Inhibition effects of ionic and non-ionic derivatives of imidazole compounds on hydrogen permeation during carbon steel pickling
Hydrogen embrittlement can occur when atomic hydrogen is absorbed by steel during the acid cleaning process. In the literature, studies of corrosion inhibition by organic compounds in acid solutions have not given attention to the inhibition of hydrogen permeation in the steel. In this work, we show...
| Main Authors: | , , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2022-01-01
|
| Series: | Journal of Materials Research and Technology |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2238785421015118 |
| _version_ | 1798024720645357568 |
|---|---|
| author | Matheus G. Silva Rodrigo G. de Araujo Raquel L. Silvério Alberto N.C. Costa Diego P. Sangi Leandro F. Pedrosa Gláucio S. da Fonseca Ladário da Silva Lilian W. Coelho Elivelton A. Ferreira |
| author_facet | Matheus G. Silva Rodrigo G. de Araujo Raquel L. Silvério Alberto N.C. Costa Diego P. Sangi Leandro F. Pedrosa Gláucio S. da Fonseca Ladário da Silva Lilian W. Coelho Elivelton A. Ferreira |
| author_sort | Matheus G. Silva |
| collection | DOAJ |
| description | Hydrogen embrittlement can occur when atomic hydrogen is absorbed by steel during the acid cleaning process. In the literature, studies of corrosion inhibition by organic compounds in acid solutions have not given attention to the inhibition of hydrogen permeation in the steel. In this work, we show that the best corrosion inhibition does not always indicate the best hydrogen permeation inhibition. For the first time, imidazole-based compounds were studied as hydrogen permeation inhibitors during carbon steel pickling in hydrochloric acid at high concentration (5.4 mol L−1). The immersion of steel in solutions containing 250 mg L−1 of the inhibitors 1-butyl-3-methylimidazolium tetrafluoroborate ([Bmim]BF4) and 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) resulted in low corrosion inhibition efficiency of approximately 18% in both cases. On the other hand, the hydrogen permeation inhibition efficiency was 59%. The addition of 2-(nitromethylene) imidazolidine (IMD) and 2-(nitromethylene) oxazolidine (OXA) to HCl solutions provided corrosion inhibition efficiencies of 46.7% and 24.4%, respectively. However, these compounds did not present hydrogen permeation inhibition effects. |
| first_indexed | 2024-04-11T18:07:16Z |
| format | Article |
| id | doaj.art-242b6ddee5de4bd0aeba605b25988bd9 |
| institution | Directory Open Access Journal |
| issn | 2238-7854 |
| language | English |
| last_indexed | 2024-04-11T18:07:16Z |
| publishDate | 2022-01-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Journal of Materials Research and Technology |
| spelling | doaj.art-242b6ddee5de4bd0aeba605b25988bd92022-12-22T04:10:17ZengElsevierJournal of Materials Research and Technology2238-78542022-01-011613241338Inhibition effects of ionic and non-ionic derivatives of imidazole compounds on hydrogen permeation during carbon steel picklingMatheus G. Silva0Rodrigo G. de Araujo1Raquel L. Silvério2Alberto N.C. Costa3Diego P. Sangi4Leandro F. Pedrosa5Gláucio S. da Fonseca6Ladário da Silva7Lilian W. Coelho8Elivelton A. Ferreira9Programa de Pós-Graduação em Engenharia Metalúrgica (PPGEM), Universidade Federal Fluminense, 27255-125, Volta Redonda, Rio de Janeiro, BrazilInstituto de Ciências Exatas, Universidade Federal Fluminense, 27213-145, Volta Redonda, Rio de Janeiro, BrazilInstituto de Ciências Exatas, Universidade Federal Fluminense, 27213-145, Volta Redonda, Rio de Janeiro, BrazilPrograma de Pós-Graduação em Engenharia Mecânica, Universidade Estadual Paulista, Guaratinguetá, 12516-410, São Paulo, Brazil; Companhia Siderúrgica Nacional (CSN), 27260-390, Volta Redonda, Rio de Janeiro, BrazilInstituto de Ciências Exatas, Universidade Federal Fluminense, 27213-145, Volta Redonda, Rio de Janeiro, Brazil; Corresponding author.Instituto de Ciências Exatas, Universidade Federal Fluminense, 27213-145, Volta Redonda, Rio de Janeiro, BrazilPrograma de Pós-Graduação em Engenharia Metalúrgica (PPGEM), Universidade Federal Fluminense, 27255-125, Volta Redonda, Rio de Janeiro, BrazilPrograma de Pós-Graduação em Engenharia Metalúrgica (PPGEM), Universidade Federal Fluminense, 27255-125, Volta Redonda, Rio de Janeiro, Brazil; Instituto de Ciências Exatas, Universidade Federal Fluminense, 27213-145, Volta Redonda, Rio de Janeiro, BrazilDepartamento de Ciências Exatas, Escola de Engenharia Industrial e Metalurgia de Volta Redonda, 27255-125, Volta Redonda, Rio de Janeiro, Brazil; Corresponding author.Programa de Pós-Graduação