The Influence of Green Surface Modification of Oil Palm Mesocarp Fiber by Superheated Steam on the Mechanical Properties and Dimensional Stability of Oil Palm Mesocarp Fiber/Poly(butylene succinate) Biocomposite
In this paper, superheated steam (SHS) was used as cost effective and green processing technique to modify oil palm mesocarp fiber (OPMF) for biocomposite applications. The purpose of this modification was to promote the adhesion between fiber and thermoplastic. The modification was carried out in a...
Main Authors: | , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2014-08-01
|
Series: | International Journal of Molecular Sciences |
Subjects: | |
Online Access: | http://www.mdpi.com/1422-0067/15/9/15344 |
_version_ | 1811327047097647104 |
---|---|
author | Yoon Yee Then Nor Azowa Ibrahim Norhazlin Zainuddin Hidayah Ariffin Wan Md Zin Wan Yunus Buong Woei Chieng |
author_facet | Yoon Yee Then Nor Azowa Ibrahim Norhazlin Zainuddin Hidayah Ariffin Wan Md Zin Wan Yunus Buong Woei Chieng |
author_sort | Yoon Yee Then |
collection | DOAJ |
description | In this paper, superheated steam (SHS) was used as cost effective and green processing technique to modify oil palm mesocarp fiber (OPMF) for biocomposite applications. The purpose of this modification was to promote the adhesion between fiber and thermoplastic. The modification was carried out in a SHS oven at various temperature (200–230 °C) and time (30–120 min) under normal atmospheric pressure. The biocomposites from SHS-treated OPMFs and poly(butylene succinate) (PBS) at a weight ratio of 70:30 were prepared by melt blending technique. The mechanical properties and dimensional stability of the biocomposites were evaluated. This study showed that the SHS treatment increased the roughness of the fiber surface due to the removal of surface impurities and hemicellulose. The tensile, flexural and impact properties, as well as dimensional stability of the biocomposites were markedly enhanced by the presence of SHS-treated OPMF. Scanning electron microscopy analysis showed improvement of interfacial adhesion between PBS and SHS-treated OPMF. This work demonstrated that SHS could be used as an eco-friendly and sustainable processing method for modification of OPMF in biocomposite fabrication. |
first_indexed | 2024-04-13T14:59:46Z |
format | Article |
id | doaj.art-23f8e48f7eab400f82709a026298c8bf |
institution | Directory Open Access Journal |
issn | 1422-0067 |
language | English |
last_indexed | 2024-04-13T14:59:46Z |
publishDate | 2014-08-01 |
publisher | MDPI AG |
record_format | Article |
series | International Journal of Molecular Sciences |
spelling | doaj.art-23f8e48f7eab400f82709a026298c8bf2022-12-22T02:42:20ZengMDPI AGInternational Journal of Molecular Sciences1422-00672014-08-01159153441535710.3390/ijms150915344ijms150915344The Influence of Green Surface Modification of Oil Palm Mesocarp Fiber by Superheated Steam on the Mechanical Properties and Dimensional Stability of Oil Palm Mesocarp Fiber/Poly(butylene succinate) BiocompositeYoon Yee Then0Nor Azowa Ibrahim1Norhazlin Zainuddin2Hidayah Ariffin3Wan Md Zin Wan Yunus4Buong Woei Chieng5Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, MalaysiaDepartment of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, MalaysiaDepartment of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, MalaysiaDepartment of Bioprocess Technology, Faculty of Biotechnology and Biomolecular Sciences, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, MalaysiaDepartment of Chemistry, Centre For Defence Foundation Studies, National Defence University of Malaysia, Sungai Besi Camp, 57000 Kuala Lumpur, Federal Territory of Kuala Lumpur, MalaysiaDepartment of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, MalaysiaIn this paper, superheated steam (SHS) was used as cost effective and green processing technique to modify oil palm mesocarp fiber (OPMF) for biocomposite applications. The purpose of this modification was to promote the adhesion between fiber and thermoplastic. The modification was carried out in a SHS oven at various temperature (200–230 °C) and time (30–120 min) under normal atmospheric pressure. The biocomposites from SHS-treated OPMFs and poly(butylene succinate) (PBS) at a weight ratio of 70:30 were prepared by melt blending technique. The mechanical properties and dimensional stability of the biocomposites were evaluated. This study showed that the SHS treatment increased the roughness of the fiber surface due to the removal of surface impurities and hemicellulose. The tensile, flexural and impact properties, as well as dimensional stability of the biocomposites were markedly enhanced by the presence of SHS-treated OPMF. Scanning electron microscopy analysis showed improvement of interfacial adhesion between PBS and SHS-treated OPMF. This work demonstrated that SHS could be used as an eco-friendly and sustainable processing method for modification of OPMF in biocomposite fabrication.http://www.mdpi.com/1422-0067/15/9/15344biocompositedimensional stabilitymechanical propertiesoil palm mesocarp fiberpoly(butylene succinate)superheated steam |
