Synthesis and crystal structure of NaCuIn(PO4)2
Single crystals of sodium copper(II) indium bis[phosphate(V)], NaCuIn(PO4)2, were grown from the melt under atmospheric conditions. The title phosphate crystallizes in the space group P21/n and is isotypic with KCuFe(PO4)2. In the crystal, two [CuO5] trigonal bipyramids share an edge to form a dimer...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2020-03-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989020001929 |
| _version_ | 1798017699116220416 |
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| author | Elhassan Benhsina Jamal Khmiyas Said Ouaatta Abderrazzak Assani Mohamed Saadi Lahcen El Ammari |
| author_facet | Elhassan Benhsina Jamal Khmiyas Said Ouaatta Abderrazzak Assani Mohamed Saadi Lahcen El Ammari |
| author_sort | Elhassan Benhsina |
| collection | DOAJ |
| description | Single crystals of sodium copper(II) indium bis[phosphate(V)], NaCuIn(PO4)2, were grown from the melt under atmospheric conditions. The title phosphate crystallizes in the space group P21/n and is isotypic with KCuFe(PO4)2. In the crystal, two [CuO5] trigonal bipyramids share an edge to form a dimer [Cu2O8] that is connected to two PO4 tetrahedra. The obtained [Cu2P2O12] units are interconnected through vertices to form sheets that are sandwiched between undulating layers resulting from the junction of PO4 tetrahedra and [InO6] octahedra. The two types of layers are alternately stacked along [101] and are joined into a three-dimensional framework through vertex- and edge-sharing, leaving channels parallel to the stacking direction. The channels host the sodium cations that are surrounded by four oxygen atoms in form of a distorted disphenoid. |
| first_indexed | 2024-04-11T16:11:38Z |
| format | Article |
| id | doaj.art-2475464f09ef474597fe3c4ea193a77b |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-04-11T16:11:38Z |
| publishDate | 2020-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-2475464f09ef474597fe3c4ea193a77b2022-12-22T04:14:41ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902020-03-0176336636910.1107/S2056989020001929wm5539Synthesis and crystal structure of NaCuIn(PO4)2Elhassan Benhsina0Jamal Khmiyas1Said Ouaatta2Abderrazzak Assani3Mohamed Saadi4Lahcen El Ammari5Laboratoire de Chimie Appliquée des Matériaux, Centre des Sciences des Matériaux, Faculty of Sciences, Mohammed V University in Rabat, Avenue Ibn Batouta, BP 1014, Rabat, MoroccoLaboratoire de Chimie Appliquée des Matériaux, Centre des Sciences des Matériaux, Faculty of Sciences, Mohammed V University in Rabat, Avenue Ibn Batouta, BP 1014, Rabat, MoroccoLaboratoire de Chimie Appliquée des Matériaux, Centre des Sciences des Matériaux, Faculty of Sciences, Mohammed V University in Rabat, Avenue Ibn Batouta, BP 1014, Rabat, MoroccoLaboratoire de Chimie Appliquée des Matériaux, Centre des Sciences des Matériaux, Faculty of Sciences, Mohammed V University in Rabat, Avenue Ibn Batouta, B.P. 1014, Rabat, MoroccoLaboratoire de Chimie Appliquée des Matériaux, Centre des Sciences des Matériaux, Faculty of Sciences, Mohammed V University in Rabat, Avenue Ibn Batouta, B.P. 1014, Rabat, MoroccoLaboratoire de Chimie Appliquée des Matériaux, Centre des Sciences des Matériaux, Faculty of Sciences, Mohammed V University in Rabat, Avenue Ibn Batouta, B.P. 1014, Rabat, MoroccoSingle crystals of sodium copper(II) indium bis[phosphate(V)], NaCuIn(PO4)2, were grown from the melt under atmospheric conditions. The title phosphate crystallizes in the space group P21/n and is isotypic with KCuFe(PO4)2. In the crystal, two [CuO5] trigonal bipyramids share an edge to form a dimer [Cu2O8] that is connected to two PO4 tetrahedra. The obtained [Cu2P2O12] units are interconnected through vertices to form sheets that are sandwiched between undulating layers resulting from the junction of PO4 tetrahedra and [InO6] octahedra. The two types of layers are alternately stacked along [101] and are joined into a three-dimensional framework through vertex- and edge-sharing, leaving channels parallel to the stacking direction. The channels host the sodium cations that are surrounded by four oxygen atoms in form of a distorted disphenoid.http://scripts.iucr.org/cgi-bin/paper?S2056989020001929crystal structurephosphateamm'(po4)2 familytrigonal–bipyramidal coordinationisotypism |
| spellingShingle | Elhassan Benhsina Jamal Khmiyas Said Ouaatta Abderrazzak Assani Mohamed Saadi Lahcen El Ammari Synthesis and crystal structure of NaCuIn(PO4)2 Acta Crystallographica Section E: Crystallographic Communications crystal structure phosphate amm'(po4)2 family trigonal–bipyramidal coordination isotypism |
| title | Synthesis and crystal structure of NaCuIn(PO4)2 |
| title_full | Synthesis and crystal structure of NaCuIn(PO4)2 |
| title_fullStr | Synthesis and crystal structure of NaCuIn(PO4)2 |
| title_full_unstemmed | Synthesis and crystal structure of NaCuIn(PO4)2 |
| title_short | Synthesis and crystal structure of NaCuIn(PO4)2 |
| title_sort | synthesis and crystal structure of nacuin po4 2 |
| topic | crystal structure phosphate amm'(po4)2 family trigonal–bipyramidal coordination isotypism |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989020001929 |
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