A modulation wave approach to the order hidden in disorder

The usefulness of a modulation wave approach to understanding and interpreting the highly structured continuous diffuse intensity distributions characteristic of the reciprocal spaces of the very large family of inherently flexible materials which exhibit ordered `disorder' is pointed out. It i...

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Main Author: Ray Withers
Format: Article
Language:English
Published: International Union of Crystallography 2015-01-01
Series:IUCrJ
Subjects:
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2052252514022556
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author Ray Withers
author_facet Ray Withers
author_sort Ray Withers
collection DOAJ
description The usefulness of a modulation wave approach to understanding and interpreting the highly structured continuous diffuse intensity distributions characteristic of the reciprocal spaces of the very large family of inherently flexible materials which exhibit ordered `disorder' is pointed out. It is shown that both longer range order and truly short-range order are simultaneously encoded in highly structured diffuse intensity distributions. The long-range ordered crystal chemical rules giving rise to such diffuse distributions are highlighted, along with the existence and usefulness of systematic extinction conditions in these types of structured diffuse distributions.
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spelling doaj.art-247b15249bf94cc9ac3c578545c556142022-12-21T19:42:14ZengInternational Union of CrystallographyIUCrJ2052-25252015-01-0121748410.1107/S2052252514022556gq5002A modulation wave approach to the order hidden in disorderRay Withers0Research School of Chemistry, Australian National University, Building 1.38, Sullivan's Creek Road, Canberra, Australian Central Territory 0200, AustraliaThe usefulness of a modulation wave approach to understanding and interpreting the highly structured continuous diffuse intensity distributions characteristic of the reciprocal spaces of the very large family of inherently flexible materials which exhibit ordered `disorder' is pointed out. It is shown that both longer range order and truly short-range order are simultaneously encoded in highly structured diffuse intensity distributions. The long-range ordered crystal chemical rules giving rise to such diffuse distributions are highlighted, along with the existence and usefulness of systematic extinction conditions in these types of structured diffuse distributions.http://scripts.iucr.org/cgi-bin/paper?S2052252514022556modulation wave approachordered `disorder'crystalline structurelong-range ordershort-range order
spellingShingle Ray Withers
A modulation wave approach to the order hidden in disorder
IUCrJ
modulation wave approach
ordered `disorder'
crystalline structure
long-range order
short-range order
title A modulation wave approach to the order hidden in disorder
title_full A modulation wave approach to the order hidden in disorder
title_fullStr A modulation wave approach to the order hidden in disorder
title_full_unstemmed A modulation wave approach to the order hidden in disorder
title_short A modulation wave approach to the order hidden in disorder
title_sort modulation wave approach to the order hidden in disorder
topic modulation wave approach
ordered `disorder'
crystalline structure
long-range order
short-range order
url http://scripts.iucr.org/cgi-bin/paper?S2052252514022556
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