spellingShingle | Yoon Yee Then Nor Azowa Ibrahim Norhazlin Zainuddin Hidayah Ariffin Wan Md Zin Wan Yunus Buong Woei Chieng The Influence of Green Surface Modification of Oil Palm Mesocarp Fiber by Superheated Steam on the Mechanical Properties and Dimensional Stability of Oil Palm Mesocarp Fiber/Poly(butylene succinate) Biocomposite International Journal of Molecular Sciences biocomposite dimensional stability mechanical properties oil palm mesocarp fiber poly(butylene succinate) superheated steam |
title | The Influence of Green Surface Modification of Oil Palm Mesocarp Fiber by Superheated Steam on the Mechanical Properties and Dimensional Stability of Oil Palm Mesocarp Fiber/Poly(butylene succinate) Biocomposite |
title_full | The Influence of Green Surface Modification of Oil Palm Mesocarp Fiber by Superheated Steam on the Mechanical Properties and Dimensional Stability of Oil Palm Mesocarp Fiber/Poly(butylene succinate) Biocomposite |
title_fullStr | The Influence of Green Surface Modification of Oil Palm Mesocarp Fiber by Superheated Steam on the Mechanical Properties and Dimensional Stability of Oil Palm Mesocarp Fiber/Poly(butylene succinate) Biocomposite |
title_full_unstemmed | The Influence of Green Surface Modification of Oil Palm Mesocarp Fiber by Superheated Steam on the Mechanical Properties and Dimensional Stability of Oil Palm Mesocarp Fiber/Poly(butylene succinate) Biocomposite |
title_short | The Influence of Green Surface Modification of Oil Palm Mesocarp Fiber by Superheated Steam on the Mechanical Properties and Dimensional Stability of Oil Palm Mesocarp Fiber/Poly(butylene succinate) Biocomposite |
title_sort | influence of green surface modification of oil palm mesocarp fiber by superheated steam on the mechanical properties and dimensional stability of oil palm mesocarp fiber poly butylene succinate biocomposite |
topic | biocomposite dimensional stability mechanical properties oil palm mesocarp fiber poly(butylene succinate) superheated steam |
url | http://www.mdpi.com/1422-0067/15/9/15344 |
work_keys_str_mv | AT yoonyeethen theinfluenceofgreensurfacemodificationofoilpalmmesocarpfiberbysuperheatedsteamonthemechanicalpropertiesanddimensionalstabilityofoilpalmmesocarpfiberpolybutylenesuccinatebiocomposite AT norazowaibrahim theinfluenceofgreensurfacemodificationofoilpalmmesocarpfiberbysuperheatedsteamonthemechanicalpropertiesanddimensionalstabilityofoilpalmmesocarpfiberpolybutylenesuccinatebiocomposite AT norhazlinzainuddin theinfluenceofgreensurfacemodificationofoilpalmmesocarpfiberbysuperheatedsteamonthemechanicalpropertiesanddimensionalstabilityofoilpalmmesocarpfiberpolybutylenesuccinatebiocomposite AT hidayahariffin theinfluenceofgreensurfacemodificationofoilpalmmesocarpfiberbysuperheatedsteamonthemechanicalpropertiesanddimensionalstabilityofoilpalmmesocarpfiberpolybutylenesuccinatebiocomposite AT wanmdzinwanyunus theinfluenceofgreensurfacemodificationofoilpalmmesocarpfiberbysuperheatedsteamonthemechanicalpropertiesanddimensionalstabilityofoilpalmmesocarpfiberpolybutylenesuccinatebiocomposite AT buongwoeichieng theinfluenceofgreensurfacemodificationofoilpalmmesocarpfiberbysuperheatedsteamonthemechanicalpropertiesanddimensionalstabilityofoilpalmmesocarpfiberpolybutylenesuccinatebiocomposite AT yoonyeethen influenceofgreensurfacemodificationofoilpalmmesocarpfiberbysuperheatedsteamonthemechanicalpropertiesanddimensionalstabilityofoilpalmmesocarpfiberpolybutylenesuccinatebiocomposite AT norazowaibrahim influenceofgreensurfacemodificationofoilpalmmesocarpfiberbysuperheatedsteamonthemechanicalpropertiesanddimensionalstabilityofoilpalmmesocarpfiberpolybutylenesuccinatebiocomposite AT norhazlinzainuddin influenceofgreensurfacemodificationofoilpalmmesocarpfiberbysuperheatedsteamonthemechanicalpropertiesanddimensionalstabilityofoilpalmmesocarpfiberpolybutylenesuccinatebiocomposite AT hidayahariffin influenceofgreensurfacemodificationofoilpalmmesocarpfiberbysuperheatedsteamonthemechanicalpropertiesanddimensionalstabilityofoilpalmmesocarpfiberpolybutylenesuccinatebiocomposite AT wanmdzinwanyunus influenceofgreensurfacemodificationofoilpalmmesocarpfiberbysuperheatedsteamonthemechanicalpropertiesanddimensionalstabilityofoilpalmmesocarpfiberpolybutylenesuccinatebiocomposite AT buongwoeichieng influenceofgreensurfacemodificationofoilpalmmesocarpfiberbysuperheatedsteamonthemechanicalpropertiesanddimensionalstabilityofoilpalmmesocarpfiberpolybutylenesuccinatebiocomposite |