Methyl 12-Methyl-3,9-dinitro-5,6,7,12-tetrahydro-13-oxodibenzo[<i>b</i>.<i>g</i>]bicyclo[3.3.1]nonane-6-carboxylate and Related Compounds

Methyl 12-Methyl-3,9-dinitro-5,6,7,12-tetrahydro-13-oxodibenzo[<i>b</i>.<i>g</i>]bicyclo[3.3.1]nonane-6-carboxylate and Related Compounds

A synthesis of the title compound and related structures is reported. The procedure involves double alkylation of a β-ketoester followed by double S<sub>N</sub>Ar ring closure from the γ carbon to give a dibenzo[3.3.1]bicyclic unit. This paper appears to be the first to generate a mid-si...

Full description

Bibliographic Details
Main Authors:	Dylan R. Nanney, Richard A. Bunce
Format:	Article
Language:	English
Published:	MDPI AG 2022-12-01
Series:	Molbank
Subjects:	double alkylation double S<sub>N</sub>Ar ring closure dibenzo[3.3.1]bicyclic systems
Online Access:	https://www.mdpi.com/1422-8599/2022/4/M1526

Similar Items

<i>trans</i>-11-(3,4-Dimethoxyphenyl)-2,3,8,9-tetramethoxy-6-oxo-11,12-dihydro-6<i>H</i>-dibenzo[<i>c,h</i>]chromene-12-carboxylic Acid
by: Victor Angelov, et al.
Published: (2024-11-01)

5-Methyl-1-phenyl-3-(thieno[2,3-<i>d</i>]pyrimidin-4-yl)chromeno[4,3-<i>d</i>]pyrazolo[3,4-<i>b</i>]pyridin-6(3<i>H</i>)-one
by: Xuelian Yin, et al.
Published: (2022-10-01)

<i>N</i>,<i>N</i>′-1,2-Phenylene-bis(3-tert-butylsalicylideneiminato)nickel (II)
by: Maria Novozhilova, et al.
Published: (2023-06-01)

(<i>E</i>)-3-((2-Fluorophenyl)(hydroxy)methylene)imidazo[1,2-<i>a</i>]pyridin-2(3<i>H</i>)-one
by: Giammarco Tenti, et al.
Published: (2021-05-01)

Double Roman Graphs in <i>P</i>(3<i>k</i>, <i>k</i>)
by: Zehui Shao, et al.
Published: (2021-02-01)

Tb<sup>3+</sup> and Bi<sup>3+</sup> Co-Doping of Lead-Free Cs<sub>2</sub>NaInCl<sub>6</sub> Double Perovskite Nanocrystals for Tailoring Optical Properties
by: Yang Yu, et al.
Published: (2023-01-01)

Design and Device Numerical Analysis of Lead-Free Cs<sub>2</sub>AgBiBr<sub>6</sub> Double Perovskite Solar Cell
by: Tarek I. Alanazi
Published: (2023-02-01)

Ni<sub>3</sub>S<sub>2</sub>@NiMo-LDH Composite for Flexible Hybrid Capacitors
by: Qi He, et al.
Published: (2024-06-01)

Unsymmetrically-Substituted 5,12-dihydrodibenzo[<i>b</i>,<i>f</i>][1,4]diazocine-6,11-dione Scaffold—A Useful Tool for Bioactive Molecules Design
by: Bartosz Bieszczad, et al.
Published: (2020-06-01)

1,1’,1’’-(2’,4’-Dinitro-[1,1’-biphenyl]-2,4,6-triyl)tripiperidine
by: Gabriele Micheletti, et al.
Published: (2020-08-01)

Entropy Related to <i>K</i>-Banhatti Indices via Valency Based on the Presence of <i>C</i><sub>6</sub><i>H</i><sub>6</sub> in Various Molecules
by: Muhammad Usman Ghani, et al.
Published: (2023-01-01)

