Application of Continuous-Wave Cavity Ring-Down Spectroscopy to Laminar Flames

In this paper, we describe the application of diode-laser continuous-wave cavity ring-down spectroscopy (cw-CRDS) to in-situ flame diagnostics. Spectra of the P17e acetylene feature at 1535.4 nm were recorded in a premixed laminar ethylene/air flame. The overall absorption of the feature was measure...

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Main Authors: Gordon S. Humphries, Iain S. Burns, Michael Lengden
Format: Article
Language:English
Published: IEEE 2016-01-01
Series:IEEE Photonics Journal
Subjects:
Online Access:https://ieeexplore.ieee.org/document/7378838/
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author Gordon S. Humphries
Iain S. Burns
Michael Lengden
author_facet Gordon S. Humphries
Iain S. Burns
Michael Lengden
author_sort Gordon S. Humphries
collection DOAJ
description In this paper, we describe the application of diode-laser continuous-wave cavity ring-down spectroscopy (cw-CRDS) to in-situ flame diagnostics. Spectra of the P17e acetylene feature at 1535.4 nm were recorded in a premixed laminar ethylene/air flame. The overall absorption of the feature was measured to be <inline-formula> <tex-math notation="LaTeX">$\approx\!\!1.5\times 10^{-4}\ \text{cm}^{-1}$</tex-math></inline-formula>, which is a short distance above the reaction zone for a flame fuel equivalence ratio of 1.66, and the minimum detection limit <inline-formula> <tex-math notation="LaTeX">$(3\sigma)$</tex-math></inline-formula> of the system was calculated to be <inline-formula> <tex-math notation="LaTeX">$1.2\times 10^{-5}\ \text{cm}^{-1}$</tex-math></inline-formula>. This demonstrates the potential of the technique for the measurement of weakly absorbing species in flames. Finally, we discuss the advantages and limitations of the cw-CRDS technique for flame measurements.
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spelling doaj.art-24550b816bb0420c85be9d679ba728332023-04-27T23:00:18ZengIEEEIEEE Photonics Journal1943-06552016-01-018111010.1109/JPHOT.2016.25175757378838Application of Continuous-Wave Cavity Ring-Down Spectroscopy to Laminar FlamesGordon S. Humphries0Iain S. Burns1Michael Lengden2Dept. of Electron. &amp; Electr. Eng., Univ. of Strathclyde, Glasgow, UKDept. of Chem. &amp; Process Eng., Univ. of Strathclyde, Glasgow, UKDept. of Electron. &amp; Electr. Eng., Univ. of Strathclyde, Glasgow, UKIn this paper, we describe the application of diode-laser continuous-wave cavity ring-down spectroscopy (cw-CRDS) to in-situ flame diagnostics. Spectra of the P17e acetylene feature at 1535.4 nm were recorded in a premixed laminar ethylene/air flame. The overall absorption of the feature was measured to be <inline-formula> <tex-math notation="LaTeX">$\approx\!\!1.5\times 10^{-4}\ \text{cm}^{-1}$</tex-math></inline-formula>, which is a short distance above the reaction zone for a flame fuel equivalence ratio of 1.66, and the minimum detection limit <inline-formula> <tex-math notation="LaTeX">$(3\sigma)$</tex-math></inline-formula> of the system was calculated to be <inline-formula> <tex-math notation="LaTeX">$1.2\times 10^{-5}\ \text{cm}^{-1}$</tex-math></inline-formula>. This demonstrates the potential of the technique for the measurement of weakly absorbing species in flames. Finally, we discuss the advantages and limitations of the cw-CRDS technique for flame measurements.https://ieeexplore.ieee.org/document/7378838/cw-CRDSCombustionCavity Ring-DownDiode laser.
spellingShingle Gordon S. Humphries
Iain S. Burns
Michael Lengden
Application of Continuous-Wave Cavity Ring-Down Spectroscopy to Laminar Flames
IEEE Photonics Journal
cw-CRDS
Combustion
Cavity Ring-Down
Diode laser.
title Application of Continuous-Wave Cavity Ring-Down Spectroscopy to Laminar Flames
title_full Application of Continuous-Wave Cavity Ring-Down Spectroscopy to Laminar Flames
title_fullStr Application of Continuous-Wave Cavity Ring-Down Spectroscopy to Laminar Flames
title_full_unstemmed Application of Continuous-Wave Cavity Ring-Down Spectroscopy to Laminar Flames
title_short Application of Continuous-Wave Cavity Ring-Down Spectroscopy to Laminar Flames
title_sort application of continuous wave cavity ring down spectroscopy to laminar flames
topic cw-CRDS
Combustion
Cavity Ring-Down
Diode laser.
url https://ieeexplore.ieee.org/document/7378838/
work_keys_str_mv AT gordonshumphries applicationofcontinuouswavecavityringdownspectroscopytolaminarflames
AT iainsburns applicationofcontinuouswavecavityringdownspectroscopytolaminarflames
AT michaellengden applicationofcontinuouswavecavityringdownspectroscopytolaminarflames