(Disulfur dinitrido)triphenylantimony(V)
The title compound, [Sb(C6H5)3(N2S2)], contains a molecular entity that is very similar to that of the known polymorph of Sb(S2N2)Ph3 [Kunkel et al. (1997). Z. Naturforsch. Teil B, 52, 193–198], differing only in the orientation of the phenyl rings. The bond order in the SNSN unit is S...
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Format: | Article |
Language: | English |
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International Union of Crystallography
2010-04-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810009487 |
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author | Alexandra M. Z. Slawin Paul G. Waddell J. Derek Woollins |
author_facet | Alexandra M. Z. Slawin Paul G. Waddell J. Derek Woollins |
author_sort | Alexandra M. Z. Slawin |
collection | DOAJ |
description | The title compound, [Sb(C6H5)3(N2S2)], contains a molecular entity that is very similar to that of the known polymorph of Sb(S2N2)Ph3 [Kunkel et al. (1997). Z. Naturforsch. Teil B, 52, 193–198], differing only in the orientation of the phenyl rings. The bond order in the SNSN unit is S—N=S=N, consisting of one long S—N bond, an intermediate length N=S bond and a short S=N bond. |
first_indexed | 2024-12-18T15:13:50Z |
format | Article |
id | doaj.art-2419f6212e9f4409a78782ffab8399a4 |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-12-18T15:13:50Z |
publishDate | 2010-04-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-2419f6212e9f4409a78782ffab8399a42022-12-21T21:03:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-04-01664m418m41810.1107/S1600536810009487(Disulfur dinitrido)triphenylantimony(V)Alexandra M. Z. SlawinPaul G. WaddellJ. Derek WoollinsThe title compound, [Sb(C6H5)3(N2S2)], contains a molecular entity that is very similar to that of the known polymorph of Sb(S2N2)Ph3 [Kunkel et al. (1997). Z. Naturforsch. Teil B, 52, 193–198], differing only in the orientation of the phenyl rings. The bond order in the SNSN unit is S—N=S=N, consisting of one long S—N bond, an intermediate length N=S bond and a short S=N bond.http://scripts.iucr.org/cgi-bin/paper?S1600536810009487 |
spellingShingle | Alexandra M. Z. Slawin Paul G. Waddell J. Derek Woollins (Disulfur dinitrido)triphenylantimony(V) Acta Crystallographica Section E |
title | (Disulfur dinitrido)triphenylantimony(V) |
title_full | (Disulfur dinitrido)triphenylantimony(V) |
title_fullStr | (Disulfur dinitrido)triphenylantimony(V) |
title_full_unstemmed | (Disulfur dinitrido)triphenylantimony(V) |
title_short | (Disulfur dinitrido)triphenylantimony(V) |
title_sort | disulfur dinitrido triphenylantimony v |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536810009487 |
work_keys_str_mv | AT alexandramzslawin disulfurdinitridotriphenylantimonyv AT paulgwaddell disulfurdinitridotriphenylantimonyv AT jderekwoollins disulfurdinitridotriphenylantimonyv |