications
topic photo-grafting
pH sensing
cotton functionalization
halochromic dye
smart textiles
wearable sensors
url https://www.frontiersin.org/article/10.3389/fmats.2020.00039/full
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AT valentinatrovato surfacefunctionalizationofcottonfabricsbyphotograftingforphsensingapplications
AT giusepperosace surfacefunctionalizationofcottonfabricsbyphotograftingforphsensingapplications
AT adaferri surfacefunctionalizationofcottonfabricsbyphotograftingforphsensingapplications
AT robertabongiovanni surfacefunctionalizationofcottonfabricsbyphotograftingforphsensingapplications
AT alessandravitale surfacefunctionalizationofcottonfabricsbyphotograftingforphsensingapplications