4-Amino-5-benzoyl-1-benzyl-2-(4,5,6,7-tetrahydro-1<i>H</i>-indol-2-yl)-1<i>H</i>-pyrrole-3-carbonitrile
by: Olga V. Petrova, et al.
Published: (2023-01-01)

1,6-Nucleophilic Di- and Trifluoromethylation of <i>para</i>-Quinone Methides with Me<sub>3</sub>SiCF<sub>2</sub>H/Me<sub>3</sub>SiCF<sub>3</sub> Facilitated by CsF/18-Crown-6
by: Dingben Chen, et al.
Published: (2024-06-01)

6-Chloro-3-nitro-2-[(phenylsulfonyl)methyl]imidazo[1,2-<i>b</i>]pyridazine
by: Romain Paoli-Lombardo, et al.
Published: (2023-02-01)

Multiferroic and Magnetodielectric Effects in Multiferroic Pr<sub>2</sub>FeAlO<sub>6</sub> Double Perovskite
by: Sheng Liu, et al.
Published: (2022-08-01)

Entropies Via Various Molecular Descriptors of Layer Structure of <i>H</i><sub>3</sub><i>BO</i><sub>3</sub>
by: Muhammad Usman Ghani, et al.
Published: (2022-12-01)

Thermal Catalytic Decomposition of Dimethyl Methyl Phosphonate Using CuO-CeO<sub>2</sub>/<i>γ</i>-Al<sub>2</sub>O<sub>3</sub>
by: Han Gao, et al.
Published: (2022-10-01)

Klein Tunneling in <i>β</i><sub>12</sub> Borophene
by: Jinhao Lai, et al.
Published: (2024-05-01)

Bipolar Nb<sub>3</sub>Cl<sub>8</sub> Field Effect Transistors
by: Yixiang Lu, et al.
Published: (2024-06-01)

(1<i>S</i>,5<i>R</i>)-6,6-Dimethyl-4-(((1<i>S</i>,2<i>S</i>,5<i>S</i>)-2,6,6-trimethyl-4-oxobicyclo[3.1.1]heptan-2-yl)methyl)bicyclo[3.1.1]hept-3-en-2-one
by: Oleg V. Ardashov, et al.
Published: (2022-10-01)

<i>N</i>,<i>N</i>′-Bis(3-ethoxy-2-hydroxybenzylidene)-phenylene-1,3-diamine Methanol Solvate
by: Dariusz Osypiuk, et al.
Published: (2023-07-01)

(<i>E</i>)-2-(1,3-Diphenylallyl)-3,5-dimethoxyphenol
by: Lara Mollà-Guerola, et al.
Published: (2023-08-01)

<sub>3</sub><i>F</i><sub>4</sub> Hypergeometric Functions as a Sum of a Product of <sub>2</sub><i>F</i><sub>3</sub> Functions
by: Jack C. Straton
Published: (2024-03-01)

Comparative Assessment of Genetic Variability Realised in Doubled Haploids Induced from F<sub>1</sub> and F<sub>2</sub> Plants for Response to Fusarium Stalk Rot and Yield Traits in Maize (<i>Zea mays</i> L.)
by: Budensab Mamtazbi Showkath Babu, et al.
Published: (2022-12-01)

THE STUDY OF THE LUMINESCENCE PROPERTIES OF Y<sub>0.85‑ <i>x</i></sub>Yb<sub>0.15</sub>Er <i><sub>x</sub> </i>Al<sub>3</sub>(BO<sub>3</sub>)<sub>4</sub>
by: Sergey Vladimirovich Kostyukov, et al.
Published: (2022-05-01)

Optimization of Deposition Parameters for α-Al<sub>2</sub>O<sub>3</sub> Coatings by Double Glow Plasma Technique
by: Y.-B. Lin, et al.
Published: (2015-09-01)

