(Disulfur dinitrido)triphenylantimony(V)

The title compound, [Sb(C6H5)3(N2S2)], contains a molecular entity that is very similar to that of the known polymorph of Sb(S2N2)Ph3 [Kunkel et al. (1997). Z. Naturforsch. Teil B, 52, 193–198], differing only in the orientation of the phenyl rings. The bond order in the SNSN unit is S...

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Main Authors: Alexandra M. Z. Slawin, Paul G. Waddell, J. Derek Woollins
Format: Article
Language:English
Published: International Union of Crystallography 2010-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810009487
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author Alexandra M. Z. Slawin
Paul G. Waddell
J. Derek Woollins
author_facet Alexandra M. Z. Slawin
Paul G. Waddell
J. Derek Woollins
author_sort Alexandra M. Z. Slawin
collection DOAJ
description The title compound, [Sb(C6H5)3(N2S2)], contains a molecular entity that is very similar to that of the known polymorph of Sb(S2N2)Ph3 [Kunkel et al. (1997). Z. Naturforsch. Teil B, 52, 193–198], differing only in the orientation of the phenyl rings. The bond order in the SNSN unit is S—N=S=N, consisting of one long S—N bond, an intermediate length N=S bond and a short S=N bond.
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spelling doaj.art-2419f6212e9f4409a78782ffab8399a42022-12-21T21:03:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-04-01664m418m41810.1107/S1600536810009487(Disulfur dinitrido)triphenylantimony(V)Alexandra M. Z. SlawinPaul G. WaddellJ. Derek WoollinsThe title compound, [Sb(C6H5)3(N2S2)], contains a molecular entity that is very similar to that of the known polymorph of Sb(S2N2)Ph3 [Kunkel et al. (1997). Z. Naturforsch. Teil B, 52, 193–198], differing only in the orientation of the phenyl rings. The bond order in the SNSN unit is S—N=S=N, consisting of one long S—N bond, an intermediate length N=S bond and a short S=N bond.http://scripts.iucr.org/cgi-bin/paper?S1600536810009487
spellingShingle Alexandra M. Z. Slawin
Paul G. Waddell
J. Derek Woollins
(Disulfur dinitrido)triphenylantimony(V)
Acta Crystallographica Section E
title (Disulfur dinitrido)triphenylantimony(V)
title_full (Disulfur dinitrido)triphenylantimony(V)
title_fullStr (Disulfur dinitrido)triphenylantimony(V)
title_full_unstemmed (Disulfur dinitrido)triphenylantimony(V)
title_short (Disulfur dinitrido)triphenylantimony(V)
title_sort disulfur dinitrido triphenylantimony v
url http://scripts.iucr.org/cgi-bin/paper?S1600536810009487
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