Synthesis of Ethyl Levulinate by a New Bio-nanocatalyst

Lipase from Thermomyces lanuginosus was physically anchored to AgAu-Fe3O4@tartaric acid nanoparticles (NPs) to be used for the conversion of levulinic acid into ethyl-levulinate, in the presence of ethanol. The proposed strategy explored the direct immobilization of the enzyme on the as-prepared tar...

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Bibliographic Details
Main Authors: Maria Sarno, Mariagrazia Iuliano
Format: Article
Language:English
Published: AIDIC Servizi S.r.l. 2020-06-01
Series:Chemical Engineering Transactions
Online Access:https://www.cetjournal.it/index.php/cet/article/view/10931
Description
Summary:Lipase from Thermomyces lanuginosus was physically anchored to AgAu-Fe3O4@tartaric acid nanoparticles (NPs) to be used for the conversion of levulinic acid into ethyl-levulinate, in the presence of ethanol. The proposed strategy explored the direct immobilization of the enzyme on the as-prepared tartaric acid modified NPs. A very remarkable conversion of 90 % was achieved at 4:1 ETOH/acid molar ratio, after 12 h and at 45°C reaction temperature, higher than that shown by free lipase.
ISSN:2283-9216