Reação entre fenilnitrometanos e enoato derivado do D-manitol na presença de TBAF ou DBU: adição conjugada sin-seletiva e reação de NEF consecutiva The reaction between Phenylnitromethanes and enoate derived from D-mannitol in the presence of TBAF or DBU: tandem syn-selective conjugate addition and NEF reaction

Reação entre fenilnitrometanos e enoato derivado do D-manitol na presença de TBAF ou DBU: adição conjugada sin-seletiva e reação de NEF consecutiva The reaction between Phenylnitromethanes and enoate derived from D-mannitol in the presence of TBAF or DBU: tandem syn-selective conjugate addition and NEF reaction

<abstract language="eng">A tandem syn-selective conjugate addition - Nef reaction was observed when phenylnitromethane and oxygenated derivatives were allowed to react with an enoate derived from D-mannitol at rt in the presence of TBAF or DBU. While nitro-adducts predominate after 4...

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Bibliographic Details
Main Authors: Ayres G. Dias, Vagner D. Pinho, Paulo R. R. Costa
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2008-01-01
Series:Química Nova
Subjects:
Nef reaction
chiral enoates
stereoselective conjugate addition
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422008000400024

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