Investigation of Structural and Luminescent Properties of Sol-Gel-Derived Cr‑Substituted Mg<sub>3</sub>Al<sub>1−x</sub>Cr<sub>x</sub> Layered Double Hydroxides
by: Ligita Valeikiene, et al.
Published: (2021-03-01)

Methyl 3,3-Bis[4-(dimethylamino)phenyl]-2,2-dimethylpropanoate
by: Lara Mollà-Guerola, et al.
Published: (2023-05-01)

Impact of the Substitution Pattern at the Basic Center and Geometry of the Amine Fragment on 5-HT<sub>6</sub> and D<sub>3</sub>R Affinity in the 1<i>H</i>-Pyrrolo[3,2-<i>c</i>]quinoline Series
by: Katarzyna Grychowska, et al.
Published: (2023-01-01)

Fe<sub>3</sub>O<sub>4</sub>-PEI Nanocomposites for Magnetic Harvesting of <i>Chlorella vulgaris</i>, <i>Chlorella ellipsoidea</i>, <i>Microcystis aeruginosa</i>, and <i>Auxenochlorella protothecoides</i>
by: Kristína Gerulová, et al.
Published: (2022-05-01)

<i>In-situ</i> Al<sub>3</sub>Ti/ADC12 Composites Synthesized from Al-Ti System
by: XIONG Jun-jie, et al.
Published: (2017-08-01)

Comparison of Sb<sub>2</sub>O<sub>3</sub> and Sb<sub>2</sub>O<sub>3</sub>/SiO<sub>2</sub> Double Stacked pH Sensing Membrane Applied in Electrolyte-Insulator-Semiconductor Structure
by: Chyuan-Haur Kao, et al.
Published: (2022-07-01)

RESEARCH OF THE INFLUENCE OF IMPURITIES DYSPROSIUM AND THULIUM ON THE LUMINESCENCE OF SOLID SOLUTIONS Y<sub>1– <i>x</i></sub>Yb <i><sub>x</sub> </i>Al<sub>3</sub>(BO<sub>3</sub>)<sub>4</sub>
by: Sergey Vladimirovich Kostyukov
Published: (2022-05-01)

Cold Sintering of Li<sub>6.4</sub>La<sub>3</sub>Zr<sub>1.4</sub>Ta<sub>0.6</sub>O<sub>12</sub>/PEO Composite Solid Electrolytes
by: Binlang He, et al.
Published: (2022-10-01)

Growth Peculiarities and Properties of K<i>R</i><sub>3</sub>F<sub>10</sub> (<i>R</i> = Y, Tb) Single Crystals
by: Denis N. Karimov, et al.
Published: (2021-03-01)

Conformational Restriction of Histamine with a Rigid Bicyclo[3.1.0]hexane Scaffold Provided Selective H<sub>3</sub> Receptor Ligands
by: Mizuki Watanabe, et al.
Published: (2020-08-01)

Tuning Ionic Liquid-Based Catalysts for CO<sub>2</sub> Conversion into Quinazoline-2,4(1<i>H</i>,3<i>H</i>)-diones
by: Ruina Zhang, et al.
Published: (2023-01-01)

Crystal Structure, Chemical Bond, and Microwave Dielectric Properties of Ba<sub>1−<i>x</i></sub>Sr<i><sub>x</sub></i>(Zn<sub>1/3</sub>Nb<sub>2/3</sub>)O<sub>3</sub> Solid Solution Ceramics
by: Lei Xiao, et al.
Published: (2023-04-01)

6-Chloro-3-nitro-8-(phenylthio)-2-[(phenylthio)methyl] imidazo[1,2-<i>a</i>]pyridine
by: Romain Paoli-Lombardo, et al.
Published: (2023-03-01)

High Efficiency and High Stability for SHG in an <i>Nd</i>:<i>YVO</i><sub>4</sub> Laser with a KTP Intracavity and Q-Switching through Harmonic Modulation
by: Samuel Mardoqueo Afanador Delgado, et al.
Published: (2023-04-01)