Directional DC Charge-Transfer Resistance on an Electrode–Electrolyte Interface in an AC Nyquist Curve on Lead-Acid Battery

Both the frequency domain Nyquist curve of electrochemical impedance spectroscopy (EIS) and time domain simulation of DC equivalent first principle linear circuit (<i>FPLC<sub>DCequ</sub></i>) are some of the fundamentals of lead-acid batteries management system design. The N...

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Main Authors: Wubin Wang, Wenxi Yao, Wei Chen, Dong Chen, Zhen Ma, Zhengyu Lu
Format: Article
Language:English
Published: MDPI AG 2020-03-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/10/6/1907
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author Wubin Wang
Wenxi Yao
Wei Chen
Dong Chen
Zhen Ma
Zhengyu Lu
author_facet Wubin Wang
Wenxi Yao
Wei Chen
Dong Chen
Zhen Ma
Zhengyu Lu
author_sort Wubin Wang
collection DOAJ
description Both the frequency domain Nyquist curve of electrochemical impedance spectroscopy (EIS) and time domain simulation of DC equivalent first principle linear circuit (<i>FPLC<sub>DCequ</sub></i>) are some of the fundamentals of lead-acid batteries management system design. The Nyquist curve is used to evaluate batteries&#8217; state of health (SoH), but the curve does not distinguish charging/discharging impedances on electrode&#8722;electrolyte interfaces in the frequency domain. <i>FPLC<sub>DCequ</sub></i> is used to simulate batteries&#8217; terminal electrical variables, and the circuit distinguishes charging/discharging impedances on electrode&#8722;electrolyte interfaces in the time domain. Therefore, there is no direct physical relationship between Nyquist and <i>FPLC<sub>DCequ</sub></i> This paper proposes an AC equivalent first principle linear circuit (<i>FPLC<sub>ACequ</sub></i>) by average switch modeling, and the novel circuit distinguishes charging/discharging impedances on electrode&#8722;electrolyte interfaces in Nyquist. The novel circuit establishes a physical bridge between Nyquist and <i>FPLC<sub>DCequ</sub></i> for lead-acid batteries management system design.
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spelling doaj.art-23cf25fc51d643f58dd02b40508beaf82022-12-22T02:04:43ZengMDPI AGApplied Sciences2076-34172020-03-01106190710.3390/app10061907app10061907Directional DC Charge-Transfer Resistance on an Electrode–Electrolyte Interface in an AC Nyquist Curve on Lead-Acid BatteryWubin Wang0Wenxi Yao1Wei Chen2Dong Chen3Zhen Ma4Zhengyu Lu5College of Electrical Engineering, Zhejiang University, Hangzhou 310027, ChinaCollege of Electrical Engineering, Zhejiang University, Hangzhou 310027, ChinaZhejiang Narada Power Source Co., Ltd., Hangzhou 310030, ChinaZhejiang Narada Power Source Co., Ltd., Hangzhou 310030, ChinaShanghai Institute of Space Power-sources, Shanghai 200245, ChinaCollege of Electrical Engineering, Zhejiang University, Hangzhou 310027, ChinaBoth the frequency domain Nyquist curve of electrochemical impedance spectroscopy (EIS) and time domain simulation of DC equivalent first principle linear circuit (<i>FPLC<sub>DCequ</sub></i>) are some of the fundamentals of lead-acid batteries management system design. The Nyquist curve is used to evaluate batteries&#8217; state of health (SoH), but the curve does not distinguish charging/discharging impedances on electrode&#8722;electrolyte interfaces in the frequency domain. <i>FPLC<sub>DCequ</sub></i> is used to simulate batteries&#8217; terminal electrical variables, and the circuit distinguishes charging/discharging impedances on electrode&#8722;electrolyte interfaces in the time domain. Therefore, there is no direct physical relationship between Nyquist and <i>FPLC<sub>DCequ</sub></i> This paper proposes an AC equivalent first principle linear circuit (<i>FPLC<sub>ACequ</sub></i>) by average switch modeling, and the novel circuit distinguishes charging/discharging impedances on electrode&#8722;electrolyte interfaces in Nyquist. The novel circuit establishes a physical bridge between Nyquist and <i>FPLC<sub>DCequ</sub></i> for lead-acid batteries management system design.https://www.mdpi.com/2076-3417/10/6/1907state of healthstate of chargelead-acid batteryelectrochemical impedance spectroscopybattery management systemcharge-transfer resistancedouble-layer capacitancefirst principle circuitbehavioral circuitpower electronicsaverage switch modeling
spellingShingle Wubin Wang
Wenxi Yao
Wei Chen
Dong Chen
Zhen Ma
Zhengyu Lu
Directional DC Charge-Transfer Resistance on an Electrode–Electrolyte Interface in an AC Nyquist Curve on Lead-Acid Battery
Applied Sciences
state of health
state of charge
lead-acid battery
electrochemical impedance spectroscopy
battery management system
charge-transfer resistance
double-layer capacitance
first principle circuit
behavioral circuit
power electronics
average switch modeling
title Directional DC Charge-Transfer Resistance on an Electrode–Electrolyte Interface in an AC Nyquist Curve on Lead-Acid Battery
title_full Directional DC Charge-Transfer Resistance on an Electrode–Electrolyte Interface in an AC Nyquist Curve on Lead-Acid Battery
title_fullStr Directional DC Charge-Transfer Resistance on an Electrode–Electrolyte Interface in an AC Nyquist Curve on Lead-Acid Battery
title_full_unstemmed Directional DC Charge-Transfer Resistance on an Electrode–Electrolyte Interface in an AC Nyquist Curve on Lead-Acid Battery
title_short Directional DC Charge-Transfer Resistance on an Electrode–Electrolyte Interface in an AC Nyquist Curve on Lead-Acid Battery
title_sort directional dc charge transfer resistance on an electrode electrolyte interface in an ac nyquist curve on lead acid battery
topic state of health
state of charge
lead-acid battery
electrochemical impedance spectroscopy
battery management system
charge-transfer resistance
double-layer capacitance
first principle circuit
behavioral circuit
power electronics
average switch modeling
url https://www.mdpi.com/2076-3417/10/6/1907
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AT zhenma directionaldcchargetransferresistanceonanelectrodeelectrolyteinterfaceinanacnyquistcurveonleadacidbattery
AT zhengyulu directionaldcchargetransferresistanceonanelectrodeelectrolyteinterfaceinanacnyquistcurveonleadacidbattery