em Engenharia Metalúrgica (PPGEM), Universidade Federal Fluminense, 27255-125, Volta Redonda, Rio de Janeiro, Brazil; Instituto de Ciências Exatas, Universidade Federal Fluminense, 27213-145, Volta Redonda, Rio de Janeiro, Brazil; Corresponding author.Hydrogen embrittlement can occur when atomic hydrogen is absorbed by steel during the acid cleaning process. In the literature, studies of corrosion inhibition by organic compounds in acid solutions have not given attention to the inhibition of hydrogen permeation in the steel. In this work, we show that the best corrosion inhibition does not always indicate the best hydrogen permeation inhibition. For the first time, imidazole-based compounds were studied as hydrogen permeation inhibitors during carbon steel pickling in hydrochloric acid at high concentration (5.4 mol L−1). The immersion of steel in solutions containing 250 mg L−1 of the inhibitors 1-butyl-3-methylimidazolium tetrafluoroborate ([Bmim]BF4) and 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) resulted in low corrosion inhibition efficiency of approximately 18% in both cases. On the other hand, the hydrogen permeation inhibition efficiency was 59%. The addition of 2-(nitromethylene) imidazolidine (IMD) and 2-(nitromethylene) oxazolidine (OXA) to HCl solutions provided corrosion inhibition efficiencies of 46.7% and 24.4%, respectively. However, these compounds did not present hydrogen permeation inhibition effects.http://www.sciencedirect.com/science/article/pii/S2238785421015118SAE 1020 steelImidazole-based compoundsHydrogen permeation inhibitionDiffusion coefficientDevanathan-Stachurski cellCorrosion inhibition |
| spellingShingle | Matheus G. Silva Rodrigo G. de Araujo Raquel L. Silvério Alberto N.C. Costa Diego P. Sangi Leandro F. Pedrosa Gláucio S. da Fonseca Ladário da Silva Lilian W. Coelho Elivelton A. Ferreira Inhibition effects of ionic and non-ionic derivatives of imidazole compounds on hydrogen permeation during carbon steel pickling Journal of Materials Research and Technology SAE 1020 steel Imidazole-based compounds Hydrogen permeation inhibition Diffusion coefficient Devanathan-Stachurski cell Corrosion inhibition |
| title | Inhibition effects of ionic and non-ionic derivatives of imidazole compounds on hydrogen permeation during carbon steel pickling |
| title_full | Inhibition effects of ionic and non-ionic derivatives of imidazole compounds on hydrogen permeation during carbon steel pickling |
| title_fullStr | Inhibition effects of ionic and non-ionic derivatives of imidazole compounds on hydrogen permeation during carbon steel pickling |
| title_full_unstemmed | Inhibition effects of ionic and non-ionic derivatives of imidazole compounds on hydrogen permeation during carbon steel pickling |
| title_short | Inhibition effects of ionic and non-ionic derivatives of imidazole compounds on hydrogen permeation during carbon steel pickling |
| title_sort | inhibition effects of ionic and non ionic derivatives of imidazole compounds on hydrogen permeation during carbon steel pickling |
| topic | SAE 1020 steel Imidazole-based compounds Hydrogen permeation inhibition Diffusion coefficient Devanathan-Stachurski cell Corrosion inhibition |
| url | http://www.sciencedirect.com/science/article/pii/S2238785421015118 |
| work_keys_str_mv | AT matheusgsilva inhibitioneffectsofionicandnonionicderivativesofimidazolecompoundsonhydrogenpermeationduringcarbonsteelpickling AT rodrigogdearaujo inhibitioneffectsofionicandnonionicderivativesofimidazolecompoundsonhydrogenpermeationduringcarbonsteelpickling AT raquellsilverio inhibitioneffectsofionicandnonionicderivativesofimidazolecompoundsonhydrogenpermeationduringcarbonsteelpickling AT albertonccosta inhibitioneffectsofionicandnonionicderivativesofimidazolecompoundsonhydrogenpermeationduringcarbonsteelpickling AT diegopsangi inhibitioneffectsofionicandnonionicderivativesofimidazolecompoundsonhydrogenpermeationduringcarbonsteelpickling AT leandrofpedrosa inhibitioneffectsofionicandnonionicderivativesofimidazolecompoundsonhydrogenpermeationduringcarbonsteelpickling AT glauciosdafonseca inhibitioneffectsofionicandnonionicderivativesofimidazolecompoundsonhydrogenpermeationduringcarbonsteelpickling AT ladariodasilva inhibitioneffectsofionicandnonionicderivativesofimidazolecompoundsonhydrogenpermeationduringcarbonsteelpickling AT lilianwcoelho inhibitioneffectsofionicandnonionicderivativesofimidazolecompoundsonhydrogenpermeationduringcarbonsteelpickling AT eliveltonaferreira inhibitioneffectsofionicandnonionicderivativesofimidazolecompoundsonhydrogenpermeationduringcarbonsteelpickling |